Results 211 to 220 of about 3,602,918 (298)

Directly Sunlight‐Chargeable Core‐Shell Azobenzene Fabric via Coaxial Electrospinning with Tunable Personal Thermal Management

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
This work presents a leakage‐free, sunlight‐chargeable core‐shell Azo‐based textile that effectively bridges molecular photothermal storage with wearable functionality, offering a robust platform for on‐demand solar‐powered personal thermal management.
Yating Zhang   +6 more
wiley   +1 more source

The Serendipitous Discovery of Rollover Cyclometalation: From Unrecognized Observation to Transformative Chemistry

open access: yesEuropean Journal of Inorganic Chemistry, EarlyView.
Rollover cyclometalation is a distinctive variant of classical cyclometalation where a chelated heterocyclic ligand undergoes internal rotation, releasing one donor atom from coordination and subsequently activating a remote C─H bond with high regioselectivity.
Antonio Zucca, Maria I. Pilo
wiley   +1 more source

Click Bioconjugation of Aza‐BODIPY Fluorophores to LfcinB Peptides for Improved Biocompatibility

open access: yesEuropean Journal of Organic Chemistry, EarlyView.
Click bioconjugation attaches NIR aza‐BODIPY fluorophores to LfcinB‐derived anticancer peptides via CuAAC and thiol‐maleimide chemistry. Conjugates exhibit improved predicted solubility while retaining strong NIR absorption (703–730 nm). Peptide‐aza‐BODIPY conjugates induce apoptotic morphology in HeLa cancer cells.
A. Verónica Rodríguez‐Mayor   +6 more
wiley   +1 more source

Efficient Synthesis of Cannabinoid Acids

open access: yesEuropean Journal of Organic Chemistry, EarlyView.
In this study, an alternative synthesis of cannabinoid acids was developed based on an O→C acyl rearrangement. Specifically, this strategy involved regioselective bromination followed by halogen–lithium exchange and intramolecular nucleophilic addition, which led to successful carboxylation.
Ryosuke Arai   +8 more
wiley   +1 more source

Thermal Nickel‐Catalyzed N‐Arylation of Sulfonimidamides With (Hetero)aryl Chlorides Enabled by PAd‐DalPhos Ligation

open access: yesEuropean Journal of Organic Chemistry, EarlyView.
The nickel‐catalyzed S═NH N‐arylation of sulfonimidamides is described, with useful demonstrated substrate scope involving inexpensive and widely available (hetero)aryl chloride reaction partners, including the active pharmaceutical ingredient chlorpromazine.
Samuel A. Fisher   +2 more
wiley   +1 more source

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