Novel Bioactive Multifunctional Polyphenols: A Chemo‐Enzymatic Approach
One‐step synthesis of complex alkyl oxystilbenin glucosides (6‐47% yield) in alcoholic medium. Switching to ter‐BuOH as solvent afforded δ‐Viniferin diglucoside, with high selectivity and high yield (> 90%), that can be upgraded by enzymatic esterification to alkyl δ‐Viniferin diglucosides.
Amandine L. Flourat +8 more
wiley +1 more source
Sustainable Nonenantioselective Production and Stereochemical Characterization of the Lignin-Derived Chiral Building Block 3-Carboxymuconolactone. [PDF]
Suzuki Y +8 more
europepmc +1 more source
Acid‐Catalyzed Synthesis of Si‐Stereogenic Silanes
Si‐stereogenic silanes are important structural motifs in chemical synthesis, medicinal chemistry, and materials science. However, their catalytic enantioselective synthesis has largely relied on transition‐metal catalysts. Recently, Brønsted acids have been developed as promising alternatives.
Jung Tae Han, Benjamin List
wiley +1 more source
Monosaccharide-Derived Enantioselectivity in SWCNT Chemoresistive VOC Sensing. [PDF]
Shitrit A +10 more
europepmc +1 more source
Anisotropy Factor Spectra for Weakly Allowed Electronic Transitions in Chiral Ketones
Anisotropy factor spectra for the weak n→π*‐type A‐band of chiral ketones cannot be described within the Franck–Condon approximation. Thus, we present such spectra computed by accounting for Herzberg–Teller corrections and compare them to experiments for fenchone, camphor and 3MCP to describe chiroptical properties of these molecules in the mid to near
Leon A. Kerber +5 more
wiley +1 more source
Biocatalytic Enantioselective Oxidation of <i>N</i>-Acyl-<i>S</i>-Methyl Sulfenamides for the Asymmetric Synthesis of <i>S</i>-Methyl Sulfoximines. [PDF]
Patel S +4 more
europepmc +1 more source
Efficient Enantiomeric Selectivity Separation Via Homochiral Graphene Oxide Membrane
A new type of chiral graphene oxide (GO) membrane is proposed that exhibits a separation factor of up to 20.1 as well as a preferential enantiomer flux of 4.5 mmol m−2 h−1. Moreover, the only first FPLC‐compatible column has been further developed via stacking these chiral GO membranes.
Junbo Wang +10 more
wiley +1 more source
High-performance gas-phase chiral enantiomer detectors based on chiral-induced spin selectivity effect. [PDF]
Wu X +6 more
europepmc +1 more source

