Results 141 to 150 of about 75,325 (204)

Post‐Modification of Tripyrenylenes to Enantiopure π‐Extended D3‐Symmetric Propellers

open access: yesChemistry – A European Journal, Volume 32, Issue 36, 24 September 2026.
The post‐modification of tripyrenylenes to π‐extended enantiopure propellers with tris‐phenanthrophenazines is presented and the chiroptical properties as well as the solid‐state packings investigated in comparison to the corresponding racemic mixtures.
Dennis Popp   +8 more
wiley   +1 more source

Force‐Induced Control of Circularly Polarized Luminescence With Rotaxane Architecture

open access: yesAngewandte Chemie, Volume 138, Issue 39, 21 September 2026.
Force‐induced reversible on/off switching of circularly polarized luminescence is achieved with a rotaxane‐based supramolecular mechanophore. The mechanophore, featuring a chiral helicene luminophore, is incorporated as a first network cross‐linker into a double‐network organogel.
Keigo Nonaka   +10 more
wiley   +2 more sources

Molecular basis and biological relevance of bacterial and plant pinoresinol/lariciresinol reductase specificities. [PDF]

open access: yesProtein Sci
Smith CA   +7 more
europepmc   +1 more source

Asymmetric Synthesis of Tertiary α‐Aryl Stereocentres in Tetrahydro‐4H‐pyran‐4‐ones Using Pd‐Catalyzed Decarboxylative Asymmetric Protonation

open access: yesEuropean Journal of Organic Chemistry, Volume 29, Issue 36, 24 September 2026.
The Pd‐catalyzed decarboxylative asymmetric protonation (DAP) has been developed for sterically hindered tetrahydro‐4H‐pyran‐4‐one derived α‐aryl‐β‐keto esters. A substrate scope of nine examples of DAP showed that substrates containing a di‐ortho methoxy substitution pattern on the aryl ring gave rise to the highest enantioselectivities of up to 85 ...
Fionn McNeill   +5 more
wiley   +1 more source

Regioselective Oxidative Oligomerization of 2‐Tert‐Butylpyrene Toward Structurally Defined Oligomers and Their Application in Organic Light‐Emitting Diodes

open access: yesEuropean Journal of Organic Chemistry, Volume 29, Issue 36, 24 September 2026.
Treatment of 2‐tert‐butylpyrene with Cu2+ afforded structurally well‐defined pyrene oligomers, up to the 13‐mer. Single‐crystal X‐ray diffraction, spectroscopic analyses, and computational studies were conducted to evaluate the properties of the resulting oligopyrenes.
Md Jadu Mia   +14 more
wiley   +1 more source

Borylcyclopropanes: Synthetic Strategies and Applications

open access: yesAngewandte Chemie, Volume 138, Issue 37, 7 September 2026.
Borylcyclopropanes (cyclopropanes bearing a boron substituent) sit at the intersection of two privileged frameworks in synthesis. This review provides the first exhaustive survey of their chemistry, spanning metal–carbene, nucleophilic cyclization, radical, hydroboration, and C─H activation routes, and documenting applications in medicinal chemistry ...
Aiza A. Butt, Joseph M. Ready
wiley   +2 more sources

A machine learning-based workflow for transaminase selection. [PDF]

open access: yesChem Sci
Rago AJ   +5 more
europepmc   +1 more source

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