Results 141 to 150 of about 75,325 (204)
Post‐Modification of Tripyrenylenes to Enantiopure π‐Extended D3‐Symmetric Propellers
The post‐modification of tripyrenylenes to π‐extended enantiopure propellers with tris‐phenanthrophenazines is presented and the chiroptical properties as well as the solid‐state packings investigated in comparison to the corresponding racemic mixtures.
Dennis Popp +8 more
wiley +1 more source
Force‐Induced Control of Circularly Polarized Luminescence With Rotaxane Architecture
Force‐induced reversible on/off switching of circularly polarized luminescence is achieved with a rotaxane‐based supramolecular mechanophore. The mechanophore, featuring a chiral helicene luminophore, is incorporated as a first network cross‐linker into a double‐network organogel.
Keigo Nonaka +10 more
wiley +2 more sources
Molecular basis and biological relevance of bacterial and plant pinoresinol/lariciresinol reductase specificities. [PDF]
Smith CA +7 more
europepmc +1 more source
The Pd‐catalyzed decarboxylative asymmetric protonation (DAP) has been developed for sterically hindered tetrahydro‐4H‐pyran‐4‐one derived α‐aryl‐β‐keto esters. A substrate scope of nine examples of DAP showed that substrates containing a di‐ortho methoxy substitution pattern on the aryl ring gave rise to the highest enantioselectivities of up to 85 ...
Fionn McNeill +5 more
wiley +1 more source
Treatment of 2‐tert‐butylpyrene with Cu2+ afforded structurally well‐defined pyrene oligomers, up to the 13‐mer. Single‐crystal X‐ray diffraction, spectroscopic analyses, and computational studies were conducted to evaluate the properties of the resulting oligopyrenes.
Md Jadu Mia +14 more
wiley +1 more source
Interaction-structure coupling enables high-flux enantioselective transport in lamellar membranes. [PDF]
Han S +6 more
europepmc +1 more source
Multicolumn Two-Dimensional Liquid Chromatography Screening Platform for Stereopeptidomics and Application to Antimicrobial Peptide Polyene and Lipopeptide. [PDF]
Knappe C +7 more
europepmc +1 more source
Borylcyclopropanes: Synthetic Strategies and Applications
Borylcyclopropanes (cyclopropanes bearing a boron substituent) sit at the intersection of two privileged frameworks in synthesis. This review provides the first exhaustive survey of their chemistry, spanning metal–carbene, nucleophilic cyclization, radical, hydroboration, and C─H activation routes, and documenting applications in medicinal chemistry ...
Aiza A. Butt, Joseph M. Ready
wiley +2 more sources
A machine learning-based workflow for transaminase selection. [PDF]
Rago AJ +5 more
europepmc +1 more source

