The asymmetric synthesis of (+)-sitophilure, the aggregation pheromone of Sitophilus oryzae L. and Sitophilus zeamais M., was carried out in 12 steps, 18% overall yield and 82% enantiomeric excess from the enzymatic reduction of methyl 3-oxopentanoate ...
Pilli Ronaldo A., Riatto Valéria B.
doaj
The structural transition between the two fully‐characterized states of a supramolecular helical hydrogen‐bonded polymer (represented as blue and light pink stacks) can be predictably varied over 85 K by changing the nature and amount of cosolvent; entropy of solvation (schematized as solvents of different sizes) is the main lever to tune the ...
Huanjun Kong +12 more
wiley +2 more sources
General phase diagram for antiferroelectric liquid crystals in dependence on enantiomeric excess [PDF]
Ewa Górecka +4 more
openalex +1 more source
Magnetic circular dichroism in Archean atmosphere and asymmetric photolysis of biomolecules: enantiomeric excess of prebiotic sugar. [PDF]
Sharma A.
europepmc +1 more source
Hydrothermal Decomposition of Amino Acids and Origins of Prebiotic Meteoritic Organic Compounds [PDF]
The organic compounds found in carbonaceous chondrite meteorites provide insight into primordial solar system chemistry. Evaluating the formation and decomposition mechanisms of meteoritic amino acids may aid our understanding of the origins of life and ...
Aponte, José C. +6 more
core +1 more source
Selected Ion Monitoring Using Low-Cost Mass Spectrum Detectors Provide a Rapid, General, and Accurate Method for Enantiomeric Excess Determination in High Throughput Experimentation [PDF]
Katerina M. Korch +5 more
openalex +1 more source
Properties of epoxide hydrolase from the yeast Rhodotorula glutinis [PDF]
Epoxide hydrolases are ubiquitous enzymes that can be found in nearly all living organisms. Some of the enzymes play an important role in detoxifying xenobiotic and metabolic compounds.
Ariës-Kronenburg, N.A.E.
core +1 more source
This brief compendium summarizes the most successful asymmetric hydrogenation strategies for the preparation of chiral monocyclic γ‐lactone derivatives from keto acids and keto esters, with emphasis on their relevance for large‐scale production and high enatioselectivities. This article provides a brief compendium on the production of chiral monocyclic
Marta Feliz, Maria J. Sabater
wiley +1 more source
Improved synthesis and comparative analysis of the tool properties of new and existing D-ring modified (S)-blebbistatin analogs [PDF]
Bracke, Marc +3 more
core +2 more sources
Helix Regulation of Poly(phenylacetylene)s through the Interplay between Enantiomeric Excess and Temperature-Triggered Pendant Isomerization. [PDF]
Wang D +10 more
europepmc +1 more source

