Results 11 to 20 of about 10,075 (214)
A note on the Noyori model for chiral amplification in the aminoalcohol-catalyzed reaction of aldehydes with dialkylzinc [PDF]
The Noyori model of chiral amplification in the alkylation of aldehydes by means of dialkylzinc, catalyzed by chiral aminoalcohols, is further elaborated.
Gutman Ivan
doaj +3 more sources
Importance of molecular symmetry for enantiomeric excess recognition by NMR [PDF]
Porphyrins with an exposed inner core N–H system respond to a chiral guest with exceptionally sensitive enantiomeric excess detection.
Karolis Norvaiša +5 more
openaire +2 more sources
Assembly of mesoscale helices with near-unity enantiomeric excess and light-matter interactions for chiral semiconductors [PDF]
Wenchun Feng +2 more
exaly +2 more sources
Numerous terpenes present in essential oils (EOs) display one or more chiral centers. Within the same genus the enantiomeric ratio of these compounds can be different. Thus, the determination of enantiomers is a valuable tool to evaluate authenticity and
Martina Allenspach +3 more
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2D Ising Model for Enantiomer Adsorption on Achiral Surfaces: L- and D-Aspartic Acid on Cu(111)
The 2D Ising model is well-formulated to address problems in adsorption thermodynamics. It is particularly well-suited to describing the adsorption isotherms predicting the surface enantiomeric excess, ees, observed during competitive co-adsorption of ...
Soham Dutta, Andrew J. Gellman
doaj +1 more source
Asymmetric Meerwein-Ponndorf-Verley reduction of long chain keto alkanoic acid methyl esters [PDF]
3-, 7- and 13-Monoketo tetradecanoic acid methyl esters carrying a keto group at the ends and at the middle of the chain with 14 carbon atoms were reduced by a Meerwein-Ponndorf-Verley reaction in the presence of R-(+)-1,1'-binaphthalene- 2,2'-diol, 1,2 ...
Onar Çelik Hülya +2 more
doaj +3 more sources
Background and Aims: Local anaesthetics are drugs that are widely used in clinical practice. However, the effects of these drugs on the neuromuscular junction and their influence on the blockade produced by non-depolarising neuromuscular blocking drugs ...
Angelica de Fátima de Assunção Braga +5 more
doaj +1 more source
Organocatalytic Properties of 3,4-Dihydroxyprolines
The synthesis and organocatalytic properties of (2S,3R,4R)-3,4-bis((tert-butyldimethylsilyl)oxy)pyrrolidine-2-carboxylic acid are reported. Using the aldol condensation of cyclohexanone with p-nitrobenzaldehyde as a model, a yield of 86%, an enantiomeric
Ramón J. Estévez +3 more
doaj +1 more source
The natural variability in the enantiomeric distribution of biologically active chiral terpenoids in Solidago canadensis L. essential oil from Kumaon was evaluated by enantioselective capillary GC, capillary GC, and GC-MS.
Chandan S. Chanotiya, Anju Yadav
doaj +1 more source
The volatile fraction of plant-based foods provides useful functional information concerning sample-related variables such as plant genotype and phenotype expression, pedoclimatic and harvest conditions, transformation/processing technologies, and can be
Federico Stilo +6 more
doaj +1 more source

