Results 11 to 20 of about 10,075 (214)

A note on the Noyori model for chiral amplification in the aminoalcohol-catalyzed reaction of aldehydes with dialkylzinc [PDF]

open access: yesJournal of the Serbian Chemical Society, 1999
The Noyori model of chiral amplification in the alkylation of aldehydes by means of dialkylzinc, catalyzed by chiral aminoalcohols, is further elaborated.
Gutman Ivan
doaj   +3 more sources

Importance of molecular symmetry for enantiomeric excess recognition by NMR [PDF]

open access: yesChemical Communications, 2022
Porphyrins with an exposed inner core N–H system respond to a chiral guest with exceptionally sensitive enantiomeric excess detection.
Karolis Norvaiša   +5 more
openaire   +2 more sources

Authenticity control of pine sylvestris essential oil by chiral gas chromatographic analysis of α-pinene

open access: yesScientific Reports, 2021
Numerous terpenes present in essential oils (EOs) display one or more chiral centers. Within the same genus the enantiomeric ratio of these compounds can be different. Thus, the determination of enantiomers is a valuable tool to evaluate authenticity and
Martina Allenspach   +3 more
doaj   +1 more source

2D Ising Model for Enantiomer Adsorption on Achiral Surfaces: L- and D-Aspartic Acid on Cu(111)

open access: yesEntropy, 2022
The 2D Ising model is well-formulated to address problems in adsorption thermodynamics. It is particularly well-suited to describing the adsorption isotherms predicting the surface enantiomeric excess, ees, observed during competitive co-adsorption of ...
Soham Dutta, Andrew J. Gellman
doaj   +1 more source

Asymmetric Meerwein-Ponndorf-Verley reduction of long chain keto alkanoic acid methyl esters [PDF]

open access: yesJournal of the Serbian Chemical Society, 2007
3-, 7- and 13-Monoketo tetradecanoic acid methyl esters carrying a keto group at the ends and at the middle of the chain with 14 carbon atoms were reduced by a Meerwein-Ponndorf-Verley reaction in the presence of R-(+)-1,1'-binaphthalene- 2,2'-diol, 1,2 ...
Onar Çelik Hülya   +2 more
doaj   +3 more sources

Effect of 50% enantiomeric excess bupivacaine mixture combined with pancuronium on neuromuscular transmission in rat phrenic nerve-diaphragm preparation; a pilot study

open access: yesIndian Journal of Anaesthesia, 2015
Background and Aims: Local anaesthetics are drugs that are widely used in clinical practice. However, the effects of these drugs on the neuromuscular junction and their influence on the blockade produced by non-depolarising neuromuscular blocking drugs ...
Angelica de Fátima de Assunção Braga   +5 more
doaj   +1 more source

Organocatalytic Properties of 3,4-Dihydroxyprolines

open access: yesChemistry Proceedings, 2023
The synthesis and organocatalytic properties of (2S,3R,4R)-3,4-bis((tert-butyldimethylsilyl)oxy)pyrrolidine-2-carboxylic acid are reported. Using the aldol condensation of cyclohexanone with p-nitrobenzaldehyde as a model, a yield of 86%, an enantiomeric
Ramón J. Estévez   +3 more
doaj   +1 more source

Natural Variability in Enantiomeric Composition of Bioactive Chiral Terpenoids in the Essential Oil of L. from Uttarakhand, India

open access: yesNatural Product Communications, 2008
The natural variability in the enantiomeric distribution of biologically active chiral terpenoids in Solidago canadensis L. essential oil from Kumaon was evaluated by enantioselective capillary GC, capillary GC, and GC-MS.
Chandan S. Chanotiya, Anju Yadav
doaj   +1 more source

Corylus avellana L. Natural Signature: Chiral Recognition of Selected Informative Components in the Volatilome of High-Quality Hazelnuts

open access: yesFrontiers in Plant Science, 2022
The volatile fraction of plant-based foods provides useful functional information concerning sample-related variables such as plant genotype and phenotype expression, pedoclimatic and harvest conditions, transformation/processing technologies, and can be
Federico Stilo   +6 more
doaj   +1 more source

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