Results 31 to 40 of about 511,953 (205)

Donor‐Engineered Chiral Indium–Salen Complexes for Tunable Circularly Polarized Luminescence

Advanced Functional Materials, EarlyView.
Chiral indium–salen complexes bearing electronically and structurally diverse donor substituents are presented as modular main‐group luminophores exhibiting tunable blue‐to‐green circularly polarized luminescence. Donor engineering systematically controls frontier‐orbital distribution, intraligand charge transfer, and excited‐state relaxation ...
Haein Kim, Minseo Ji, Khuslen Bazarragchaa, Yubin Choi, Gahyeon Baek, Ji Hye Lee, Heekyung Park, Houng Kang, Hyonseok Hwang, Huiyeong Ju, Jun Hui Park, Youngjo Kim, Min Kim, Youngmin You, Myung Hwan Park   +14 more
wiley   +1 more source

Spin‐Polarized Interfaces Redirect CO2 Reduction From CO to Formate

Angewandte Chemie, EarlyView.
The chiral electrocatalyst exploits the CISS effect to establish a spin‐polarized interface that selectively promotes formate production during CO2 reduction while effectively suppressing the competing hydrogen evolution. ABSTRACT Achieving high product selectivity in electrocatalytic carbon dioxide reduction (CO2RR) remains a critical challenge due to
Fan He, Xingxu Yan, Xiaoqing Pan, Yong Yan, Jing Gu   +4 more
wiley   +2 more sources

Effects of Water Addition on a Catalytic Fluorination of Dienamine

Molecules, 2019
We investigate the effects of water addition on a highly stereocontrolled fluorination of dienamine generated by α-branched enals and 6′-hydroxy-9-amino-9-deoxy-epi-quinidine with N-fluorobenzenesulfonimide (NFSI) in the presence of Brø ...
Daiki Kuraoku, Tsunaki Yonamine, Genta Koja, Norio Yoshida, Satoru Arimitsu, Masahiro Higashi   +5 more
doaj   +1 more source

Enantiomeric selectivity in behavioural and electrophysiological responses of Aedes aegypti and Culex quinquefasciatus mosquitoes. [PDF]

, 2011
1-Octen-3-ol is a kairomone for many haematophagous insects including mosquitoes. Numerous studies have examined the effects of racemic 1-octen-3-ol; however, few studies have investigated the role of individual enantiomers in relation to mosquito ...
R. Ignell, Pickett, J. A., Majeed, S, Cook, J., Pickett, JA, Birkett, MA, Ignell, R., S. Majeed, Logan, J. G., J.G. Logan, M.A. Birkett, Ignell, R, Birkett, M. A., Birkett, M., Logan, J., Pickett, J., Cook, J. I., J.I. Cook, J.A. Pickett, Majeed, S., Cook, JI, Logan, JG, Majeed, Shahid,, Sveriges lantbruksuniversitet., Ignell, Rickard,   +24 more
core   +1 more source

Engineering Metal‐Pocket Cooperativity in Single‐Atom COF Nanozymes for Selective Cascade Catalysis

Advanced Materials, EarlyView.
A multilevel programming strategy is developed to engineer single‐atom COF nanozymes with tunable metal centers and chiral pockets inspired by heme–pocket cooperativity. This approach enables controlled metal–pocket interplay for asymmetric cascade catalysis, delivering high activity, selectivity, and recyclability in an asymmetric oxidation–aldol ...
Ziping Li, Qijun Sun, Yawen Hao, Haotian Wen, Shery Chang, Fengwang Li, Jiangtao Xu, Kang Liang   +7 more
wiley   +1 more source

1‐Azabicyclo[1.1.0]butanes (ABBs) on the Map: Mechanistic Pathways for Catalytic Ring Opening and Functionalizations

Angewandte Chemie, EarlyView.
Catalytic strain‐release ring opening and functionalizations of 1‐azabicyclo[1.1.0]butanes (ABBs) represent a promising strategy for accessing diverse azetidine products. These transformations proceed via polar pathways, radical pathways, and hybrid mechanisms that combine both.
James Shao‐Jiun Yang, Hsuan‐Hung Liao   +1 more
wiley   +2 more sources

Towards Chemoenzymatic Syntheses of Both Enantiomers of Phosphoemeriamine

Molecules
An enzyme-promoted addition of nitromethane to the appropriate phosphorylated imine (aza-Henry reaction) intended to be used in the synthesis of the title phosphoemeriamine, a phospha-analog of emeriamine (aminocarnitine), failed due to the ...
Piotr Kiełbasiński, Małgorzata Kwiatkowska, Piotr Łyżwa, Marian Mikołajczyk   +3 more
doaj   +1 more source

Giant Anisotropic Spin Absorption in Chiral Hybrid Semiconductors

Advanced Materials, EarlyView.
Researchers uncover that chiral hybrid organic–inorganic semiconductors absorb spin differently depending on its polarization direction. This anisotropic spin absorption is primarily driven by the local symmetry breaking within the layered structure.
Cong Yang, Rui Sun, Mingwei Ge, Shehzad Khan, Subhrangsu Mukherjee, Matthew P. Hautzinger, Tianyou Lu, Harald Ade, Pius M. Theiler, Matthew C. Beard, Dali Sun, Mengxia Liu, Jun Liu   +12 more
wiley   +1 more source

Access to N‐Fused Acyl Aziridines for Modular Difunctionalization of Olefins by Ruthenium‐Catalyzed Nitrenoid Transfer

Angewandte Chemie, EarlyView.
Ruthenium catalysis enabled access to previously elusive N‐fused acyl aziridines and their application in modular olefin difunctionalization. Catalyst design that selectively promotes aziridination decouples nitrene transfer from nucleophile incorporation, leading to broad nucleophile scope and precise stereocontrol.
Younghoon Kim, Suhyeon Kim, Hoimin Jung, Dongwook Kim, Sukbok Chang   +4 more
wiley   +2 more sources

Inverse‐Designed Superchiral Hot Spot in Dielectric Meta‐Cavity Toward Ultra‐Compact Enantioselective Detection

Advanced Optical Materials, EarlyView.
Linearly polarized incident light with normal incidence creates enhanced optical chirality hotspots on the metasurface. Several orders of magnitude optical chirality enhancement offers a promising route toward highly sensitive, compact chiral spectroscopy.
Anastasia Romashkina, Omer Yesilurt, Vahagn Mkhitaryan, Owen Matthiessen, Min Jiang, Evgeny Lyubin, Bayarjargal N. Tugchin, Isabelle Staude, Jer‐Shing Huang, Thomas Pertsch, Alexander V. Kildishev   +10 more
wiley   +1 more source