Results 21 to 30 of about 511,953 (205)

Amino Acids in the Universe

open access: yesBIO Web of Conferences, 2014
What is the role played by amino acids in the chemistry of the interstellar medium and the emergence of life on the early Earth? Are they really the primary key compounds as free amino acids?
Guillemin J-C.
doaj   +1 more source

Theoretical Prediction and Experimental Verification of ees Versus Time in Biocatalytic Resolution and its Application in a Bioresolution-inversion Process

open access: yesMATEC Web of Conferences, 2015
A systematic theoretical derivation of bioresolution-inversion process was made. An equation was derived between the maximum ee value of final product (eef(max)) and enantiomeric ratio (E) of a reaction. The corresponding equations of conv.(max), eep(max)
Xu Yi, Zhou Dan, Chen Jianbo
doaj   +1 more source

Enantiomeric Excess Determination of Primary Amines

open access: yes, 2016
Certain organic compounds can exist in two variations, known as enantiomers. Such compounds are characterized as being “chiral”. Enantiomers can exist in either R or S configurations, and the relative proportions of one configuration to another can be ...
Ticatic, Jacylin   +1 more
core   +2 more sources

Nonnative Thiol and Aniline Methylation, Including Enantioselective Dithiol Desymmetrization, by Multicomponent Cobamide‐Dependent Methyltransferases Using Unactivated Methyl Donors

open access: yesAngewandte Chemie, EarlyView.
Mixed MtaABC/MtgABC methyltransferase systems were developed for non‐native thiol and aniline methylation using the unactivated methyl donors methanol and glycine betaine. The platform enabled site‐selective and enantioselective methylation with turnover number up to 6000, representing the first enantioselective non‐native catalysis by cobamide ...
Amardeep Kumar   +3 more
wiley   +2 more sources

Enantiomeric Tartaric Acid Production Using cis-Epoxysuccinate Hydrolase: History and Perspectives

open access: yesMolecules, 2019
Tartaric acid is an important chiral chemical building block with broad industrial and scientific applications. The enantioselective synthesis of l(+)- and d(−)-tartaric acids has been successfully achieved using bacteria presenting cis ...
Jinsong Xuan, Yingang Feng
doaj   +1 more source

Determining enantiomeric excess using indicator-displacement assays [PDF]

open access: yes, 2005
The invention includes an enantioselective indicator-displacement assay useful to determine enantiomeric excess (ee) enantiomeric samples calorimetrically.
Zhu, Lei   +2 more
core   +1 more source

Accurate Determination of Enantiomeric Excess Using Raman Optical Activity

open access: yes, 2022
The optical purity of a chiral sample is of particular importance to the analytical chemistry and pharmaceutical industries. In recent years, the vibrational optical activity (VOA) has become established as a sensitive and nondestructive technique for ...
Pavel Michal   +5 more
core   +1 more source

Homochiral Acyl Isocyanates as Diagnostic NMR Probes for the Enantiomeric Purity of Chiral Alcohols

open access: yesSultan Qaboos University Journal for Science, 2000
The first reported acyl and sulfonylisocyanates were developed and tested in reactions with chiral alcohols to afford diastereomeric carbamates. NMR analysis of these investigates the chemical shift discrimination that would allow these activated ...
Gregory H. P. Roos, Anthony R. Donovanb
doaj   +1 more source

Chemical Composition, Enantiomeric Distribution and Anticholinesterase and Antioxidant Activity of the Essential Oil of Diplosthephium juniperinum

open access: yesPlants, 2022
The aim of this study was to extract and identify the chemical compounds of Diplosthephium juniperinum essential oil (EO) from Ecuador and to assess its anticholinesterase and antioxidant properties. The EO chemical composition was determined by GC–MS. A
Melissa Salinas   +4 more
doaj   +1 more source

Determining enantiomeric excess using indicator-displacement assays [PDF]

open access: yes, 2007
The invention includes an enantioselective indicator-displacement assay useful to determine enantiomeric excess (ee) enantiomeric samples colorimetrically.
Folmer-Andersen, Jan Frantz   +2 more
core   +1 more source

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