Results 251 to 260 of about 3,272,143 (363)

Asymmetric Synthesis of Propargylic and Allenic Silanes, Germanes, and Stannanes

open access: yesChemistry – An Asian Journal, EarlyView.
Organotetrel compounds are important reagents with broad applications in chemical industries and natural product synthesis. This review provides a summary of strategies for the synthesis of propargylic and allenic organotetrels in their enantioenriched forms.
Hai Chang, Ruihan Wang, Yi‐Ming Wang
wiley   +1 more source

Reusable Selenenyl Iodide‐Initiated Cascade Cyclization of Polyenes with N‐terminating Groups

open access: yesChemistry – An Asian Journal, EarlyView.
A cascade cyclization of polyenes with N‑terminating groups, initiated by an isolable selenenyl iodide, was developed. The cavity‑shaped substituent stabilized both the selenenyl iodide and the selenenic acid generated via β‑selenoxide elimination, enabling the regeneration of selenenyl iodide.
Satoru Kuwano   +4 more
wiley   +1 more source

(R)‐ and (S)‐SbF3(C8H9NO3): Chiral Antimony‐Based Hybrid Materials with Enhanced Second‐Harmonic Generation and Birefringence

open access: yesChemistry – An Asian Journal, EarlyView.
We report two chiral NCS compounds, (R)‐Sb and (S)‐Sb, featuring aligned Sb3⁺ lone pairs and hydrogen‐bonded [SbOF₃] polyhedra with 4‐hydroxyphenylglycine. These structures exhibit strong SHG (2.6 × KDP), a wide band gap (4.19 eV), and suitable birefringence (0.184@546.1 nm), highlighting the potential of Sb3⁺‐based hybrids for NLO applications ...
Seoyeon Choi, Kang Min Ok
wiley   +1 more source

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