Results 221 to 230 of about 26,006 (279)
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Journal of the American Chemical Society, 2021
Selective hydrogenation of epoxides would be a direct and powerful approach for alcohol synthesis, but it has proven to be elusive. Here, electrochemically epoxide hydrogenation using electrons and protons as reductants is reported. A wide range of primary, secondary, and tertiary alcohols can be achieved through selective Markovnikov or anti ...
Cheng Huang +5 more
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Selective hydrogenation of epoxides would be a direct and powerful approach for alcohol synthesis, but it has proven to be elusive. Here, electrochemically epoxide hydrogenation using electrons and protons as reductants is reported. A wide range of primary, secondary, and tertiary alcohols can be achieved through selective Markovnikov or anti ...
Cheng Huang +5 more
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Journal of the American Chemical Society, 2008
Oxidation of graphite may be carried out by reaction with meta-chloroperoxybenzoic acid to yield graphite epoxide. Scanning tunneling microscopy (STM) showed that the functionalization occurs at the edges rather than on the basal plane of the graphite.
Jayanta, Chattopadhyay +8 more
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Oxidation of graphite may be carried out by reaction with meta-chloroperoxybenzoic acid to yield graphite epoxide. Scanning tunneling microscopy (STM) showed that the functionalization occurs at the edges rather than on the basal plane of the graphite.
Jayanta, Chattopadhyay +8 more
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Chemistry and Physics of Lipids, 2001
Previously unknown 4,5-epoxy-N-acetyl-sphingosine (1) was synthesized by epoxidation of N-acetyl-sphingosine with 1,1-dimethyldioxirane. A by-product generated by HPLC purification is the tetrahydrofuryl derivative of acetamide (2). Mainly allylic oxidation was observed when natural ceramides were reacted with dimethyldioxirane.
A, Möllenberg, G, Spiteller
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Previously unknown 4,5-epoxy-N-acetyl-sphingosine (1) was synthesized by epoxidation of N-acetyl-sphingosine with 1,1-dimethyldioxirane. A by-product generated by HPLC purification is the tetrahydrofuryl derivative of acetamide (2). Mainly allylic oxidation was observed when natural ceramides were reacted with dimethyldioxirane.
A, Möllenberg, G, Spiteller
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The interaction of cytosolic epoxide hydrolase with chiral epoxides
International Journal of Biochemistry, 19931. The kinetic parameters of the cytosolic epoxide hydrolase were examined with two sets of spectrophotometric substrates. The (2S,3S)- and (2R,3R)-enantiomers of 4-nitrophenyl trans-2,3-epoxy-3-phenylpropyl carbonate had a KM of 33 and 68 microns and a Vmax of 16 and 27 mumol/min/mg, respectively.
E C, Dietze, E, Kuwano, B D, Hammock
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Epoxidation of 4-Alkylidenecyclopentenones
Synlett, 2006AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.
Ahmar, Mohammed +2 more
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Epoxidations: Titanium‐Catalyzed Epoxidation
ChemInform, 2005AbstractFor Abstract see ChemInform Abstract in Full Text.
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Tetrahedron, 1964
Abstract New preparative routes to the 13α,17aα-epoxide (II) and the 13β,17aβ-epoxide (III) are described. Boron trifluoride in benzene converts the α-epoxide (II) into a mixture from which five products were isolated, but the β-epoxide (III) gives only the 17aβ-hydroxy-Δ8(14)-olefin (VIII).
J.M. Coxon, M.P. Hartshorn, D.N. Kirk
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Abstract New preparative routes to the 13α,17aα-epoxide (II) and the 13β,17aβ-epoxide (III) are described. Boron trifluoride in benzene converts the α-epoxide (II) into a mixture from which five products were isolated, but the β-epoxide (III) gives only the 17aβ-hydroxy-Δ8(14)-olefin (VIII).
J.M. Coxon, M.P. Hartshorn, D.N. Kirk
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Epoxidation of homoisoflavones
Journal of Heterocyclic Chemistry, 2003AbstractA comparative study of the epoxidation of homoisoflavones (3‐benzyl‐4‐chromones) 1–4 has been performed by various oxidizing agents, víz. Epoxidation with isolated dimethyldioxirane (Method A), with alkaline hydrogen peroxide (Method B), and with sodium hypochlorite (Method C) to obtain the epoxides 4–8.
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Proceedings of the 2015 ACM Conference on Special Interest Group on Data Communication, 2015
SDN opens a new chapter in network troubleshooting as besides misconfigurations and firmware/hardware errors, software bugs can occur all over the SDN stack. As an answer to this challenge the networking community developed a wealth of piecemeal SDN troubleshooting tools aiming to track down misconfigurations or bugs of a specific nature (e.g.
Tamás Lévai +3 more
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SDN opens a new chapter in network troubleshooting as besides misconfigurations and firmware/hardware errors, software bugs can occur all over the SDN stack. As an answer to this challenge the networking community developed a wealth of piecemeal SDN troubleshooting tools aiming to track down misconfigurations or bugs of a specific nature (e.g.
Tamás Lévai +3 more
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ChemInform, 1991
Publisher Summary The method for asymmetric epoxidation of alicyclic alcohols is known as Sharpless. The success of this method initiated much research into other techniques of asymmetric oxidation of alkenes in general and this chapter considers the progress in the area for the last six years.
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Publisher Summary The method for asymmetric epoxidation of alicyclic alcohols is known as Sharpless. The success of this method initiated much research into other techniques of asymmetric oxidation of alkenes in general and this chapter considers the progress in the area for the last six years.
openaire +1 more source

