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Valorization of CO2 through the Synthesis of Cyclic Carbonates Catalyzed by ZIFs
Molecules, 2022 One way to exploit CO2 is to use it as a feedstock for the production of cyclic carbonates via its reaction with organic epoxides. As far as we know, there is still no heterogeneous catalyst that accelerates the reaction in a selective, efficient and ...
José J. Delgado-Marín +5 more
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A straightforward approach towards combined α-amino and α-hydroxy acids based on Passerini reactions
Beilstein Journal of Organic Chemistry, 2011 Complex amino acids with an α-acyloxycarbonyl functionality in the side chain are easily available through epoxide opening by chelated enolates and subsequent oxidation/Passerini reaction. This protocol works with both, aldehyde and ketone intermediates,
Ameer F. Zahoor +2 more
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Molecules, 2019 Small ring heterocycles, such as epoxides and aziridines, are present in several natural products and are also highly versatile building blocks, frequently involved in the synthesis of numerous bioactive products and pharmaceuticals.
Allan Ribeiro da Silva +3 more
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Epoxides and Soluble Epoxide Hydrolase in Cardiovascular Physiology [PDF]
Physiological Reviews, 2012 Epoxyeicosatrienoic acids (EETs) are arachidonic acid metabolites that importantly contribute to vascular and cardiac physiology. The contribution of EETs to vascular and cardiac function is further influenced by soluble epoxide hydrolase (sEH) that degrades EETs to diols. Vascular actions of EETs include dilation and angiogenesis.
openaire +2 more sources
A model study of epothilone synthesis: an alternative synthetic approach to the C1C7 fragment [PDF]
Journal of the Serbian Chemical Society, 2002 In this model study an alternative synthetic approach to the C1C7 fragment of epothilones was investigated. Starting from 4,4-dimethylcyclopentenone, a 7 step reaction sequence afforded the key intermediate 7 in 27 % overall yield.
RADOMIR N. SAICIC +3 more
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NEW ROOM TEMPERATURE LIQUIDS: SYNTHESIS AND CHARACTERIZATION [PDF]
Chemistry Journal of Moldova: General, Industrial and Ecological Chemistry, 2007 Room temperature ionic liquids (ILs) have been recognized as a new generation of solvents for “green chemistry” and represent remarkably promising classes of technologically useful and fundamentally interesting materials [1-6].
Macaev Fliur +4 more
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Beilstein Journal of Organic Chemistry, 2012 Terminal epoxides undergo lithium 2,2,6,6-tetramethylpiperidide-induced α-lithiation and subsequent interception with Ph3P to provide a new and direct entry to β-lithiooxyphosphonium ylides.
David. M. Hodgson, Rosanne S. D. Persaud
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Molecules, 2012 Fullerene epoxides, C<sub>60</sub>O<sub>n</sub>, having epoxide groups directly attached to the fullerene cage, constitute an interesting class of fullerene derivatives.
Yusuke Tajima +3 more
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Über die Synthese neuer Epoxyverbindungen
CHIMIA, 1962 Firstly, the different types of epoxy compounds are considered : • Glycidyl ethers, esters, and amines. • Epoxydation products: a) linear aliphatic epoxides, epoxidised fatty acids and fatty acid derivatives and epoxidised polybutadienes; b ...
Hans Batzer, Erwin Nikles
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Synthesis of the calcilytic ligand NPS 2143
Beilstein Journal of Organic Chemistry, 2013 (R)-3 (NPS 2143) is a negative allosteric modulator of the human calcium-sensing receptor (CaSR) and as such represents an important pharmacological tool compound for studying the CaSR.
Henrik Johansson +4 more
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