Results 31 to 40 of about 15,949 (256)

A model study of epothilone synthesis: an alternative synthetic approach to the C1–C7 fragment [PDF]

open access: yesJournal of the Serbian Chemical Society, 2002
In this model study an alternative synthetic approach to the C1–C7 fragment of epothilones was investigated. Starting from 4,4-dimethylcyclopentenone, a 7 step reaction sequence afforded the key intermediate 7 in 27 % overall yield.
RADOMIR N. SAICIC   +3 more
doaj   +3 more sources

Über die Synthese neuer Epoxyverbindungen

open access: yesCHIMIA, 1962
Firstly, the different types of epoxy compounds are considered : • Glycidyl ethers, esters, and amines. • Epoxydation products: a) linear aliphatic epoxides, epoxidised fatty acids and fatty acid derivatives and epoxidised polybutadienes; b ...
Hans Batzer, Erwin Nikles
doaj   +1 more source

(NHC)Mn(I) complex catalyzed selective transfer hydrogenation of epoxides, azoarenes and nitroarenes utilizing ammonia borane [PDF]

open access: yes
Herein, we have reported an effective protocol for the regioselective transfer hydrogenation (TH) of epoxides by utilizing a phosphine-free bis-NHC-Mn(I) complex and ammonia borane. By employing this strategy, aromatic epoxides were selectively converted
Kanak Ranjan, Saha   +3 more
core   +2 more sources

Synthesis of the calcilytic ligand NPS 2143

open access: yesBeilstein Journal of Organic Chemistry, 2013
(R)-3 (NPS 2143) is a negative allosteric modulator of the human calcium-sensing receptor (CaSR) and as such represents an important pharmacological tool compound for studying the CaSR.
Henrik Johansson   +4 more
doaj   +1 more source

Scientific Opinion on Flavouring Group Evaluation 82, Revision 1 (FGE.82Rev1): Consideration of Epoxides evaluated by the JECFA (65th meeting) [PDF]

open access: yesEFSA Journal, 2014
The Panel on Food Contact Materials, Enzymes, Flavourings and Processing Aids of the European Food Safety Authority was requested to consider evaluations of flavouring substances assessed since 2000 by the Joint FAO/WHO Expert Committee on Food Additives
EFSA Panel on Food Contact Materials, Enzymes, Flavourings and Processing Aids (CEF)
doaj   +1 more source

Microbial transformation of epoxides.

open access: yes, 1998
Enantioselective degradation of racemic epoxides is an interesting method to obtain optically pure epoxides. In this review, an overview is presented on the bioconversion of epoxides in microorganisms.
Bont, J.A.M., de   +3 more
core   +1 more source

Iridium Catalyzed Deoxygenation of Epoxides with Carbon Monoxide [PDF]

open access: yes, 2019
This work describes the selective desoxygenation of epoxides to olefins using carbon monoxide as the reducing agent and an iridium pincer complex as the homogeneous catalyst.
Theo, Maulbetsch   +2 more
core   +2 more sources

Molecular Bridges for 2D Nanomaterials

open access: yesAdvanced Functional Materials, EarlyView.
Molecular cross‐linking provides a versatile strategy to engineer interfaces in 2D materials. By tuning the linker backbone, binding mode, and interflake spacing, molecular bridges can regulate charge transport, mechanical integrity, chemical functionality, and processing.
Yudhajit Bhattacharjee   +3 more
wiley   +1 more source

Cloning and application of epoxide hydrolases from yeasts [PDF]

open access: yes, 2002
Epoxides are cyclic ethers that readily react with various nucleophilic compounds. Consequently, epoxides can be used in many chemical synthesis reactions. Two enantiomeric forms of an epoxide are possible if one of the carbon atoms is chiral. This means
Visser, J.H.
core  

Ion exchange resin-mediated hydrolytic cleavage of epoxides. Simple one-pot synthesis of 2-arylketones from 1-aryl-1,2-epoxides

open access: yes, 1990
Epoxides are cleaved in an aqueous solution with Dowex-50W. Alicyclic epoxides are converted to trans-1,2-diols whereas 1-aryl-1,2-epoxides furnish 2-arylketones in excellent ...
Ranu, Brindaban C., Chakraborty, Rupak
core   +1 more source

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