Use of metal catalysts bearing Schiff base macrocycles for the ring opening polymerization (ROP) of cyclic esters [PDF]
© 2017 by the authors. Schiff base macrocycles are emerging as useful scaffolds for binding two or more catalytic metals in close proximity. Such coordination chemistry allows for the evaluation of potentially beneficial catalytic cooperative effects. In
Redshaw, Carl
core +2 more sources
AbstractThe introduction of ester groups on the 5‐ and 15‐meso positions of corroles stabilizes them against oxidation and induces a redshift of their absorption and emission spectra. These effects are studied through the photophysical and electrochemical characterization of up to 16 different 5,15‐diester corroles, in which the third meso position is ...
Canard, Gabriel +5 more
openaire +3 more sources
An Overview of CRISPR-Based Technologies in Wine Yeasts to Improve Wine Flavor and Safety
Modern industrial winemaking is based on the use of specific starters of wine strains. Commercial wine strains present several advantages over natural isolates, and it is their use that guarantees the stability and reproducibility of industrial ...
Alice Vilela
doaj +1 more source
Impact of Stabilization Method and Filtration Step on the Ester Profile of “Brandy de Jerez”
Brandy stabilization is an important step aimed at decanting the suspended organic and inorganic particles that may cause undesirable turbidity (cloudiness or haze) in brandies, affecting the physico-chemical stability, the organoleptic characteristics ...
José Manuel Muñoz-Redondo +4 more
doaj +1 more source
Descriptors for terpene esters from chromatographic and partition measurements: Estimation of human odor detection thresholds [PDF]
We have used gas chromatographic retention data together with other data to obtain Abraham descriptors for 30 terpene esters. These include the air-water partition coefficient, as log Kw, for which no experimental values are available for any terpene ...
Abraham, Michael H +2 more
core
A novel ruthenium complex binding to two subtly different aminophosphine ligands, (o-PPh2C6H4CH2NH2)(o-PPh2C6H4NH2)RuCl2, was successfully isolated. This bis(aminophosphine)–ruthenium complex shows efficient activity in both dimethyl oxalate (DMO) and ...
Xiaolong Fang +8 more
doaj +1 more source
Scientific Opinion on Flavouring Group Evaluation 20, Revision 4 (FGE.20Rev4): Benzyl alcohols, benzaldehydes, a related acetal, benzoic acids, and related esters from chemical groups 23 and 30 [PDF]
The Panel on Food Contact Materials, Enzymes, Flavourings and Processing Aids of the European Food Safety Authority was requested to evaluate 45 flavouring substances in the Flavouring Group Evaluation 20, Revision 4 (FGE.20Rev4), using the Procedure in ...
EFSA Panel on Food Contact Materials, Enzymes, Flavourings and Processing Aids (CEF)
doaj +1 more source
Cu/ZrO2 Catalyst Modified with Y2O3 for Effective and Stable Dehydration of Glycerol to Acetol
Glycerol is a main by-product of biodiesel production, and its further processing is essential for the biorefinery. In this paper, a highly active and stable catalyst for the catalytic dehydration of glycerol to acetol is obtained by modifying a Cu-Zr ...
Zhoubing Liang +5 more
doaj +1 more source
CO2 conversion to liquid fuels provides an appealing means to remove the greenhouse gas, although it is challenging to find materials that are both active and selective.
Wenchao Ma +8 more
doaj +1 more source
Solvent-Free Iron(III) Chloride-Catalyzed Direct Amidation of Esters
Amide functional groups are prominent in a broad range of organic compounds with diverse beneficial applications. In this work, we report the synthesis of these functional groups via an iron(iii) chloride-catalyzed direct amidation of esters.
Blessing D. Mkhonazi +4 more
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