Results 1 to 10 of about 9,491 (269)
Electrochemical oxidation-induced etherification via C(sp3)─H/O─H cross-coupling [PDF]
Science Advances, 2020 An electrochemical oxidation-induced C(sp3)─H etherification strategy by using nonsolvent alcohols has been disclosed. Direct electrochemical construction of C─O bonds through C(sp3)─H functionalization still remains fundamentally challenging.
Huamin Wang +5 more
semanticscholar +2 more sources
International Journal of Polymer Science, 2022 Although many studies are being actively conducted to develop biodegradable plastic materials, most of these reports focused more on efficiency or performance improvement than on the reaction mechanism. This paper discussed the reaction mechanism applied
Yongeun Kim, Cheolsoo Jung
doaj +2 more sources
Nucleophilic C-H Etherification of Heteroarenes Enabled by Base-Catalyzed Halogen Transfer.
Journal of the American Chemical Society, 2021 We report a general protocol for the direct C-H etherification of N-heteroarenes. Potassium tert-butoxide catalyzes halogen transfer from 2-halothiophenes to N-heteroarenes to form N-heteroaryl halide intermediates that undergo tandem base-promoted ...
Thomas R Puleo +2 more
semanticscholar +3 more sources
Microwave-Assisted Glycerol Etherification Over Sulfonic Acid Catalysts [PDF]
Materials, 2020 Glycerol is the main by-product of biodiesel production. For this reason, its valorization into value-added products, by using green procedures, represents an important goal.
L. Aguado-Deblas +5 more
semanticscholar +2 more sources
Pd-Catalyzed Etherification of Nitroarenes [PDF]
Organometallics, 2021 The Pd-catalyzed etherification of nitroarenes with arenols has been achieved using a new rationally designed ligand. Mechanistic insights were used to design the ligand so that both the oxidative addition and reductive elimination steps of a plausible catalytic cycle were facilitated.
Naoki Matsushita +3 more
semanticscholar +3 more sources
Etherification of Glycerol with Propylene or 1-Butene for Fuel Additives [PDF]
The Scientific World Journal, 2017 The etherification of glycerol with propylene over acidic heterogeneous catalysts, Amberlyst-15, S100, and S200 resins, produced mono-propyl glycerol ethers (MPGEs), 1,3-di- and 1,2-di-propyl glycerol ethers (DPGEs), and tri-propyl glycerol ether (TPGE).
Chakrapong Saengarun +2 more
doaj +2 more sources
Nature Communications, 2020 Since its discovery, the Hofer-Moest mechanism strongly limits the scope of electrochemical decarboxylative etherification. Here, the authors report the electrochemical conversion of carboxylic acids into alkyl benzotriazole ethers expanding the scope to
Ángel Manu Martínez +4 more
doaj +2 more sources
Energies, 2019 Biodiesel production has considerably increased in recent decades, generating a surplus of crude glycerol, which is the main drawback for the economy of the process.
Rafael Estevez +3 more
doaj +2 more sources
Promoting Effect of Ball Milling on the Functionalization and Catalytic Performance of Carbon Nanotubes in Glycerol Etherification [PDF]
MoleculesA facile and eco-friendly approach using in situ-generated 4-benzenediazonium sulfonate (BDS) was applied to prepare highly functionalized carbon nanotubes (CNTs). The effectiveness of this functionalization was additionally enhanced by a green and short-
Karolina Ptaszyńska +4 more
doaj +2 more sources