Influence of Asymmetry on the Molecular and Electronic Structures of μ‐Oxo Diferric Complexes
The 6‐methyl substituents at the pyridines (shown in red) enforce longer MNpy bonds than without them (shown in green).The asymmetric dinucleating susanH2Me2 is used for the synthesis of a μ‐oxo diferric complex. Comparison to the two symmetric complexes of susan and susan6−Me shows a strong effect on the redox potentials.
Sören Jansen +4 more
wiley +1 more source
Ferrocenyl ferroptosis inducers as an emerging class of anticancer agents: a mini review. [PDF]
Klarek M, Gautam A, Kowalski K.
europepmc +1 more source
Copper‐Catalyzed Markovnikov Hydroboration of Alkenes via Hydrogen Atom Transfer (MHAT)
The copper‐catalyzed Markovnikov hydroboration of alkenes is disclosed. Remarkably, this methodology operates at mild reaction conditions and delivers high catalytic efficiency (TONs and TOFs up to 2800 and 2600 h‐1, respectively). Furthermore, this approach diverges from previous reports by relying on two subsequent hydrogen‐atom‐transfer processes ...
Antonio Torres‐Calis +1 more
wiley +1 more source
1-Azinyl-1'-Alkenylferrocenes with Anticholinesterase, Antioxidant, and Antiaggregating Activities as Multifunctional Agents for Potential Treatment of Alzheimer's Disease. [PDF]
Makhaeva GF +15 more
europepmc +1 more source
A Wearable, Dual Closed‐loop Insulin Delivery System for Precision Diabetes Management
A wearable dual closed‐loop drug delivery system for diabetes management is presented, featuring an adaptive, on‐body trained edge AI algorithm for precise insulin delivery, which enhances therapeutic accuracy from 92.10% to 98.82%. Abstract Effective blood glucose management is an increasing demand worldwide.
Xuecheng He +12 more
wiley +1 more source
Construction of remote dual stereocenters by electrochemical cobalt-catalyzed enantioselective desymmetrization. [PDF]
Li Y +4 more
europepmc +1 more source
Herein, we report a novel ferrocenyldithiophosphonate functional conducting polymer and its use as an immobilization matrix in amperometric biosensor applications. Initially, 4-(2,5-di(thiophen-2-yl)-1H-pyrrol-1-yl)amidoferrocenyldithiophosphonate was synthesized and copolymerized with 4-(2,5-di(thiophen-2-yl)-1H-pyrrol-1-yl)benzenamine at graphite ...
Ayranci, R +3 more
openaire +2 more sources
Ferroelectrics Hybrids: Harnessing Multifunctionality of 2D Semiconductors in the Post‐Moore Era
In this Review, the state of art of ferroelectric hybrid systems—combining ferroelectrics, 2D semiconductors, and molecular switches is presented—as next‐generation platforms for high‐density, multifunctional electronics. By discussing 2D FeFET applications, nanoscale material downscaling, M3D integration, and emerging ferroelectrics, it highlights ...
Haixin Qiu +3 more
wiley +1 more source
Zero-current chronopotentiometry for wired biosensors. [PDF]
Nonis A, Damala P, Bakker E.
europepmc +1 more source
Recent Advances in Mediator and Proton Relay Usage in Molecular Catalysis
The use of electron–proton transfer mediators, redox mediators, and proton relays in synergy with molecular catalysts in energy‐related small‐molecule and organic transformations is discussed, with a focus on recent advances. Linear free‐energy relationship and catalytic Tafel plots provide a systematic foundation for benchmarking these catalytic ...
Yu‐Lin Chi +3 more
wiley +1 more source

