Results 71 to 80 of about 53,639 (282)

Orbital and spin magnetic moments of transforming 1D iron inside metallic and semiconducting carbon nanotubes

open access: yes, 2012
The orbital and spin magnetic properties of iron inside transforming metallic and semiconducting 1D carbon nanotube hybrids are studied by means of local x-ray magnetic circular dichroism (XMCD) and bulk superconducting quantum interference device (SQUID)
Ayala, Paola   +9 more
core   +2 more sources

Methyl 2-(4-ferrocenylbenzamido)thiophene-3-carboxylate and ethyl 2-(4-ferrocenylbenzamido)-1,3-thiazole-4-acetate, a unique ferrocen [PDF]

open access: yes, 2005
The conformations and hydrogen bonding in the thiophene and thiazole title compounds, [Fe(C₅H₅)(C₂₀H₁₄NO₃S)], (I), and [Fe(C₅H₅)(C₁₉H₁₇N₂O₃S)], (II), are discussed.
Alley, Steven   +4 more
core   +1 more source

TADF‐Emitting Dendrimers for Scalable Bar‐Coating Fabrication of Light‐Emitting Electrochemical Cells

open access: yesAdvanced Materials Technologies, EarlyView.
TADF‐emitting dendrimers promise to enable scalable solution‐based fabrication of efficient electroluminescent devices by the virtue of an attractive set of properties. Here, we report on how light‐emitting electrochemical cells, comprising the TADF‐dendrimer tBuCz2m2pTRZ, can be fabricated by scalable bar‐coating under ambient air and deliver uniform ...
Shi Tang   +5 more
wiley   +1 more source

Síntese de heterociclos bioativos derivados do ferroceno Synthesis of bioactive heterocyclic ferrocene derivatives

open access: yesQuímica Nova, 2013
The discovery of ferrocene marked one of the points of departure for modern organometallic chemistry. In general, the compounds of ferrocene derivatives are widely applied in several areas.
Claudio M. P. Pereira   +2 more
doaj  

New ferrocene-derived hydroxymethylphosphines: FcP(CH₂OH)₂ [Fc=(η⁵-C₅H₅)Fe(η⁵-C₅H₄)] and the dppf analogue 1,1′-Fc′[P(CH₂OH)₂]₂ [Fc′=Fe(η⁵-C₅H₄)₂] [PDF]

open access: yes, 2001
Reactions of the ferrocene-phosphines FcPH₂ and 1,1′-Fc′(PH₂)₂ with excess formaldehyde gives the new hydroxymethylphosphines FcP(CH₂OH)₂ 1 and 1,1′-Fc′[P(CH₂OH)₂]₂ 2, respectively. Phosphine 1 is an air-stable crystalline solid, whereas 2 is isolated as
Alley, Steven R., Henderson, William
core   +2 more sources

Bay‐functionalized [7]Helicene Bilayer Nanographenes

open access: yesAdvanced Optical Materials, EarlyView.
Bay‐functionalized [7]helical bilayer nanographenes are synthesized via a scalable, modular strategy enabling late‐stage diversification. Tailored methoxy, diketone, and phenazine substitutions precisely tune redox, photophysical, and chiroptical properties, delivering strong electronic circular dichroism and bright circularly polarized luminescence ...
Anmol Thanai   +9 more
wiley   +1 more source

Electron-Transfer Properties of Phenyleneethynylene Linkers Bound to Gold via a Self-Assembled Monolayer of Molecular Tripod

open access: yesMolecules, 2018
The three-point adsorption of tripod-shaped molecules enables the formation of robust self-assembled monolayers (SAMs) on solid surfaces, where the component molecules are fixed in a strictly upright orientation.
Toshikazu Kitagawa   +5 more
doaj   +1 more source

Gaussian Decoherence and Gaussian Echo from Spin Environments [PDF]

open access: yes, 2006
We examine an exactly solvable model of decoherence -- a spin-system interacting with a collection of environment spins. We show that in this simple model (introduced some time ago to illustrate environment--induced superselection) generic assumptions ...
Cucchietti, F. M.   +2 more
core   +1 more source

Bucky ferrocene. Hybrid of ferrocene and fullerene [PDF]

open access: yesPure and Applied Chemistry, 2003
Abstract The idea of “bucky ferrocene” intrigues chemists owing to its aesthetic beauty and to its polarized, extended conjugated system, but the idea has remained hypothetical. The synthesis of close analogs of Fe(C60Me5)Cp and Fe(C70Me3)Cp was achieved in two steps from [60] and [70]fullerenes, relying on an oxidative C–H bond ...
openaire   +1 more source

Donor‐Substituted C(sp3)‐Bridged Phosphorus‐Heterotriangulenes as Blue Thermally Activated Delayed Fluorescence Emitters

open access: yesAdvanced Optical Materials, EarlyView.
The newly developed regioselective strategy for the para‐functionalization of C(sp3)‐bridged phosphorus‐centered heterotriangulene delivers a series of donor‐acceptor emitters exhibiting thermally activated delayed fluorescence. The carbazole‐substituted compounds feature a unique combination of high photoluminescence quantum yields up to 75%, deep ...
Maximilian Schöner   +8 more
wiley   +1 more source

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