Results 121 to 130 of about 92,954 (262)

The Electronic Spin State of Diradicals Obtained from the Nuclear Perspective: The Strange Case of Chichibabin Radicals

open access: yesChemPhysChem, Volume 26, Issue 6, March 15, 2025.
The electronic spin state of two Chichibabin radicals is investigated using 2‐dimensional hyperfine correlated Electron Nuclear Double Resonance. The protons (I=1/2) act as a reference for the electronic spin quantum number (S) via their hyperfine interactions.
Gabriel Moise   +7 more
wiley   +1 more source

A Thermally Robust Luminescent Antimony Halide for Real‐Time Detection of Volatile Iodine at Elevated Temperatures

open access: yesEcoEnergy, EarlyView.
Zero‐dimensional antimony halides drive efficient iodine capture through electron transfer and display rapid fluorescence quenching at 75°C (348 K), establishing the first luminescent sensor for real‐time I2 detection at elevated temperatures. ABSTRACT Real‐time monitoring of volatile molecular iodine (I2), a hazardous radioactive byproduct of nuclear ...
Ying Jiang   +13 more
wiley   +1 more source

Metal‐Free Ligand‐Centered Radical Scavenging in Pyridine‐Modified Tetraaza Macrocycles

open access: yesEuropean Journal of Organic Chemistry, EarlyView.
Ligand‐centered hydrogen‐atom transfer in pyridinophane macrocycles generates delocalized radicals, with Py2N2 enabling cooperative captodative stabilization and enhanced DPPH• quenching. Pyridine‐modified tetraaza macrocycles are widely studied as ligand platforms for metal coordination, yet their intrinsic redox and radical reactivity in the absence ...
Christina Mantsorov   +9 more
wiley   +1 more source

Advances in Anthocyanin Recovery and Purification From Natural Sources: Bioavailability, Mechanistic Action in the Human Body and Applications in Novel Food Development

open access: yesFood Chemistry International, EarlyView.
This review highlights green recovery, purification, stabilisation, bioavailability, health relevance, and novel food applications of anthocyanins from natural and agro‐industrial sources. ABSTRACT Anthocyanins are water‐soluble natural pigments and multifunctional food ingredients that support clean‐label colour, antioxidant activity, and value‐added ...
Chandan Kumar Sahu   +4 more
wiley   +1 more source

Organic photonic synaptic transistors for bionic vision: From spectral engineering to flexible intelligent perception

open access: yesFlexMat, EarlyView.
Different wavelength photonic synapses are used for biomimetic visual applications. Abstract Bionic intelligent visual perception systems have significant application prospects in fields such as autonomous driving and robotics, medical imaging and auxiliary diagnosis, security and monitoring.
Longlong Jiang   +6 more
wiley   +1 more source

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