Results 41 to 50 of about 25,797 (319)

Recent Advances in Homogeneous Metal-Catalyzed Aerobic C–H Oxidation of Benzylic Compounds [PDF]

open access: yes, 2018
Csp(3)-H oxidation of benzylic methylene compounds is an established strategy for the synthesis of aromatic ketones, esters, and amides. The need for more sustainable oxidizers has encouraged researchers to explore the use of molecular oxygen.
Domínguez Pérez, Pilar Esther   +3 more
core   +2 more sources

Flash Pyrolysis – Synthetic and Mechanistic Aspects

open access: yesCHIMIA, 1977
Some examples of synthetically useful flash pyrolysis reactions are presented, and the reaction mechanisms are discussed. Cyanocyclopentadienes, -indenes, and -pyrroles are produced by pyrolysis of the appropriate triazoloarenes or isatins, or as the ...
Curt Wentrup
doaj   +1 more source

Strength of π-Stacking, from Neutral to Cation: Precision Measurement of Binding Energies in an Isolated π-Stacked Dimer [PDF]

open access: yes, 2018
π-Stacking interactions are ubiquitious across chemistry and biochemistry, impacting areas from organic materials and photovoltaics to biochemistry and DNA.
Cai, Jin-Zhe   +5 more
core   +4 more sources

Synthesis and Properties of Benzo-Fused Indeno[2,1-c]fluorenes.

open access: yesChemistry - An Asian Journal, 2019
A set of fully-conjugated indenofluorenes has been synthesized and confirmed by solid-state structure analysis. The indeno[2,1-c]fluorenes and their benzo-fused analogues all contain the antiaromatic as-indacene core.
Tanguy Jousselin-Oba   +8 more
semanticscholar   +1 more source

Straightforward Synthesis of Dihydrobenzo[a]fluorenes through Au(I)-Catalyzed Formal [3 + 3] Cycloadditions [PDF]

open access: yes, 2012
Dihydrobenzo[a]fluorene derivatives have been prepared by a formal intramolecular [3 + 3] cycloaddition of o-alkynylstyrenes bearing a secondary alkyl group at the β-position of the styrene moiety.
Fernández Rodríguez, Manuel A.   +4 more
core   +1 more source

Shellfish Tissue Monitoring in Piscataqua Region Estuaries 2013 [PDF]

open access: yes, 2013
Originally conducted by the Gulf of Maine Council on the Marine Environment from 1993 to 2011, the Gulfwatch Program examined trends in the water quality of the Gulf of Maine by monitoring toxic contaminant concentrations in the tissues of shellfish ...
Trowbridge, Philip R., Wood, Matthew A.
core   +4 more sources

Bioactive fluorenes. part I. Synthesis, pharmacological study and molecular docking of novel dihydrofolate reductase inhibitors based-2,7-dichlorofluorene

open access: yesHeliyon, 2019
In this study, a new series of 2,7-dichloro-4-(2-substituted-amino acetyl)fluorene derivatives were synthesized, characterized and evaluated for their antimicrobial activity and screened for cytotoxic activity against human lung carcinoma (A-549) and ...
Essam M. Hussein   +6 more
doaj   +1 more source

Diatom aggregation when exposed to crude oil and chemical dispersant: Potential impacts of ocean acidification.

open access: yesPLoS ONE, 2020
Diatoms play a key role in the marine carbon cycle with their high primary productivity and release of exudates such as extracellular polymeric substances (EPS) and transparent exopolymeric particles (TEP). These exudates contribute to aggregates (marine
Jennifer L Genzer   +6 more
doaj   +1 more source

Vicinal Dichlorination of o-Vinylbiphenyls and the Synthesis of 9-(Arylmethyl)fluorenes via Tandem Friedel–Crafts Alkylations

open access: yesSynthesis, 2019
Reacting ortho-vinylbiphenyls with (dichloroiodo)benzene (PhICl2) gives vicinal dichlorides, rapidly, and in excellent yield at room temperature. Treating the vic-dichlorides with 50 mol% AlCl3 in the presence of arene nucleophiles results in sequential ...
Zhensheng Zhao   +2 more
semanticscholar   +1 more source

Ladder‐Type Benzene‐Perylene Dyes with Efficient Laser Properties in the Near‐IR by Detracting/Activating Low/High Frequency Vibronic Modes

open access: yesAdvanced Functional Materials, EarlyView.
The NNR‐n series of oligomeric nanographenes delivers exceptional emission performance. This work shows that this performance is originated by their ladder‐type structure, which effectively deactivates low‐frequency vibronic modes. This deactivation neglects the main pathway for non‐emissive deactivation, even in the near‐infrared region. The potential
Marcos Díaz‐Fernández   +12 more
wiley   +1 more source

Home - About - Disclaimer - Privacy