Results 191 to 200 of about 316,859 (287)

Photonic time crystals assisted by quasi-bound states in the continuum. [PDF]

open access: yesSci Adv
Garg P   +10 more
europepmc   +1 more source

Evolutionäre, funktionelle und mechanistische Charakterisierung mikrobieller Terpensynthase‐ähnlicher Gene aus Springschwänzen

open access: yesAngewandte Chemie, EarlyView.
Eine Genomanalyse zeigte das Vorkommen zahlreicher Terpensynthasen des bakteriellen Typs in Springschwänzen. Vier Enzyme aus Sinella curviseta wurden funktionell charakterisiert, was zur Isolierung mehrerer Verbindungen führte, darunter Sinellenether, der erste identifizierte Diterpenether einer Terpensynthase mit einem neuartigen Grundgerüst.
Min Wang   +5 more
wiley   +1 more source

CO‐Adsorption auf MgO in neuem Licht: polarisationsaufgelöste Infrarotspektroskopie identifiziert Stufenkanten als dominierende Defekte auf MgO(100) und MgO(110)

open access: yesAngewandte Chemie, EarlyView.
Durch die Kombination von polarisationsaufgelöster IRRAS mit hybriden HSE06‐DFT‐Berechnungen ermitteln wir platzspezifische Schwingungsfingerabdrücke, Adsorptionsgeometrien und Bindungsenergien für CO auf MgO‐Oberflächen mit großer Bandlücke. Niedrig koordinierte Mg4c2+‐Stufenkantenplätze werden anstelle von Schottky‐Defekten auf Terrassen als die ...
Wangtao Li   +9 more
wiley   +1 more source

mRNA therapy improves the composition and motility in CCDC40-deficient cilia in vitro and in vivo. [PDF]

open access: yesAm J Respir Cell Mol Biol
Wohlgemuth K   +24 more
europepmc   +1 more source

Heavy‐Atom Tunneling at Room Temperature Revealed by Instanton Theory

open access: yesAngewandte Chemie, EarlyView.
Usually, tunneling does not play a significant role in chemical reactions except at low temperature, especially when heavy atoms are involved. However, using nonadiabatic instanton theory we find that heavy‐atom tunneling dominates the reaction mechanism for spin‐forbidden processes in the synthesis of strained organic molecules even at room ...
Debaarjun Mukherjee   +2 more
wiley   +1 more source

Functional and omics-based rationale for the induction of BRCAness by androgen receptor pathway inhibitors to sensitize prostate cancer to PARP inhibition, regardless of HRR status. [PDF]

open access: yesBr J Cancer
Elsesy ME   +17 more
europepmc   +1 more source

Post‐Synthetic Zinc Modifications to Correct Speciation in Ti‐MWW Zeolites for Catalytic Oxidation

open access: yesAngewandte Chemie, EarlyView.
Post‐synthetic Zn modifications of Ti‐MWW zeolite catalysts exhibit improved catalytic properties in the selective oxidation reaction, namely the ammoximation reaction. The origin of the beneficial effect of Zn is related via an array of spectroscopic and microscopic techniques to the modification of extra‐framework TiO2 and TiOx clusters and the ...
Christoph J. Kaul   +10 more
wiley   +1 more source

[Radiological postgraduate training-Current and future directions]. [PDF]

open access: yesRadiologie (Heidelb)
Molwitz I, See E, Nikolaou K, Bamberg F.
europepmc   +1 more source

Key Drivers of Activity and Selectivity in Cu‐Based Catalysts for Methanol Synthesis From CO2: Insights From Atomically Dispersed Promoters

open access: yesAngewandte Chemie, EarlyView.
Mechanistic studies on model Cu─M/SiO2 catalysts (M = Zn, Ga, and In) reveal that promoters enable a formate spillover pathway from Cu to Mn+ (n = 2 or 3) sites. The promoter's electronic effect on formate bond strengths serves as a quantitative descriptor for activity and selectivity, balancing spillover dynamics with intermediate stabilization to ...
Nat Phongprueksathat   +6 more
wiley   +1 more source

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