Results 141 to 150 of about 197,879 (225)

On the Mechanism of Soft Self‐assembly from Melt: The ubiquitous Heat Capacity Hump and Spontaneous Melt Chirality

Angewandte Chemie International Edition, Accepted Article.
We investigate two unusual phenomena in self‐assembly of anisotropic molecules from isotropic (Iso) melt: a heat‐capacity (Cp) maximum, and spontaneous formation of the recently discovered chiral liquid (Iso*). Based on experiments on new non‐chiral monomers, dimers and polymers, we construct a statistical theory that shows why many complex ...
Yi-nan Xue, Xiang-bing Zeng, Bo-wen Wu, Ya-xin Li, Liliana Cseh, Shu-gui Yang, Jie Liu, Gillian Gehring, Feng Liu, Goran Ungar   +9 more
wiley   +1 more source

Reactivity of Pnictaalumenes towards 1,3‐Dipole Molecules

Angewandte Chemie International Edition, Accepted Article.
Alkynes undergo 1,3‐dipolar cyclisation reactions with organic azides giving 1,2,3‐triazoles. Pnictaalumenes RPn=AlRˈ are the isoelectronic congeners of alkynes, hence a similar reactivity towards 1,3‐dipole molecules is expected. Herein, we report the reactions of DippTerPn=AlCp* (DippTer = 2,6‑(2,6‐iPr2C6H3)‐C6H3, Cp* = [Me5C5]−, Pn = P, As) towards ...
Tim Wellnitz, Edgar Zander, Leonie Wüst, Jakob Boardman, Max Neubauer, Samuel Nees, Holger Braunschweig, Christian Hering-Junghans   +7 more
wiley   +1 more source

What is rheumatoid factor? From screening to personalized management. [PDF]

Rheumatology (Oxford)
Tanaka Y.
europepmc   +1 more source

Comparative Structure Activity Relationship Characterization of the Biosimilar BAT1806/BIIB800 to Reference Tocilizumab. [PDF]

BioDrugs
Liu Y, Xie J, Li Z, Mei X, Cao D, Li S, Engle L, Liu S, Ebbers HC, Liu C.   +9 more
europepmc   +1 more source

Sequence Control in Sulfur‐Containing Ring‐Opening Co‐ and Terpolymerisations

Angewandte Chemie International Edition, Accepted Article.
Sulfur‐containing polymers uniquely expand the catalogue of accessible material properties compared to current commodity materials, yet their synthesis remains underdeveloped. Combining sulfur‐ and oxygen‐containing monomers in ring‐opening copolymerisation leads to a reshuffling reaction of the sulfur centres, which has been challenging to control — a
Bhargav R. Manjunatha, Cesare Gallizioli, Christoph Fornacon-Wood, Jenny Stephan, Merlin R. Stühler, Alex Johannes Plajer   +5 more
wiley   +1 more source

A novel <i>in vitro</i> serum stability assay for antibody therapeutics incorporating internal standards. [PDF]

MAbs
Li Y, Villafuerte-Vega R, Shenoy VM, Jackson HM, Wang Y, Parrish KE, Jenkins GJ, Sarvaiya H.   +7 more
europepmc   +1 more source

Characterization of Anti-Emicizumab Antibodies Using Repository Samples Obtained in Clinical Studies of Emicizumab Conducted in Japan. [PDF]

TH Open, 2023
Matsumoto N, Abe H, Kawasaki R, Tashiro Y, Noguchi-Sasaki M, Harada S, Yoneyama K, Niino T, Soeda T, Yoshimura Y.   +9 more
europepmc   +1 more source

Promoting Alkane Binding: Crystallization of a Cationic Manganese(I)‐Pentane σ‐Complex from Solution

Angewandte Chemie International Edition, Accepted Article.
Transition metal–alkane σ‐complexes are key intermediates in C‐H activation and, until now, analysis of these species has been restricted to either the solution OR the solid state. Here we present a synthetic methodology that converts Mn2(CO)10 in a non‐coordinating solvent environment to [Mn(CO)5]+ at room temperature, and this species binds n‐pentane
Malte Sellin, James Duncan Watson, Julia Fischer, Graham Edwin Ball, Leslie David Field, Ingo Krossing   +5 more
wiley   +1 more source

Rheumatoid factors revisited in the age of biologic therapy. [PDF]

Rheumatology (Oxford)
Avci AB, Feist E, Burmester GR.
europepmc   +1 more source

Uniaxial Stretching of Biodegradable Poly(Butylene Succinate‐Co‐Adipate) Films Filled With Silane‐Treated Wollastonite: Processing and Performance Evaluation

Journal of Applied Polymer Science, EarlyView.
Biobased poly(butylene succinate‐co‐adipate) films filled with silane‐treated wollastonite were engineered using blown film extrusion followed by uniaxial stretching. The tensile strength and moisture barrier properties of 15% filled films improved by approximately 213% and 12%, respectively, after uniaxial stretching.
Debarshi Nath, Manjusri Misra, Amar K. Mohanty   +2 more
wiley   +1 more source