Results 211 to 220 of about 121,959 (273)

Ion–Dipole Interaction‐Driven Assembly of Silicate Cages

open access: yesAggregate, EarlyView.
On the basis of ion–dipole interactions, silicate cages containing R[SiO4]− units can directionally bind K+ ions, thereby constructing frameworks with specific topologies. This strategy effectively addresses the challenges of strong solvation and non‐directional binding.
Yutao Guan   +5 more
wiley   +1 more source

Immunoglobulin: unraveling its complex web in aging. [PDF]

open access: yesFront Immunol
Gu Q   +7 more
europepmc   +1 more source

Cooperative Construction of Silver(I) Nanoclusters of Primary–Tertiary Diphosphine Directed by Thiolate Templates Through Ligand Metathesis

open access: yesAggregate, EarlyView.
By introducing a novel dual‐exchange strategy, we successfully synthesized Ag34 nanoclusters using thiolate templates and a hybrid chelator 2‐Ph2PC6H4PH2 containing both primary and tertiary phosphine. The approach results in thermodynamically stable nanoclusters with remarkable near‐infrared photoluminescence properties.
Xu‐Yang Ding   +6 more
wiley   +1 more source

Deciphering Ball Milling Mechanochemistry via Molecular Simulations of Collision‐Driven and Liquid‐Assisted Reactivity

open access: yesAngewandte Chemie, EarlyView.
Supported by experiments, molecular dynamics simulations were developed to reveal how mechanochemical reactions, such as between KCl and 18‐crown‐6 with water as a liquid additive, proceed. Product formation is triggered by collision‐induced fragmentation, with liquid content showing a non‐linear effect.
Rupam Gayen   +5 more
wiley   +2 more sources

Promotion of 5‐hydroxymethylfurfural synthesis from glucose over AlCl3 catalyst with choline chloride

open access: yesAIChE Journal, EarlyView.
Abstract Efficient production of 5‐hydroxymethylfurfural (HMF) from glucose was achieved in a water‐methyl isobutyl ketone biphasic solvent system over AlCl3 catalyst, using a green and cheap choline chloride (ChCl) salt as a promoter. An optimized HMF yield of 67% was obtained from 0.6 M glucose over 0.06 M AlCl3 with 3.8 M ChCl addition at 140°C ...
Chencong Ruan, Hero Jan Heeres, Jun Yue
wiley   +1 more source

Self‐Assembly, Rearrangement, and Disassembly of {Cr6} Horseshoe Oligomers

open access: yesAngewandte Chemie, EarlyView.
Using a combination of ion mobility mass spectrometry (IM‐MS), tandem mass spectrometry (MS2), and low‐temperature scanning tunneling microscopy (STM), we elucidate the self‐assembly, rearrangement, and disassembly processes of polymetallic {Cr6}x (x = 1 – 5) horseshoe oligomers.
Niklas Geue   +8 more
wiley   +2 more sources

Designing Memristive Materials for Artificial Dynamic Intelligence

open access: yesAdvanced Intelligent Discovery, EarlyView.
Key characteristics required of memristors for realizing next‐generation computing, along with modeling approaches employed to analyze their underlying mechanisms. These modeling techniques span from the atomic scale to the array scale and cover temporal scales ranging from picoseconds to microseconds. Hardware architectures inspired by neural networks
Youngmin Kim, Ho Won Jang
wiley   +1 more source

Dynamics of Metal–Metal Bond Dissociation in Pd–Pd and Ni–Ni Complexes: Reorganization and Redistribution Reactions of the Metalloradicals

open access: yesAngewandte Chemie, EarlyView.
PNP‐stabilized dinuclear [PdI]2 and [NiI]2 complexes with unsupported metal–metal bonds may serve as reservoir forms for homolytically generated metalloradical species, and a quantitative investigation of the metal–metal bond dissociation dynamics has been achieved.
Tim Bruckhoff   +4 more
wiley   +2 more sources

Latest Findings in Immunoglobulin Y Technologies and Applications. [PDF]

open access: yesInt J Mol Sci
Capotă R   +4 more
europepmc   +1 more source

Home - About - Disclaimer - Privacy