Results 161 to 170 of about 12,722 (248)

Formic Acid Stabilization on Supported Ionic Liquid Phases: Insights from Solid‐State NMR Spectroscopy

open access: yesChemistry – A European Journal, Volume 32, Issue 23, 16 June 2026.
Solid‐state NMR spectroscopy reveals insights into interactions between formic acid and molecularly‐modified silica surfaces. Our findings contribute to a mechanistic understanding of the stabilization of formic acid by ionic liquid structures, with significant implications for the formic acid production from CO2 hydrogenation and adaptive catalysis ...
Yufei Wu   +4 more
wiley   +1 more source

Generating Molecular Diversity via Addition of Nucleophiles to Electron-Deficient [3]Dendralenes: An Exploratory Study. [PDF]

open access: yesJ Org Chem
Perdomo SM   +11 more
europepmc   +1 more source

Sustainable Synthesis of 4,7‐Dihydro‐4,7‐ethano‐2H‐isoindoles—Key Building Blocks to Benzoporphyrins

open access: yesChemistry – A European Journal, Volume 32, Issue 23, 16 June 2026.
A facile and sustainable route to isoindole derivatives—key benzoporphyrin precursors—brings high‐ and low‐symmetry benzoporphyrins closer to practical application. ABSTRACT Benzoporphyrins, π extended porphyrin analogues, exhibit remarkable potential for optoelectronic and theragnostic applications, yet have remained largely confined to fundamental ...
Lampros Pascal Gazetas   +5 more
wiley   +1 more source

Pd‐Catalyzed Cyclotrimerization and Cycloaddition of 5,6‐Didehydrobenzo[8]annulenes (BenzoCOTynes): Formation of Nonplanar Tri[8]annulenes and Diels–Alder Cycloadducts

open access: yesEuropean Journal of Organic Chemistry, Volume 29, Issue 23, 16 June 2026.
A Pd(0)‐catalyzed cyclotrimerization of benzoCOTynes to form tri(benzo[8]annulenes) was developed. Three distinct isomers were isolated and structurally characterized by single‐crystal X‐ray diffraction. Ligand modulation proved crucial for enhancing regioselectivity: P(4‐OMePh), and (S)‐tBu‐Phox promoted the formation of the symmetric isomers.
Jesús Bello‐García   +2 more
wiley   +1 more source

Geminal Difunctionalization of Ketones via C─S Bond Insertion of Photogenerated Donor–Donor Diazo Compounds

open access: yesAngewandte Chemie International Edition, Volume 65, Issue 25, 15 June 2026.
Geminal difunctionalization of readily available building blocks provides rapid access to molecular complexity. This work introduces a strategy for installing two distinct functional groups on a carbonyl carbon by transforming it into a donor–donor diazo compound, enabling both batch and flow applications with broad solvent compatibility.
Vincent George   +13 more
wiley   +1 more source

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