Borylation of Aryl Halides Induced by Visible Light Under Open‐To‐Air Environment
Borylation of aryl halides was successfully achieved by a sustainable protocol which involved a purely organic confined medium, visible light as energy source under an open‐to‐air environment. Experimental and computational investigations evidenced that the reaction occurred through the formation of a ground–state complex generated by hydrogen bonding.
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A Pd/Cu cooperative catalytic system enables the direct C–H functionalization of a diverse range of five‐membered and benzo‐fused heterocycles with iodinated hexaarylborazines, providing efficient access to previously inaccessible heterocycle‐functionalized borazines.
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