Results 21 to 30 of about 328 (155)

Synthesis and crystal structure of trinuclear potassium(I) complex with oxy-bridged bis(gem-dinitro)furazan and triaminoguanidinium

open access: yesBulletin of the Chemical Society of Ethiopia, 2017
A furazan-based trinuclear potassium(I) complex derived from the oxy-bridged bis(gem-dinitro)furazan (OBNF) and triaminoguanidinium (TGA) units was synthesized and characterized by elemental analyses, nuclear magnetic resonance (NMR) and infrared (IR ...
L L. An, Q. Q. Yu
doaj   +1 more source

Strategies for constructing melt-castable energetic materials: A critical review

open access: yesEnergetic Materials Frontiers, 2021
Melt-castable energetic materials are utilized in a wide variety of civilian and military applications, such as construction, demolition, underwater blasting, mining, oil well perforation, and military munitions.
Qing Ma   +5 more
doaj   +1 more source

LX‐17 Thermal Decomposition‐Characterization of Solid Residues from Cook‐Off in a Small‐Scale Vessel Under Confinement

open access: yesPropellants, Explosives, Pyrotechnics, Volume 46, Issue 7, Page 1136-1149, July 2021., 2021
Abstract Concerns surround whether insensitive (or any) energetic materials are more dangerous to handle when exposed to abnormal thermal environments. This study characterizes the residual material remaining after LX‐17 (92.5 % 1,3,5‐triamino 2,4,6‐trinitro benzene (TATB) and 7.5 % Kel‐F) is exposed to various thermal environments in a sealed small ...
John G. Reynolds   +6 more
wiley   +1 more source

Toxicity Assessment of Energetic Materials by Using the Luminescent Bacteria Inhibition Test

open access: yesPropellants, Explosives, Pyrotechnics, Volume 46, Issue 1, Page 114-123, January 2021., 2021
Abstract The luminescent bacteria inhibition test using Aliivibrio fischeri is a well‐established method to determine the aquatic toxicity of soluble chemicals. More precisely, the effective concentration (EC50) after 15 and 30 min is determined in this test. The inhibition of natural bioluminescence of these bacteria gives a first idea of the toxicity
Thomas M. Klapötke   +3 more
wiley   +1 more source

Crystal Structures of Furazanes [PDF]

open access: yesCrystals, 2015
Several nitrogen-rich salts of 3-nitramino-4-nitrofurazane and dinitraminoazoxyfurazane were synthesized and characterized by various spectroscopic methods. The crystal structures were determined by low temperature single crystal X-ray diffraction. Moreover the sensitivities toward thermal and mechanical stimuli were determined by differential thermal ...
Klapötke, Thomas M.   +2 more
openaire   +3 more sources

A Family of Energetic Materials Based on 1,2,4-Oxadiazole and 1,2,5-Oxadiazole Backbones With Low Insensitivity and Good Detonation Performance

open access: yesFrontiers in Chemistry, 2020
Design and synthesis of new compounds with both high detonation performances and good safety properties have always been a formidable task in the field of energetic materials.
Qi Xue   +10 more
doaj   +1 more source

3-Methyl-4-(2-phenyl-1,2,4-triazolo[1,5-a]pyrimidin-7-yl)furazan

open access: yesActa Crystallographica Section E, 2013
In the title molecule, C14H10N6O, the planes of the methylfurazan fragment and the phenyl ring attached to the triazolopyrimidine bicycle are twisted from the mean plane of the bicycle at angles of 45.92 (5) and 5.45 (4)°, respectively ...
Kyrill Yu. Suponitsky   +3 more
doaj   +1 more source

Synthesis of melt-castable gem-dinitro derivatives of 4,5,6,7-tetrahydrobenzofurazan and its N-oxide

open access: yesFirePhysChem
The synthesis of energetic compounds of the gem-dinitrocarbocycle family, furazan and furoxan fused to dinitrocyclohexane, is reported. The construction of the gem-dinitro moiety was achieved by nitration of the hydroxyimine group by using both fuming ...
Albert G. Nigmatov   +3 more
doaj   +1 more source

Excitation Intensity Dependent Carrier Dynamics of Chalcogen Heteroatoms in Medium-Bandgap Polymer Solar Cells

open access: yesScientific Reports, 2017
The excitation intensity dependent carrier dynamics of blends with PC[70]BM of three new medium-band gap conjugated polymers with central chalcogen heteroatoms, PBDTfDTBX (X = O, T(Sulphur), Se) were studied.
Chandramouli Kulshreshtha   +7 more
doaj   +1 more source

Characterization of Structure, Properties, and Energetic Performance of a 1:1 Ammonium Dinitramide‐3,4‐Diaminofurazan Cocrystal

open access: yesPropellants, Explosives, Pyrotechnics, EarlyView.
Ammonium dinitramide (ADN) and 3,4‐Diaminofurazan (DAF) form a 1:1 energetic cocrystal. We report its crystal structure and spectroscopic signature and evaluate thermal stability, decomposition behavior, hygroscopicity, and combustion properties. Propellant performance calculations benchmark the material against guanylurea dinitramide (GuDN) and ...
Peter Schultz   +2 more
wiley   +1 more source

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