Coordination‐Driven Direct C─H Metalation of N‐Heterocycles With a Superbasic Co(II) Amide Co(TMP)2
Angewandte Chemie, EarlyView.By enabling regioselectivities that are inaccessible with conventional bases, this study introduces a Co(II) amide platform for the deprotonative C─H metalation of sensitive N‐heterocycles. Subsequent interception of the resulting Co(II) intermediates with external oxidants affords a family of sterically congested, TMP‐substituted heterocycles via C─N ...
Na Jin +3 more
wiley +2 more sources
Cobalt‐Catalyzed Radical Ligand Transfer (RLT) Enables Remote‐Markovnikov Hydroamination of Alkenes
Angewandte Chemie, EarlyView.A cobalt‐catalyzed remote‐Markovnikov 1,3‐hydroamination of allyl carboxylates proceeds through MHAT, 1,2‐radical acyloxy migration (1,2‐RAM), and radical ligand transfer (RLT) from a Co‐N intermediate, providing protected amino alcohols. ABSTRACT Amino alcohols are prevalent in pharmaceuticals, agrochemicals, and functional materials, yet ...
Arman Khosravi +7 more
wiley +2 more sources
Research on innovative furniture design methods combining Huizhou window grilles with digital technology. [PDF]
Sci RepWang W, Zhao J, Wang X, Zheng Q.
europepmc +1 more source
Angewandte Chemie, EarlyView.A “two‐in‐one” photoreduction strategy enabled by electron‐rich yolk Cd species both remote from and adjacent to sulfur vacancies is delivered to be ultraselective for the reduction of O2 and •CO2− in situ formed on the shell Bi2S3 composition (hole) by water oxidation and oxidative C–C cleavage of various biomass organic acids, furnishing CO with > 99%
Tengyu Liu +5 more
wiley +2 more sources
Advancing eye movement analysis through compositional modeling: A new perspective on Yarbus' classic study. [PDF]
Behav Res MethodsFačevicová K, Vymazal J, Popelka S.
europepmc +1 more source
Sustainable Pd‐Catalyzed Aminations “on Dirty Water”
Angewandte Chemie, EarlyView.Aminations, done safely yet neat, and therefore, quickly, using low levels of Pd, in “dirty water” that must contain 30% KOH; not NaOH, and not at 5%,10%, 20%, 40%, or 50% KOH. Moreover, no base sensitivity of functional groups! Very cool. Thank you, Nature.
Erfan Oftadeh +4 more
wiley +2 more sources
BioResourcesThe mortise and loose tenon (M<) joint is a form between mortise-and-tenon (M&T) joint and dowel. It combines the advantages of easy processing and high bonding strength and has no requirement for the shape of the tenon shoulder.
Jie Chen, Huiyuan Guan
doaj
Survey data on consumer circular economy behaviours: Focus on repair, reuse, recycling, refurbishment, and sharing in electronics and furniture across Germany, Italy, India and South Africa. [PDF]
Data BriefBashir A, Senft L, Klöckner CA.
europepmc +1 more source
Advances in BODIPY Derivatives for Antibacterial Phototherapy
Angewandte Chemie, EarlyView.This review systematically summarizes the design strategies and structure‐activity relationships of BODIPY‐based antibacterial phototherapy, covering molecular engineering of small‐molecule photosensitizers and nanoplatforms, bacterial targeting and carrier design, and discussing the challenges and future perspectives associated with clinical ...
Li Lv +9 more
wiley +2 more sources
Prevalence and indoor environment risk factors of parent-reported food allergy symptoms among preschool children in Haikou City, China: a cross-sectional survey. [PDF]
Front Public HealthWang S +7 more
europepmc +1 more source