Nucleophilic Gallyl Anions Enable Ga─Au Bimetallic Ammonia Activation
Unlocking gallyl nucleophiles: Counterion control enables formation of an unsupported gallyl─gold complex. Gold coordination induces a polarity switch at gallium, enabling cooperative activation of NH3 and related N─H/O─H substrates under mild conditions.
Hellen Videa +3 more
wiley +2 more sources
Research on innovative furniture design methods combining Huizhou window grilles with digital technology. [PDF]
Wang W, Zhao J, Wang X, Zheng Q.
europepmc +1 more source
An NHC‐Coordinated Silicon/Sulfur Analogue of an Acyl Carbene
An NHC complex of an Si/S analogue of an acyl carbene is synthesized by the reaction of a disilyne with a cyclic thiourea. The observed Si2S three‐membered ring with unsymmetrical Si─S distances and a Si─Si single bond is consistent with intramolecular coordination of the silathioacyl sulfur to the silylene center.
Takuto Toyooka +2 more
wiley +2 more sources
Survey data on consumer circular economy behaviours: Focus on repair, reuse, recycling, refurbishment, and sharing in electronics and furniture across Germany, Italy, India and South Africa. [PDF]
Bashir A, Senft L, Klöckner CA.
europepmc +1 more source
1,2‐Aryl migration involving in situ‐generated alkyl iodine(III) species proceeds through a previously unrecognized 1,2‐C/I(III) dyotropic rearrangement. Migratory aryl fluorination, acetoxylation, and alkoxylation of 2‐alkyl‐2‐aryl‐3‐iodopropanoates provide α‐heterofunctionalized products, accompanied by aryl migration from the α‐ to the β‐position ...
Chen‐Xu Liu +3 more
wiley +2 more sources
Advancing eye movement analysis through compositional modeling: A new perspective on Yarbus' classic study. [PDF]
Fačevicová K, Vymazal J, Popelka S.
europepmc +1 more source
A photochemical platform enables β–β coupling of cyclopropyl silyl ethers with electron‐deficient alkenes. The resulting adducts serve as entry points into annulative and radical–polar crossover pathways, providing rapid access to fused, bridged, and spirocyclic architectures, including late‐stage scaffold diversification to diterpene‐like carbocyclic ...
Jacop Rydén +5 more
wiley +2 more sources
Prevalence and indoor environment risk factors of parent-reported food allergy symptoms among preschool children in Haikou City, China: a cross-sectional survey. [PDF]
Wang S +7 more
europepmc +1 more source
The mortise and loose tenon (M<) joint is a form between mortise-and-tenon (M&T) joint and dowel. It combines the advantages of easy processing and high bonding strength and has no requirement for the shape of the tenon shoulder.
Jie Chen, Huiyuan Guan
doaj
Flame retardant biomarker changes with furniture replacement after flammability standard update. [PDF]
Attfield KR +12 more
europepmc +1 more source

