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Polymers, 2023 Poly (lactic acid) (PLA) is a promising green substitute for conventional petroleum-based plastics in a variety of applications. However, the wide application of PLA is still limited by its disadvantages, such as slow crystallization rate, inadequate gas barrier, thermal degradation, etc. In this study, lignin (1, 3, 5 PHR) was incorporated into PLA to
Yun-Xuan Weng +2 more
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ACS Sustainable Chemistry and Engineering, 2016
Lignin, one of the most naturally abundant polymers, has been successfully incorporated into ethylene glycol (EG) and poly(ethylene glycol) (PEG) in this work and fortified lubricating properties were achieved in EG/lignin and PEG/lignin. The molecular interaction between lignin and EG (or PEG) has been revealed as hydrogen bonding, which serves as the
Yijun Shi, Jiahua Zhu, Liwen Mu
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Lignin, one of the most naturally abundant polymers, has been successfully incorporated into ethylene glycol (EG) and poly(ethylene glycol) (PEG) in this work and fortified lubricating properties were achieved in EG/lignin and PEG/lignin. The molecular interaction between lignin and EG (or PEG) has been revealed as hydrogen bonding, which serves as the
Yijun Shi, Jiahua Zhu, Liwen Mu
exaly +2 more sources
Evidence for the heterogeneity of glycol lignin
Industrial & Engineering Chemistry Research, 1991Glycol and kraft lignins have been fractionated by solvent extraction using a sequence of organic solvents of increasing hydrogen-bonding capability. A comparison between the fractions from both lignins has been made in terms of yield, elemental analysis, Fourier transform infrared spectroscopy, and molecular weight distribution.
Ronald W. Thring +4 more
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STUDIES ON LIGNIN AND RELATED COMPOUNDS: II GLYCOL-LIGNIN AND GLYCOL-ETHER-LIGNIN
Canadian Journal of Research, 1930The extraction of spruce wood meal with ethylene glycol in the presence of 0.05% HCl leads to the isolation of a lignin derivative to which the name glycol-lignin is given. If the monomethyl ether of glycol be substituted for the free alcohol, a glycol-ether-lignin is obtained which has a much higher methoxyl content than glycol-lignin. The product of
Harold Hibbert, Léo Marion
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STUDIES ON LIGNIN AND RELATED COMPOUNDS: XV. PHENOL GLYCOL LIGNIN
Canadian Journal of Research, 1935Phenol condensation products of glycol lignin, of a premethylated and a fully methylated glycol lignin have been prepared. In each case it has been found that, on the basis of the five methoxyl groups present in the original glycol lignin, three molecules of phenol react with one lignin unit by nuclear condensation, and when the product is worked up ...
Fritz Brauns, Harold Hibbert
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STUDIES ON LIGNIN AND RELATED COMPOUNDS: IV. THE NITRATION OF GLYCOL-LIGNIN
Canadian Journal of Research, 1930Glycol-lignin at temperatures below 0 °C., dissolves completely in a mixture of four parts of acetic anhydride and one part of fuming nitric acid, giving rise to a 125% yield of a product (nitrated-lignin) which has undergone nitration and acetylation. The nitrogen in the product is present partly in the form of a nitro group, an ester of nitric acid,
Harold Hibbert, Leo Marion
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Thermolysis of glycol lignin in the presence of tetralin
The Canadian Journal of Chemical Engineering, 1993AbstractAn organosolv (ethylene glycol) hardwood lignin has been thermally treated in the presence of tetralin, a hydrogen donor solvent. The effects of reaction temperature and time on product distribution were studied as a function of a seventy index, Xc = ℓn (Rω with Rω = Δt t × exp [(Tr ‐ Tb)/ω] where Δt = time, Tr = reaction temperature, Tb = base
Ronald W. Thring +2 more
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Characterization of lignin residues derived from the alkaline hydrolysis of glycol lignin
Canadian Journal of Chemistry, 1990Lignin residues from the alkaline hydrolysis of solvolytic lignin have been characterized by elemental analysis, size exclusion chromatography, Fourier transform infrared spectroscopy, 13C NMR, and for methoxyl content. All lignin residues were found to have higher carbon and lower oxygen contents than the original glycol lignin.
Ronald W. Thring +4 more
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STUDIES ON LIGNIN AND RELATED COMPOUNDS: IX. ETHERS OF GLYCOL-LIGNIN
Canadian Journal of Research, 1931Glycol-lignin prepared from spruce wood has been found to form a sodium salt which reacts with chloro-derivatives, giving rise to the corresponding glycol-lignin ethers. These compounds are insoluble in aqueous sodium hydroxide but still contain free hydroxyl groups which can be methylated without the ethereal linkage being broken. Hence glycol-lignin
Harold Hibbert, Léo Marion
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