Zur Rolle von Wasser bei der CO2‐Reduktion an defektreichem TiO2 bei niedrigen Temperaturen
Unsere Ergebnisse unterstreichen das Potenzial von reduziertem Titandioxid als edelmetallfreiem Katalysator zur Aktivierung von CO2 und zeigen in situ die Reaktion von CO2 auf defektreichem TiO2 unter Verwendung von synchrotronbasiertem NAP‐XPS von Raumtemperatur bis 700 K.
Justin Klimek +6 more
wiley +1 more source
Glyoxal uptake on ammonium sulphate seed aerosol: reaction products and reversibility of uptake under dark and irradiated conditions [PDF]
Chamber studies of glyoxal uptake onto ammonium sulphate aerosol were performed under dark and irradiated conditions to gain further insight into processes controlling glyoxal uptake onto ambient aerosol. Organic fragments from glyoxal dimers and trimers
M. M. Galloway +6 more
doaj
Role of Water in Low‐Temperature CO2 Reduction at Defect‐Rich TiO2
Our results highlight the potential of reduced titania as a noble metal‐free CO2 activation catalyst and show the activation of CO2 on highly defective TiO2 using in situ synchrotron‐based NAP‐XPS from room temperature to 700 K. The distribution of surface intermediates can be decoded as a simultaneous population of reaction routes, revealing water (OH)
Justin Klimek +6 more
wiley +1 more source
Formation and composition of organic aerosols from the uptake of glyoxal on natural mineral dust aerosols: a laboratory study [PDF]
The uptake of glyoxal on realistic submicron mineral dust aerosol particles from a natural soil (Gobi Desert) is investigated during experiments in a large simulation chamber, under variable experimental conditions of relative humidity (RH), irradiation,
F. Battaglia +20 more
doaj +1 more source
Glyoxylic‐Acetal‐Based Gel‐Polymer Electrolytes for Lithium‐Ion Batteries
A safe electrolyte based on tetraethoxyglyoxal (LE) is combined with a methacrylate polymer matrix. The resulting gel‐polymer electrolyte (GPE) exhibits an increased flash point, suitable ionic conductivity, and a stable performance in lithium‐ion battery cells.
Christian Leibing +4 more
wiley +1 more source
Abstract Heterozygous loss‐of‐function variants in the gene SCN1A, which encodes the voltage‐gated sodium channel (VGSC) pore‐forming (α) subunit NaV1.1, lead to a spectrum of neurological disease, including Dravet syndrome. NaV1.1 is prominently expressed at the proximal portion of the axon initial segment (AIS) of fast‐spiking γ‐aminobutyric ...
Ania K. Dabrowski +4 more
wiley +1 more source
Advances in conjugated porous polymers via high internal phase emulsion templating
This mini‐review highlights the design, synthesis and potential applications of π‐conjugated polyHIPEs, emphasizing their unique hierarchical structure and tunable properties. The work outlines innovative synthetic strategies and explores their promising roles in photocatalysis and environmental remediation, paving the way for future advancements in ...
Julie‐Lisa Malaval +4 more
wiley +1 more source
Efficient Synthesis of Dipyrazino[2,3-f; 2'3'-h]quinoxaline
The condensation of benzenehexamine (2) with the masked forms 3a or 3b of glyoxal leads to the title compound (4) in good yields; aqueous glyoxal is highly unsatisfactory.
Jacques Nasielski +6 more
doaj +1 more source
Evaluation of Glyoxal-Based Electrolytes for Lithium-Sulfur Batteries
Lithium-sulfur batteries (LSBs) are among the most promising next generation battery technologies. First prototype cells show higher specific energies than conventional Li-ion batteries (LIBs) and the active material is cost-effective and ubiquitously ...
Sebastian Kirchhoff +7 more
doaj +1 more source
Mercury sensitized photosynthesis of glyoxal
The characteristic absorption spectrum of glyoxal at 455C K was observed in a flow system during the mercury sensitized reaction between acetylene and oxygen.
Krishnamachari, S. L. N. G. +1 more
core +1 more source

