Synthesis and Structural Characterization of Phosphanide Gold(III)/Gold(I) Complexes and Their Thallium(III) and Gold(III) Precursors [PDF]
Molecules, 2023 In this paper, we describe a series of diphenylphosphane and diphenylphosphanide gold(III) and gold(III)/gold(I) complexes containing 3,5-C6Cl2F3 as aryl ligands at gold that have been synthesized due to the arylating and oxidant properties of the new ...
Laura Coconubo-Guio +3 more
doaj +6 more sources
Gold(III)-Substituted Carbenes. [PDF]
J Am Chem SocThe Au(III)-substituted diazo compounds (N^C^C)AuC(N2)R (R = Dmp = 2,6-dimesitylphenyl and SiMe3) 1 and 6 were synthesized by reacting the (N^C^C)AuCl precursor with the corresponding lithiated diazo compounds. Dinitrogen extrusion was then promoted by UV-vis irradiation.
Wei R +5 more
europepmc +3 more sources
Complexation of Gold(III) with Pyridoxal 5′-Phosphate-Derived Hydrazones in Aqueous Solution [PDF]
Molecules, 2022 Today, complexes of gold(I) and gold(III) are recognized as promising drugs for the treatment of bacterial infectious diseases and oncological diseases, respectively.
Natalia N. Kuranova +3 more
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Crystal structures of trichlorido(4-methylpiperidine)gold(III) and two polymorphs of tribromido(4-methylpiperidine)gold(III) [PDF]
Acta Crystallographica Section E: Crystallographic CommunicationsTrichlorido(4-methylpiperidine)gold(III), [AuCl3(C6H13N)], 1, crystallizes in Pbca with Z = 8. Tribromido(4-methylpiperidine)gold(III), [AuBr3(C6H13N)], 2, crystallizes as two polymorphs, 2a in Pnma with Z = 4 (imposed mirror symmetry) and 2b, which is ...
Cindy Döring, Peter G. Jones
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Organometallic gold(I) and gold(III) complexes for lung cancer treatment [PDF]
Frontiers in Pharmacology, 2022 Metal compounds, especially gold complexes, have recently gained increasing attention as possible lung cancer therapeutics. Some gold complexes display not only excellent activity in cisplatin-sensitive lung cancer but also in cisplatin-resistant lung ...
Juzheng Zhang +7 more
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Synthesis of Cyclometalated Gold(III) Complexes via Catalytic Rhodium to Gold(III) Transmetalation
Angewandte Chemie - International Edition, 2022 Abstract A catalytic method to synthesize a broad array of cyclometalated (C^N)gold(III) complexes is reported here. An unprecedented Rh‐to‐Au III transmetalation allows the facile transfer of (C^N) ligands between these two metals in a redox‐neutral process.
Cristina Nevado +2 more
exaly +6 more sources
Crystal structures of seven gold(III) complexes of the form LAuX3 (L = substituted pyridine, X = Cl or Br) [PDF]
Acta Crystallographica Section E: Crystallographic CommunicationsThe structures of seven gold(III) halide derivatives of general formula LAuX3 (L = methylpyridines or dimethylpyridines, X = Cl or Br) are presented: trichlorido(2-methylpyridine)gold(III), [AuCl3(C6H7N)], 1 (as two polymorphs 1a and 1b); tribromido(2 ...
Cindy Döring, Peter G. Jones
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Stable Pincer Gold(III)‐TADF Emitters with Extended Donor–Acceptor Separation for Efficient Vacuum‐Deposited OLEDs with Operational Lifetime (LT95) up to 3831 h at 1000 cd m−2 [PDF]
Advanced ScienceAlthough gold‐TADF (thermally activated delayed fluorescence) emitters have attractive prospects as next‐generation practical OLED emitters, the performance of OLEDs utilizing gold(I)‐ and gold(III)‐TADF emitters lags behind the requirements of practical
Hui‐Xing Shu +4 more
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Adsorption of Gold(I) and Gold(III) Using Multiwalled Carbon Nanotubes
Applied Sciences, 2018 Carbon nanotubes are materials that have been investigated for diverse applications including the adsorption of metals. However, scarce literature has described their behavior in the case of the adsorption of precious metals.
Francisco Jose Alguacil
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Pharmaceutics, 2021 Bipyridine gold (III) dithiocarbamate compounds are Gold-III complexes with promising cytotoxic properties. In this study, the subacute toxicity of a Gold (III) complex with dithiocarbamate ligand was evaluated.
Ahmed Badar +5 more
doaj +1 more source