Results 11 to 20 of about 337,555 (257)

Au2phen and Auoxo6, Two Dinuclear Oxo-Bridged Gold(III) Compounds, Induce Apoptotic Signaling in Human Ovarian A2780 Cancer Cells

open access: yesBiomedicines, 2021
Au2phen ((2,9-dimethyl-1,10-phenanthroline)2Au2(µ-O)2)(PF6)2 and Auoxo6 ((6,6′-dimethyl-2,2′-bipyridine)2Au2(µ-O)2)(PF6)2 are two structurally related gold(III) complexes that were previously reported to display relevant and promising anticancer ...
Giulia Gorini   +7 more
doaj   +1 more source

Binding of gold(III) with DNA [PDF]

open access: yesBiopolymers, 1973
Metal $ions^{1..10}$ are known to bind to DNA. A number of metal ions have been studied and their binding established. $Cu(II)^{8,9,10}$ and $Ag(I)^4$ have been widely studied and ample literature exists on these two metals. On the other hand, the interaction of DNA with gold(III) (which does not occur as $Au^{3+}$ in solution, but rather exists in ...
Pillai, CKS, Nandi, US
openaire   +2 more sources

Gold(III) π‐Allyl Complexes [PDF]

open access: yesAngewandte Chemie International Edition, 2019
AbstractGold(III) π‐complexes have been authenticated recently with alkenes, alkynes, and arenes. The key importance of PdII π‐allyl complexes in organometallic chemistry (Tsuji–Trost reaction) prompted us to explore gold(III) π‐allyl complexes, which have remained elusive so far.
Rodriguez, Jessica   +5 more
openaire   +2 more sources

Gold(III) Complexation in the Presence of the Macropolyhedral Hydridoborate Cluster [B20H18]2−

open access: yesInorganics, 2022
Gold(III) complexation with the octadecahydrido-eicosaborate anion [B20H18]2− was studied for the first time. It was found that when gold(III) complexes [Au(L)Cl2]BF4 (L = bipy, phen) reacted with [B20H18]2−, complexes [Au(L)Cl2]2[B20H18] were isolated ...
Varvara V. Avdeeva   +6 more
doaj   +1 more source

Luminescent cyclometalated gold(iii) complexes [PDF]

open access: yesDalton Transactions, 2011
Many luminescent gold(I) compounds are known, but in the vast majority of gold(III) complexes reported until recently, room temperature emission in fluid solution does not occur. As for other d(8) and d(6) metals, the key to obtaining gold(III) compounds with favorable luminescence properties seems to be the use of cyclometalating ligands that ensure ...
Bronner, Catherine, Wenger, Oliver S.
openaire   +3 more sources

(Z)-5-Benzylidene-4-phenyl-2-(p-tolyl)-4,5-dihydrooxazole

open access: yesMolbank, 2023
By strategic use of the valence difference between hard gold(III) and soft gold(I) catalysts, one-pot synthesis of (Z)-5-benzylidene-4-phenyl-2-(p-tolyl)-4,5-dihydrooxazole (15) from propargylic alcohol (9) and p-toluamide (13) was achieved via gold(III)-
Nobuyoshi Morita   +5 more
doaj   +1 more source

Highlights on Gold TADF Complexes

open access: yesInorganics, 2019
Thermally activated delayed fluorescence (TADF) and TADF-organic light-emitting diodes (OLEDs) systems are being given increasing attention in research nowadays.
João Carlos Lima, Laura Rodríguez
doaj   +1 more source

Preparation, characterization and cytotoxic evaluation of novel au(iii) complexes of thioglycolate and 2-mercaptoglycolate ligands [PDF]

open access: yesالمجلة العراقية للصيدلة, 2013
Objectives: One of the main goals of the present research is to establish whether any direct correlation exists between the nature of the gold(III) S-ligands and the cytotoxic properties of these compounds. Methods: The gold(III) complexes [Au(L)(L')n];
N.A. Al-Omari, N. H.Butrus
doaj   +1 more source

Gold Thione Complexes

open access: yesInorganics, 2014
The reaction of the ligand Et4todit (4,5,6,7-Tetrathiocino-[1,2-b:3,4-b']-diimidazolyl-1,3,8,10-tetraethyl-2,9-dithione) with gold complexes leads to the dinuclear gold(I) complexes [{Au(C6F5)}2(Et4todit)] and [Au(Et4todit)]2(OTf)2, which do not contain ...
Francesco Caddeo   +5 more
doaj   +1 more source

Reactions of Medicinal Gold(III) Compounds With Proteins and Peptides Explored by Electrospray Ionization Mass Spectrometry and Complementary Biophysical Methods

open access: yesFrontiers in Chemistry, 2020
Electrospray ionization mass spectrometry (ESI MS) is a powerful investigative tool to analyze the reactions of metallodrugs with proteins and peptides and characterize the resulting adducts.
Lara Massai   +4 more
doaj   +1 more source

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