Results 11 to 20 of about 337,555 (257)
Au2phen ((2,9-dimethyl-1,10-phenanthroline)2Au2(µ-O)2)(PF6)2 and Auoxo6 ((6,6′-dimethyl-2,2′-bipyridine)2Au2(µ-O)2)(PF6)2 are two structurally related gold(III) complexes that were previously reported to display relevant and promising anticancer ...
Giulia Gorini +7 more
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Binding of gold(III) with DNA [PDF]
Metal $ions^{1..10}$ are known to bind to DNA. A number of metal ions have been studied and their binding established. $Cu(II)^{8,9,10}$ and $Ag(I)^4$ have been widely studied and ample literature exists on these two metals. On the other hand, the interaction of DNA with gold(III) (which does not occur as $Au^{3+}$ in solution, but rather exists in ...
Pillai, CKS, Nandi, US
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Gold(III) π‐Allyl Complexes [PDF]
AbstractGold(III) π‐complexes have been authenticated recently with alkenes, alkynes, and arenes. The key importance of PdII π‐allyl complexes in organometallic chemistry (Tsuji–Trost reaction) prompted us to explore gold(III) π‐allyl complexes, which have remained elusive so far.
Rodriguez, Jessica +5 more
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Gold(III) Complexation in the Presence of the Macropolyhedral Hydridoborate Cluster [B20H18]2−
Gold(III) complexation with the octadecahydrido-eicosaborate anion [B20H18]2− was studied for the first time. It was found that when gold(III) complexes [Au(L)Cl2]BF4 (L = bipy, phen) reacted with [B20H18]2−, complexes [Au(L)Cl2]2[B20H18] were isolated ...
Varvara V. Avdeeva +6 more
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Luminescent cyclometalated gold(iii) complexes [PDF]
Many luminescent gold(I) compounds are known, but in the vast majority of gold(III) complexes reported until recently, room temperature emission in fluid solution does not occur. As for other d(8) and d(6) metals, the key to obtaining gold(III) compounds with favorable luminescence properties seems to be the use of cyclometalating ligands that ensure ...
Bronner, Catherine, Wenger, Oliver S.
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(Z)-5-Benzylidene-4-phenyl-2-(p-tolyl)-4,5-dihydrooxazole
By strategic use of the valence difference between hard gold(III) and soft gold(I) catalysts, one-pot synthesis of (Z)-5-benzylidene-4-phenyl-2-(p-tolyl)-4,5-dihydrooxazole (15) from propargylic alcohol (9) and p-toluamide (13) was achieved via gold(III)-
Nobuyoshi Morita +5 more
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Highlights on Gold TADF Complexes
Thermally activated delayed fluorescence (TADF) and TADF-organic light-emitting diodes (OLEDs) systems are being given increasing attention in research nowadays.
João Carlos Lima, Laura Rodríguez
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Preparation, characterization and cytotoxic evaluation of novel au(iii) complexes of thioglycolate and 2-mercaptoglycolate ligands [PDF]
Objectives: One of the main goals of the present research is to establish whether any direct correlation exists between the nature of the gold(III) S-ligands and the cytotoxic properties of these compounds. Methods: The gold(III) complexes [Au(L)(L')n];
N.A. Al-Omari, N. H.Butrus
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The reaction of the ligand Et4todit (4,5,6,7-Tetrathiocino-[1,2-b:3,4-b']-diimidazolyl-1,3,8,10-tetraethyl-2,9-dithione) with gold complexes leads to the dinuclear gold(I) complexes [{Au(C6F5)}2(Et4todit)] and [Au(Et4todit)]2(OTf)2, which do not contain ...
Francesco Caddeo +5 more
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Electrospray ionization mass spectrometry (ESI MS) is a powerful investigative tool to analyze the reactions of metallodrugs with proteins and peptides and characterize the resulting adducts.
Lara Massai +4 more
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