Comparison of Bifurcated Halogen with Hydrogen Bonds
Molecules, 2021 Bifurcated halogen bonds are constructed with FBr and FI as Lewis acids, paired with NH3 and NCH bases. The first type considered places two bases together with a single acid, while the reverse case of two acids sharing a single base constitutes the ...
Steve Scheiner
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Toward a uniform description of hydrogen bond and halogen bond: correlations of interaction energies with various geometric, electronic and topological parameters [PDF]
, 2017 Correlations between interaction energies and various structural parameters were established to reveal the differences between hydrogen bonds and halogen bonds.
Hu, Gui-Xiang +3 more
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Competition between Halogen, Hydrogen and Dihydrogen Bonding in Brominated Carboranes [PDF]
, 2016 Halogen bonds are a subset of noncovalent interactions with rapidly expanding applications in materials and medicinal chemistry. While halogen bonding is well known in organic compounds, it is new in the field of boron cluster chemistry.
Allen +31 more
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Crystal structure of 7,8-dichloro-4-oxo-4H-chromene-3-carbaldehyde
Acta Crystallographica Section E: Crystallographic Communications, 2015 In the title compound, C10H4Cl2O3, a dichlorinated 3-formylchromone derivative, the fused-ring system is slightly puckered [dihedral angle between the benzene and pyran rings = 3.66 (10)°].
Yoshinobu Ishikawa
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Halogen Bonds Fabricate 2D Molecular Self-Assembled Nanostructures by Scanning Tunneling Microscopy
Crystals, 2020 Halogen bonds are currently new noncovalent interactions due to their moderate strength and high directionality, which are widely investigated in crystal engineering.
Yi Wang, Xinrui Miao, Wenli Deng
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The Halogen Bond in the Design of Functional Supramolecular Materials: Recent Advances [PDF]
, 2013 Halogen bonding is an emerging noncovalent interaction for constructing supramolecular assemblies. Though similar to the more familiar hydrogen bonding, four primary differences between these two interactions make halogen bonding a unique tool for ...
A. Priimagi +3 more
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π covalency in the halogen bond
Nature Communications, 2020 Current models of halogen bonding describe the σ-symmetric component of this interaction but do not contemplate the possibility of π-covalency. Here the authors provide experimental and computational evidence of π-covalency in halogen bonds involving ...
Cameron W. Kellett +2 more
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Hierarchical Self-Assembly of Halogen-Bonded Block Copolymer Complexes into Upright Cylindrical Domains [PDF]
, 2017 Self-assembly of block copolymers into well-defined, ordered arrangements of chemically distinct domains is a reliable strategy for preparing tailored nanostructures.
Cavallo G. +10 more
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Astatine Facing Janus: Halogen Bonding vs. Charge-Shift Bonding
Molecules, 2021 The nature of halogen-bond interactions was scrutinized from the perspective of astatine, potentially the strongest halogen-bond donor atom. In addition to its remarkable electronic properties (e.g., its higher aromaticity compared to benzene), C6At6 can
Serigne Sarr +4 more
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Crystals, 2017 Seventeen new halogen-bonded co-crystals characterized by single crystal X-ray analysis are presented from 8 × 4 combinations using methyl-substituted pyridine N-oxides and 1,ω-diiodoperfluoroalkanes. The N−O group in six of 17 co-crystals is monodentate
Rakesh Puttreddy +3 more
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