Results 81 to 90 of about 148,467 (378)

Noncovalent Binding of the Halogens to Aromatic Donors. Discrete Structures of Labile Br\u3csub\u3e2\u3c/sub\u3e Complexes with Benzene and Toluene [PDF]

, 2001
Precise molecular structures resulting from the noncovalent interaction of Br2 with benzene (and toluene) reveal the unusual localized bonding to specific (one or two) carbon centers in prereactive complexes leading directly to the transition states for ...
Kochi, Jay K., Lindeman, Sergey V., Vasilyev, Alexandr V.   +2 more
core   +1 more source

Electrochemical Formation of BiVO4/BiPO4 Photoanodes for Enhanced Selectivity toward H2O2 Generation

Advanced Functional Materials, EarlyView.
In acidic KPi, V dissolves from the BiVO4 lattice, while adsorbed phosphate reacts with the electrode under an external bias, forming a BiPO4 surface layer. This BiPO4 layer exhibits stronger bicarbonate adsorption, redirecting the water oxidation pathway toward two‐electron H2O2 production.
Kaijian Zhu, Xinyi Zhang, Lan Wen, Hongjiang Chen, Yudhistira Tirtayasri Amrillah, Vivi Fauzia, Hongzhen Dong, Shaoqiang Su, Wenjun Luo, Ferry Anggoro Ardy Nugroho, Patrick H.‐L. Sit, Yun Hau Ng, Fatwa F. Abdi   +12 more
wiley   +1 more source

Seasonality of halogen deposition in polar snow and ice [PDF]

Atmospheric Chemistry and Physics, 2014
The atmospheric chemistry of iodine and bromine in Polar regions is of interest due to the key role of halogens in many atmospheric processes, particularly tropospheric ozone destruction. Bromine is emitted from the open ocean but is enriched above first-
A. Spolaor, P. Vallelonga, J. Gabrieli, T. Martma, M. P. Björkman, E. Isaksson, G. Cozzi, C. Turetta, H. A. Kjær, M. A. J. Curran, A. D. Moy, A. Schönhardt, A.-M. Blechschmidt, J. P. Burrows, J. M. C. Plane, C. Barbante   +15 more
doaj   +1 more source

Bioinspired Bromination Enables Extensible, Strain‐Stiffening Resilin Peptide Scaffolds with Tunable Degradation

Advanced Functional Materials, EarlyView.
Bioinspired bromination of a resilin‐derived peptide enables the fabrication of electrospun nanofibrous scaffolds that uniquely combine strain‐stiffening elasticity, proteolytic stability, and antioxidant functionality. These brominated peptide–gelatin hybrids mimic the extensibility of natural elastomers, demonstrating tunable mechanical resilience ...
Elisa Marelli, Lorenzo Sori, Chiara Russo, Claudia Pigliacelli, Lorenza Draghi, Monica Soncini, Pierangelo Metrangolo   +6 more
wiley   +1 more source

Content changes of adsorbable organically bound halogens during sludge centrifugation and drying

Research in Agricultural Engineering, 2011
A wastewater treatment plant in Brno may be one of the wastewater treatment plants in the Czech Republic using a dryer for dewatering the sludge. The results of an adsorbable organically bound halogens balance analysis measured on the sludge dryer at the
K. Hrich, B. Groda
doaj   +1 more source

Estimates of Cl atom concentrations and hydrocarbon kinetic reactivity in surface air at Appledore Island, Maine (USA), during International Consortium for Atmospheric Research on Transport and Transformation/Chemistry of Halogens at the Isles of Shoals [PDF]

, 2007
Average hydroxyl radical (OH) to chlorine atom (Cl·) ratios ranging from 45 to 119 were determined from variability‐lifetime relationships for selected nonmethane hydrocarbons (NMHC) in surface air from six different transport sectors arriving at ...
Fischer, Emily V., Pszenny, Alexander A. P., Russo, Rachel S., Sive, Barkley C., Varner, Ruth K.   +4 more
core   +1 more source

Roll‐to‐Roll Mechanical Exfoliation for Large‐Area van der Waals Films with Preserved Crystallographic Alignment

Advanced Functional Materials, EarlyView.
A roll‐to‐roll exfoliation method is demonstrated that preserves the crystallographic alignment of anisotropic 2D materials over large areas, enabling scalable fabrication of directional electronic and optoelectronic devices. Abstract Anisotropic 2D materials such as black phosphorus (BP), GeS or CrSBr, exhibit direction‐dependent optical and ...
Esteban Zamora‐Amo, Francisco Fernandez‐Canizares, Yigit Sozen, Thomas Pucher, Pedro L Alcázar Ruano, Carmen Munuera, Ryo Ishikawa, Naoya Shibata, María Varela, Der‐Yuh Lin, Bing Wu, Jorge Quereda, Zdenek Sofer, Gabriel Sánchez‐Santolino, Andres Castellanos‐Gomez   +14 more
wiley   +1 more source

Energy‐Efficient Bulk Photoalignment of Main‐Chain Liquid Crystalline Polymers Enabled by In Situ Monitoring

Advanced Functional Materials, EarlyView.
In situ monitoring of bulk photoalignment reveals how molecular weight, azobenzene content, cooling rate, and thickness govern ordering in main‐chain liquid crystalline polymers. Optimized copolymers exceed conventional thickness limits, maintaining stable alignment up to 130 µm with high energy efficiency and reversible optical patterning.
Jaechul Ju, Joy Zhou, Connor J. O'Dea, Zachariah A. Page   +3 more
wiley   +1 more source

Halogens in pore water of peat bogs – the role of peat decomposition and dissolved organic matter [PDF]

Biogeosciences, 2006
Halogens are strongly enriched in peat and peatlands and such they are one of their largest active terrestrial reservoir. The enrichment of halogens in peat is mainly attributed to the formation of organohalogens and climatically controlled humification ...
H. Biester, D. Selimović, S. Hemmerich, M. Petri   +3 more
doaj  

Functionalized Germanene as a Prototype of Large-Gap Two-Dimensional Topological Insulators

, 2014
We propose new two-dimensional (2D) topological insulators (TIs) in functionalized germanenes (GeX, X=H, F, Cl, Br or I) using first-principles calculations.
Duan, Wenhui, Gu, Bing-Lin, Liu, Junwei, Si, Chen, Wu, Jian, Xu, Yong   +5 more
core   +2 more sources