Results 241 to 250 of about 70,860 (329)
The Challenging P‐Alkylation of Aromatic Phosphorus Heterocycles and Follow‐Up Reactions
P‐alkylation of λ3σ2‐phosphinines is hindered by weak nucleophilicity and scarce synthetic access, previously requiring multistep routes or extreme electrophiles. A direct ambient‐condition method is reported using 3,5‐bis(trimethylsilyl)‐phosphinine/B(C6F5)3 with esters or iso(thio)cyanates to generate stable 1‐R‐phosphininium salts.
Samantha Frank +6 more
wiley +1 more source
Biosynthesis of the 5-Isoxazolidinone-Containing Hexacyclic Structure of Parnafungin. [PDF]
Sun Z, Yost KM, Bills GF, Tang Y.
europepmc +1 more source
Nitrogen-containing heterocycles derived from isoquinoline alkaloids
I Made Sudarma
openalex +1 more source
The cis‐2,3‐bis(trifluoromethyl)cyclopropyl chemotype is introduced. The steric demand of this motif is intermediate between that of the heptafluoroisopropyl and prefluorotertbutyl groups; yet, it induces significantly less lipophilicity than these due to its facial polarity.
Daniel Gaviña +5 more
wiley +1 more source
State-of-the-art transition metal-catalyzed approaches to quinoline frameworks <i>via</i> multicomponent reactions. [PDF]
Kazemi M +7 more
europepmc +1 more source
Organophotoredox/Cobalt‐Catalyzed Retro‐Hydroformylation of Aldehydes
A new photoredox/cobalt retro‐hydroformylation is developed. This one‐pot two‐step process involves the in situ formation of the corresponding 1,4‐dihydropyridine as key intermediate. Under mild reaction conditions, alkenes are efficiently produced from a wide range of aliphatic α‐monosubstituted aldehydes, with high functional‐group tolerance.
Augustin Nouaille +3 more
wiley +1 more source
Base-Mediated Scalable Synthesis of Polybenzothiazoles: Fused-Heterocycle-Engineered Recovery of Precious Metals. [PDF]
Zhou H +7 more
europepmc +1 more source

