Results 151 to 160 of about 101,033 (289)

Isolation and Reactivity of a Square‐Planar Trisamido Silane

Angewandte Chemie International Edition, EarlyView.
We report the synthesis and comprehensive characterisation of a square‐planar Si(+IV) hydride supported by an unsymmetric, trianionic and dearomatised N,N,N‐pincer ligand. This system enables element–ligand cooperative reactivity as an alternative to silicon‐centred redox chemistry, illuminating a largely unexplored regime in high‐valent silicon ...
David M. J. Krengel, Xiaobai Wang, Christopher Golz, Regine Herbst‐Irmer, Oliver P. E. Townrow, Malte Fischer   +5 more
wiley   +1 more source

Net Oxidative Photocatalytic Strategy toward the <i>o</i>-Trifluoroacetylation of <i>N</i>-Heteroarenes. [PDF]

Org Lett
Samony KL, Thullaprambil JZ, Nabi RN, Brunner KE, Kim DK.   +4 more
europepmc   +1 more source

Catalytic Asymmetric Diastereodivergent Synthesis of 2‑Alkenylindoles Bearing both Axial and Central Chirality

Precision Chemistry
Shuang Yang, Jia-Bo Huang, Da-Hua Wang, Ning-Yi Wang, Yu-Yu Chen, Xin-Yan Ke, Hao Chen, Shao-Fei Ni, Yu-Chen Zhang, Feng Shi   +9 more
doaj   +1 more source

The Heterocycle Isostere Explorer: A Computational Tool for the Discovery of Novel Aromatic Heterocyclic Isosteres. [PDF]

J Med Chem
Holland MTO, Sebastián-Pérez V, Bradley AR, Duarte F, Brennan PE.   +4 more
europepmc   +1 more source

Asymmetric Electrophilic alpha-Amidoalkylation 5 [PDF]

, 1988
Kärtner, Annerose, Wadenstorfer, Elmar, Wanner, Klaus Th.   +2 more
core   +1 more source

Molecular blueprints for cleaner air: theoretical insights into Cu(i)-decorated heterocycles for greenhouse gas (CO/CO₂/CH₄) capture. [PDF]

RSC Adv
Bag A, Roymahapatra G.
europepmc   +1 more source

Isomerization of N-acyl-1,2,5,6-tetrahydropyridines to N-acyl-enamines by palladium on carbon [PDF]

, 1987
Kärtner, Annerose, Wanner, Klaus Th.
core   +1 more source

Two‐Dimensional Polymers as Modular Metal‐Free Solid‐State Catalysts for Efficient Sono‐Piezo‐Photocatalytic Hydrogen Peroxide Production

Angewandte Chemie International Edition, EarlyView.
This study demonstrates the high piezo‐photocatalytic activity of solid molecular catalysts (SMCs) in the production of hydrogen peroxide from water and oxygen. Through the rational design of molecular motifs (diphenylpyridine or terpyridine) and backbone functionalities (methyl group, aliphatic amine antenna, or aromatic pyrrole unit), as well as ...
Sarah Brettschneider, Keanu V. A. Birkelbach, Marcus Lantzius‐Beninga, Ahmed Mourran, Gurudas Chakraborty, Peter J. C. Hausoul, Andreas Herrmann, Regina Palkovits   +7 more
wiley   +1 more source

Mapping the Reactivity of the C═C Bond of Cyclic Enol Ether Derivatives of Sugars: Nucleophilicity Parameters of Glycals

Angewandte Chemie International Edition, EarlyView.
Endo or Exo? The first quantitative kinetic mapping of the nucleophilic reactivity of endo‐ and exo‐glycal compounds highlighted that endo‐glycals are typically 102 times less reactive than their corresponding parent cyclic enol ethers while exo‐glycals are 103 more nucleophilic. This experimental and computational structure–reactivity study highlights
Sophie Rodrigues, Saloua Chelli, Jenny Ha, Lucie Pedussaut, Sami Lakhdar, Raphaël Robiette, Stéphane P. Vincent, Guillaume Berionni   +7 more
wiley   +1 more source

RETRACTED: Ullah et al. Fluorescent and Phosphorescent Nitrogen-Containing Heterocycles and Crown Ethers: Biological and Pharmaceutical Applications. <i>Molecules</i> 2022, <i>27</i>, 6631. [PDF]

Molecules
Ullah F, Ullah S, Khan MFA, Mustaqeem M, Paracha RN, Rehman MFU, Kanwal F, Hassan SSU, Bungau S.   +8 more
europepmc   +1 more source