Results 101 to 110 of about 176,899 (357)

Crystal structures of ethyl {2-[4-(4-isopropylphenyl)thiazol-2-yl]phenyl}carbamate and ethyl {2-[4-(3-nitrophenyl)thiazol-2-yl]phenyl}carbamate

Acta Crystallographica Section E: Crystallographic Communications, 2016
The title compounds, C21H22N2O2S (I) and C18H15N3O4S (II), are structural analogs of the alkaloid Thiosporine B. Both molecules adopt a near-planar V-shaped conformation, which is consolidated by intramolecular N—H...N and C—H...O hydrogen bonds.
Elena V. Sukhonosova, Sergey A. Sokov, Gennady I. Ostapenko, Alexander S. Bunev, Pavel V. Dorovatovskii, Yan V. Zubavichus, Victor N. Khrustalev   +6 more
doaj   +1 more source

Tetranuclear Group 7/8 Mixed-Metal and Open Trinuclear Group 7 Metal Carbonyl Clusters Bearing Bridging 2-mercapto-1-methylimidazole Ligands [PDF]

, 2009
The reactivity of group 7 metal dinuclear carbonyl complexes [M2(CO)6(μ-SN2C4H5)2] (1, M = Re; 2, M = Mn) toward group 8 metal trinuclear carbonyl clusters were examined.
Bennett, Dennis W., Ghosh, Shishir, Haworth, Daniel T., Hossain, G. M. Golzar, Kabir, Shariff E., Lindeman, Sergey V., Pervin, Salina, Raha, Arun K., Roesky, Herbert W., Salassa, Luca, Siddiquee, Tasneem   +10 more
core   +1 more source

Synthesis and Coordination Compounds of A Bis(Imino)Acenaphthene (Bian)-Supported N-Heterocyclic Carbene [PDF]

, 2010
The bis(imino)acenaphthene-supported N-heterocyclic carbene IPr(BIAN) has been prepared by deprotonation of the precursor imidazolium chloride. Treatment of IPr(BIAN) imidazolium chloride with Ag(2)O afforded the silver complex [IPr(BIAN)]AgCl which can ...
Abernethy, Colin D., Butorac, Rachel R., Cowley, Alan H., Vasudevan, Kalyan V.   +3 more
core   +1 more source

Atomic Scale Engineering of Multivalence‐State Palladium Photocatalyst for Transfer Hydrogenation with Water as a Proton Source

Advanced Materials, EarlyView.
Photocatalytic transfer hydrogenation is achieved over a multivalence‐state palladium photocatalyst, in which protons generated from photocatalytic water splitting are added to unsaturated double bonds. The operando light‐induced Electron Paramagnetic Resonance (EPR) spectroscopy confirms the synergistic action between Pd single atoms and nanoparticles,
En Zhao, Wenjing Kong, Giorgio Zoppellaro, Yue Yang, Bing Nan, Lina Li, Wengjun Zhang, Zhaohui Chen, Aristides Bakandritsos, Zhu‐Jun Wang, Matthias Beller, Radek Zbořil, Zupeng Chen   +12 more
wiley   +1 more source

Polar Diels-Alder Reactions using Heterocycles as Electrophiles. Influence of Microwave Irradiation [PDF]

, 2015
In this work we studied a series of polar Diels-Alder reactions using different heterocycles derivatives acting as electrophiles joint to dienes of different nucleophilicity, analyzing the effect of the microwave irradiation in these processes. We employ
Della Rosa, Claudia Daniela, Kneeteman, Maria Nelida, López Baena, Anna Francesca, Mancini, Pedro Maximo Emilio   +3 more
core   +1 more source

Self‐Trapped Excitons Activate Pseudo‐Inert Basal Planes of 2D Organic Semiconductors for Improved Photocatalysis

Advanced Materials, EarlyView.
2D organic semiconductors are widely believed to have uniformly active surfaces. This study reveals that their basal planes can be pseudo‐inert due to anisotropic exciton migration. By inducing exciton self‐trapping through dimensional reduction, these inert planes are activated, boosting hydrogen peroxide production by over 350%. The work uncovers key
Jindi Yang, Xiangkang Zeng, Bicheng Zhu, Sharidya Rahman, Chuanbiao Bie, Ming Yong, Kaige Sun, Mike Tebyetekerwa, Zhuyuan Wang, Lijun Guo, Xin Sun, Yuan Kang, Lars Thomsen, Zhimeng Sun, Zhongguo Zhang, Xiwang Zhang   +15 more
wiley   +1 more source

1,1-Diphenyl-2-picrylhydrazyl and superoxide anion radical scavenging 1 activities of heterocyclic 2-oxo-1,2,3,4-tetrahydropyrimidines [PDF]

arXiv, 2023
To investigate1,1-Diphenyl-2-picrylhydrazyl (DPPH) and superoxide radical (SOR) 17 scavenging activities of 2-oxo-1,2,3,4-tetrahydropyrimidines derivatives. Free radicals are 18 highly unstable and reactive molecules/atoms. In the body, free radicals form during 19 normal and abnormal metabolism in the body and cause serious damage to other 20 ...
arxiv  

Bionanocomposite MIL-100(Fe)/Cellulose as a high-performance adsorbent for the adsorption of methylene blue

Scientific Reports
World production of dyes is estimated at more than 800,000 t·yr−1. The purpose of this research falls within the scope of the choice of an effective, local, and inexpensive adsorbent to remove dyes from wastewater.
Shahla Abbasi, Zahra Nezafat, Shahrzad Javanshir, Behzad Aghabarari   +3 more
doaj   +1 more source

Crystal structures of N-[(4-phenylthiazol-2-yl)carbamothioyl]benzamide and N-{[4-(4-bromophenyl)thiazol-2-yl]carbamothioyl}benzamide from synchrotron X-ray diffraction

Acta Crystallographica Section E: Crystallographic Communications, 2016
The title compounds, C17H13N3OS2, (I), and C17H12BrN3OS2, (II), are potential active pharmaceutical ingredients. Compound (I) comprises two almost planar fragments. The first is the central (carbamothioyl)amide (r.m.s.
Ekaterina S. Gantimurova, Alexander S. Bunev, Kristina Yu. Talina, Gennady I. Ostapenko, Pavel V. Dorovatovskii, Nikolai N. Lobanov, Victor N. Khrustalev   +6 more
doaj   +1 more source

GO supported Fe doped Ni(OH)2 hexagonal nanosheets for hydrogen evolution reaction in neutral electrolytes

Materials Research Express, 2021
Exploiting non-noble metals catalysts with excellent performance for hydrogen evolution reaction (HER) has aroused gigantic interest, but still challenges.
Junping Hu, Youxing Liu
doaj   +1 more source