Results 201 to 210 of about 176,899 (357)

A Novel Merocyanine Derivative for Probing Polarity at Cubosome Interfaces

open access: yesAsian Journal of Organic Chemistry, EarlyView.
This study develops a synthetic route to C10SP, a polarity‐sensitive sensor embedded in phytantriol‐based cubosomes. Strategic steps included tertiary amine‐mediated amidation to covalently attach a hydrophobic tail and controlled nitrogen methylation to form the iminium moiety within the indolenine scaffold.
Marcelo J. Eberhardt   +3 more
wiley   +1 more source

Kinetically Enhanced Access to a Dynamic Polyester Platform via Sequence Selective Terpolymerisation of Elemental Sulphur

open access: yesAngewandte Chemie, EarlyView.
A rare sequence‐selective terpolymerisation of elemental sulphur, aromatic thioanhydrides, and epoxides yields dynamic poly(ester‐alt‐Sx) polymers. Mechanistic insights reveal a lithium‐catalysed rate enhancement via ester coordination. The resulting polymers are thermally stable, backbone‐editable, and processable into degradable adhesives.
Cesare Gallizioli   +2 more
wiley   +2 more sources

Semi-synthesis and biological activities of heterocyclic compounds containing camphor. [PDF]

open access: yesRSC Adv
Hamza ZS   +6 more
europepmc   +1 more source

Heterocyclic Compounds as Hsp90 Inhibitors: A Perspective on Anticancer Applications. [PDF]

open access: yesPharmaceutics, 2022
Ardestani M   +5 more
europepmc   +1 more source

Synthesis of a Molecular Tweezer Based on Norbornadiene Framework: Unexpected Stereoselectivity

open access: yesAsian Journal of Organic Chemistry, EarlyView.
A new type of Klarner's molecular tweezer was synthesized through annulation of an α‐amino ketone. Surprisingly, the reaction takes place stereoselectivity though the initial amino ketone is racemic. This tweezer comprises two near‐parallel flat aromatic rings as pincers, each bearing two methyl ester groups, and a pyrazine unit as the tether ...
Evren Cücü   +3 more
wiley   +1 more source

Conformational Change in a Four‐Tetrad DNA G‐Quadruplex upon Intercalation of a Small‐Molecule Ligand PyDH2

open access: yesAngewandte Chemie, EarlyView.
An exception or the rule? This work represents a second observation, and the first crystallographic evidence, of true intercalation of a small‐molecule ligand (here, bisquinolinium PyDH2) into an antiparallel G‐quadruplex (G4) DNA fold. Abstract G‐quadruplexes (G4s) are non‐canonical DNA structures implicated in a number of biological processes.
Kailey N. Martin   +7 more
wiley   +2 more sources

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