Results 301 to 310 of about 176,899 (357)

Red‐Light‐Mediated Generation of Radicals: Applications in Organic Synthesis, Small‐Molecule Activation, Polymerization, and Bio‐Related Fields

open access: yesAngewandte Chemie International Edition, Accepted Article.
The field of visible light‐mediated photochemistry has experienced significant growth, leading to the development of a wide array of methodologies in synthetic organic chemistry. In particular, photocatalysis by using long‐wavelength light such as red and near‐infrared (NIR) light has garnered substantial attention recently.
Tong Zhang, Suman Pradhan, Shoubhik Das
wiley   +1 more source

A Platform for the Development of Highly Red‐Shifted Azobenzene‐based Optical Tools

open access: yesAngewandte Chemie International Edition, Accepted Article.
Azobenzenes are versatile photoswitches that can be used to generate elaborate optical tools including photopharmaceuticals. However, the targeted application‐guided design of new photoswitches with specific properties remains challenging. We have developed synthetic protocols for derivatives of the dfdc (di‐ortho‐fluoro‐di‐ortho‐chloro) azobenzene ...
Kyra Lützel   +17 more
wiley   +1 more source

The Flexibility of Tetra(N‐Heterocyclic Carbene) Ligands Controls the Nuclearity and Geometry of Polynuclear MI‒NHC Assemblies

open access: yesAngewandte Chemie International Edition, EarlyView.
Tetracarbene ligands composed of two di(phenylimidazol‐2‐ylidene)amine groups linked by an anthracene bridge exhibit restricted rotation of the Cphenyl─N─Cphenyl plane relative to the anthracene moiety if the N(Ph─NHC)2 moieties are directly attached to anthracene.
Guang‐Feng Jin   +3 more
wiley   +1 more source

Coordinative Ring‐Opening Polymerization of Limonene Carbamate towards Phosgene‐ and Isocyanate‐Free Polyurethane

open access: yesAngewandte Chemie International Edition, Accepted Article.
This study presents a phosgene‐ and isocyanate‐free route for the synthesis of polyurethanes using (R)‐limonene as a bio‐based starting material. The synthesis of the cyclic limonene‐based carbamate monomer LU is achieved in high yields using dimethyl carbonate as a sustainable, less hazardous phosgene surrogate and is verified by NMR, SC‐XRD, ESI‐MS ...
Jonas Futter   +4 more
wiley   +1 more source

Photocatalytic Hydrogenation of Quinolines to Form 1,2,3,4‐Tetrahdyroquinolines Using Water as the Hydrogen Atom Donor

open access: yesAngewandte Chemie International Edition, EarlyView.
A sequential process combining hydrogenation and a subsequent stereomutation is presented for trans selective hydrogenation of quinolines using water as the hydrogen atom source. Mechanistic studies reveal that the hydrogenation proceeds through a cascade process comprising an initial cis selective photocatalytic hydrogenation of the heteroarene core ...
Jingjing Zhang   +6 more
wiley   +1 more source

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