Results 81 to 90 of about 108,077 (187)

Iridium-Catalyzed Coupling Reaction of Primary Alcohols with 1-Aryl-1-propynes Leading to Secondary Homoallylic Alcohols

, 2016
We report iridium-catalyzed coupling of 2-alkynes such as 1-aryl-1-propynes with primary alcohols leading to secondary homoallylic alcohols as products.
Yasutaka Ishii (2209069), Shintaro Hatanaka (2358898), Yasushi Obora (1566208)   +2 more
core   +1 more source

Photoredox/Cr-catalyzed enantioselective radical-polar crossover transformation via C-H functionalization

Nature Communications
Asymmetric multicomponent reactions that aim to control multiple chiral centers with high selectivity in a single step remain an on-gonging challenge.
Si-Yuan Tang, Zhan-Jie Wang, Yu Ao, Ning Wang, Huan-Ming Huang   +4 more
doaj   +1 more source

Intramolecular Hydrosilylation and Silicon-Assisted Cross-Coupling:  An Efficient Route to Trisubstituted Homoallylic Alcohols

, 2016
Alkylidenesilacyclopentanes (formed by intramolecular hydrosilylation of homopropargyl alcohols) are efficiently coupled with aryl or alkenyl halides in the presence of tetrabutylammonium fluoride and a palladium(0) catalyst.
Weitao Pan (3000558), Scott E. Denmark (1310370)   +1 more
core   +1 more source

Vanadium-Catalyzed Asymmetric Epoxidation of Homoallylic Alcohols [J. Am. Chem. Soc. 2007, 129, 286−287].

, 2016
Vanadium-Catalyzed Asymmetric Epoxidation of Homoallylic Alcohols [J. Am. Chem. Soc. 2007, 129, 286−287]
Wei Zhang (405), Hisashi Yamamoto (1306170)   +1 more
core   +1 more source

One-Pot Sequential Deoximation and Allylation Reactions of Aldoximes in Aqueous Solution

, 2013
[[abstract]]A simple procedure has been developed for conducting tin-mediated deoximation and allylation reactions of aldoximes in water to form homoallylic alcohols.
Lin, Mei-Huey; Lin, Long-Zhi; Chuang, Tsung-Hsun; Liu, Han-Jun
core  

Facile and efficient synthesis of homoallylic alcohols using allyl bromide and commercial zinc dust

, 1995
An efficient procedure for the preparation of homoallylic alcohols has been achieved by a simple reaction of an aldehyde or a ketone with allyl bromide and commercial zinc dust in ...
Ranu, Brindaban C., Majee, Adinath, Das, Asish R.   +2 more
core   +1 more source

Palladium-Catalyzed Anti-Markovnikov Hydroalkylation of Homoallylic Alcohols Bearing β‑Fluorines

, 2016
A palladium-catalyzed anti-Markovnikov hydroalkylation of β,β-difluorinated homoallylic alcohols with alkylzinc reagents has been developed. This method affords a wide range of synthetically useful gem-difluorinated compounds with good functional group ...
Feng-Ling Qing (1308318), Xiaowei Lin (1916167)   +1 more
core   +1 more source

Preparation of aromatic geraniol analogues via a Cu(I)-mediated Grignard coupling

Journal of the Brazilian Chemical Society, 2003
Difunctional allylic terpenes are important synthetic building blocks. Functionalization of protected geranyl derivatives by SeO2/t-BuO2H adsorbed on SiO2 provides a convenient route to such compounds.
Paz J. Luis, Rodrigues J. Augusto R.
doaj  

Base-Promoted C-C Bond Activation Enables Radical Allylation with Homoallylic Alcohols. [PDF]

J Am Chem Soc, 2020
Lübbesmeyer M, Mackay EG, Raycroft MAR, Elfert J, Pratt DA, Studer A.   +5 more
europepmc   +1 more source

A Catalytic Approach for Enantioselective Synthesis of Homoallylic Alcohols Bearing a Z-Alkenyl Chloride or Trifluoromethyl Group. A Concise and Protecting Group-Free Synthesis of Mycothiazole. [PDF]

J Am Chem Soc, 2020
Morrison RJ, van der Mei FW, Romiti F, Hoveyda AH.   +3 more
europepmc   +1 more source