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Biomimetic Catalytic Remote Desaturation of Aliphatic Alcohols. [PDF]

open access: yesOrg Lett
Zuo K   +5 more
europepmc   +1 more source

Nickel-Catalyzed Isomerization of Homoallylic Alcohols

Organic Letters, 2023
Nickel-catalyzed isomerizations of homoallylic alcohols and a bishomoallylic alcohol are presented. These isomerization reactions occur in the presence of a simple nickel catalyst that does not require addition of an exogenous ligand. The corresponding ketone products are generated in ≤98% yield.
Dustin D. Youmans   +2 more
openaire   +2 more sources

Oxidation of homoallyl alcohols

Bulletin of the Academy of Sciences of the USSR Division of Chemical Science, 1986
1. Parallel polymerization (10–20%) and oxidative-degradation (20–40%) reactions occur during oxidation of diallylcarbinol and related compounds to ketones. 2. The optimal oxidizing agents for diallylcarbinol are chromic acid in a two-phase system, moist PCC, and DMSO/PBr3.
I. A. Korshevets, E. A. Mistryukov
openaire   +1 more source

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