Substitutive Approach Toward Heteroaromatic Amino Alcohols Accessed Through Dioxolanyl Radical Linchpin. [PDF]
Chang JJ +4 more
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Stereoselective Synthesis and Functionalization of Acetylenic Boronic Esters. [PDF]
Schäfer P, Kazmaier U.
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Electrochemical deoxygenative trifluoromethylallenylation of propargylic alcohols <i>via</i> sodium-mediated pre-association. [PDF]
Jang J, Kim H, Cho EJ.
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Copper-Catalyzed Three-Component Selective 1,4-Amino Oxygenation of 1,3-Dienes. [PDF]
Feng G, Velopolcek MK, Wang Q.
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Photochemical carboborylation and three-component difunctionalization of α,β-unsaturated ketones with boronic acids via tosylhydrazones. [PDF]
Valdés-Maqueda Á, Plaza M, Valdés C.
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Biomimetic Catalytic Remote Desaturation of Aliphatic Alcohols. [PDF]
Zuo K +5 more
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2,6-Dioxabicyclo[3.3.1]nonan-3-ones: from natural product treasure troves to synthetic triumphs. [PDF]
Choudhury UM, Das PP, Mohapatra DK.
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Catalytic Oxidative Ligand Transfer of Rh-Carbynoids and Alkyl Iodides. [PDF]
Esteve Guasch J, Pal D, Suero MG.
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Nickel-Catalyzed Isomerization of Homoallylic Alcohols
Organic Letters, 2023Nickel-catalyzed isomerizations of homoallylic alcohols and a bishomoallylic alcohol are presented. These isomerization reactions occur in the presence of a simple nickel catalyst that does not require addition of an exogenous ligand. The corresponding ketone products are generated in ≤98% yield.
Dustin D. Youmans +2 more
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Oxidation of homoallyl alcohols
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science, 19861. Parallel polymerization (10–20%) and oxidative-degradation (20–40%) reactions occur during oxidation of diallylcarbinol and related compounds to ketones. 2. The optimal oxidizing agents for diallylcarbinol are chromic acid in a two-phase system, moist PCC, and DMSO/PBr3.
I. A. Korshevets, E. A. Mistryukov
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