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Homogeneous Catalysis for Sustainable Energy: Hydrogen and Methanol Economies, Fuels from Biomass, and Related Topics. [PDF]

open access: yesChem Rev, 2022
As the world pledges to significantly cut carbon emissions, the demand for sustainable and clean energy has now become more important than ever. This includes both production and storage of energy carriers, a majority of which involve catalytic reactions.
Kumar A, Daw P, Milstein D.
europepmc   +2 more sources

Homogeneous Catalysis and Heterogeneous Recycling: A Simple Zn(II) Catalyst for Green Fatty Acid Esterification. [PDF]

open access: yesACS Sustain Chem Eng, 2021
This work describes the use of simple zinc(II) salts (ZnCl2, ZnCO3, Zn(OAc)2, ZnO, Zn(ClO4)2, Zn(TfO)2, and Zn(BF4)2) as effective catalysts for the esterification of fatty acids with long-chain alcohols and simple polyols through a homogeneous system ...
Melchiorre M   +6 more
europepmc   +2 more sources

Special Issue: “Advances in Homogeneous Catalysis” [PDF]

open access: yesMolecules, 2020
The use of enzymes, organo-catalysts or transition metal catalysts, as opposed to the employment of stoichiometric quantities of other traditional promoters of different organic synthetic processes (like, inorganic/organic bases, Brønsted acids ...
Joaquín García-Álvarez
doaj   +2 more sources

AI Approaches to Homogeneous Catalysis with Transition Metal Complexes. [PDF]

open access: yesACS Catal
Artificial intelligence (AI) is transforming research in chemistry, including homogeneous catalysis with transition metals. Over the past 15 years, the number of publications combining AI with catalysis has increased exponentially, reflecting the ...
Morán-González L   +3 more
europepmc   +2 more sources

Added Complexity!—Mechanistic Aspects of Heterobimetallic Complexes for Application in Homogeneous Catalysis [PDF]

open access: yesMolecules, 2023
Inspired by multimetallic assemblies and their role in enzyme catalysis, chemists have developed a plethora of heterobimetallic complexes for application in homogeneous catalysis.
Zeno Fickenscher, Evamarie Hey-Hawkins
doaj   +2 more sources

Designing Sites in Heterogeneous Catalysis: Are We Reaching Selectivities Competitive With Those of Homogeneous Catalysts?

open access: greenChemical Reviews, 2022
A critical review of different prominent nanotechnologies adapted to catalysis is provided, with focus on how they contribute to the improvement of selectivity in heterogeneous catalysis.
F. Zaera
semanticscholar   +3 more sources

Ylide-Functionalized Phosphines: Strong Donor Ligands for Homogeneous Catalysis. [PDF]

open access: yesAngew Chem Int Ed Engl, 2018
Phosphines are important ligands in homogenous catalysis and have been crucial for many advances, such as in cross‐coupling, hydrofunctionalization, or hydrogenation reactions. Herein we report the synthesis and application of a novel class of phosphines
Scherpf T   +5 more
europepmc   +2 more sources

Homogeneous catalysis in continuous flow integrating photocatalysis, electrocatalysis, and automation technologies [PDF]

open access: yesCommunications Chemistry
In recent years, homogeneous catalysis in continuous flow has undergone remarkable advances, driving significant progress across a broad range of chemical transformations.
Laura F. Peña   +4 more
doaj   +2 more sources

Self-assembled coordination thioether silver(I) macrocyclic complexes for homogeneous catalysis [PDF]

open access: yesBeilstein Journal of Organic Chemistry, 2019
The bis-ortho-thioether 9,10-bis[(o-methylthio)phenyl]anthracene was synthesized as a syn-atropisomer, as revealed by X-ray diffraction. This alkylaryl thioether ligand (L) formed different macrocyclic complexes by coordination with silver(I) salts ...
Zhen Cao   +3 more
doaj   +2 more sources

Towards Surface-Enhanced Homogeneous Catalysis: Tailoring the Enrichment of Metal Complexes at Ionic Liquid Surfaces. [PDF]

open access: greenAngew Chem Int Ed Engl
Hemmeter D   +7 more
europepmc   +2 more sources

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