Results 11 to 20 of about 655,886 (294)

Dynamics of homogeneous nucleation [PDF]

open access: yesThe Journal of Chemical Physics, 2015
The classical nucleation theory for homogeneous nucleation is formulated as a theory for a density fluctuation in a supersaturated gas at a given temperature. But molecular dynamics simulations reveal that it is small cold clusters which initiates the nucleation.
Toxværd, Søren, Søren Toxvaerd
openaire   +5 more sources

Homogeneous nucleation of ethanol [PDF]

open access: yesThe Journal of Chemical Physics, 1982
The authors have used an expansion cloud chamber to measure homogeneous nucleation rate as a function of temperature and supersaturation in ethanol. Nucleation rates from 102 to 105 drops/cm3 sec were measured in the temperature range 252–272 °K. An empirical functional fit to the data is used to extrapolate for comparison with other data in the ...
J. L. Schmitt   +2 more
openaire   +2 more sources

Homogeneous crystal nucleation in polymers [PDF]

open access: yesJournal of Physics: Condensed Matter, 2017
Abstract The pathway of crystal nucleation significantly influences the structure and properties of semi-crystalline polymers. Crystal nucleation is normally heterogeneous at low supercooling, and homogeneous at high supercooling, of the polymer melt.
C Schick, R Androsch, J W P Schmelzer
openaire   +3 more sources

Homogeneous Nucleation in Water in Microfluidic Channels [PDF]

open access: yesPhysical Review Letters, 2012
It has been an experimental challenge to test the rupture of liquids with homogeneous nucleation of vapor bubbles. Many prior studies suffered from the ubiquitous presence of impurities in liquids or at container surfaces that spontaneously nucleate and grow under tension. Here, we propose a microfluidic approach to eliminate such impurities and obtain
Ando, Keita   +2 more
openaire   +4 more sources

Homogeneous nucleation of toluene [PDF]

open access: yesThe Journal of Chemical Physics, 1983
The authors have used a fast expansion chamber to measure the homogeneous nucleation rate of toluene as a function of temperature and supersaturation. The measured nucleation rate ranges from 102 to 105 drops/cm3 s over a temperature range of 215–267 K. The measurements are compared with the ‘‘classical’’ nucleation theory and with the RKC theory.
J. L. Schmitt   +2 more
openaire   +2 more sources

Ice nucleation under cirrus cloud conditions [PDF]

open access: yes, 2012
Cirrus are thin upper tropospheric clouds that are composed entirely of ice particles. Due to their extensive coverage of the Earth’s surface, they have a significant impact on the Earth’s radiative balance.
Wilson, Theodore W
core   +6 more sources

The homogeneous nucleation of nonane [PDF]

open access: yesThe Journal of Chemical Physics, 1984
The homogeneous nucleation rate of n-nonane has been measured as a function of temperature and supersaturation ratio in a precision fast-expansion chamber. The measured nucleation rate ranges from 102 to 105 drops/cm3 over the temperature range 215–270 K.
G. W. Adams   +2 more
openaire   +2 more sources

Igniting homogeneous nucleation [PDF]

open access: yesPhysical Review E, 2005
Transient homogeneous nucleation is studied in the limit of large critical sizes. Starting from pure monomers, three eras of transient nucleation are characterized in the classic Becker-Döring kinetic equations with two different models of discrete diffusivity: the classic Turnbull-Fisher formula and an expression describing thermally driven growth of ...
Carpio Rodríguez, Ana María   +2 more
openaire   +4 more sources

Homogeneous Nucleation of Epitaxial CoSi2 and NiSi in Si Nanowires

open access: yes, 2016
Homogeneous nucleation is rare except in theory. We observed repeating events of homogeneous nucleation in epitaxial growth of CoSi2 and NiSi silicides in nanowires of silicon by using high resolution TEM. The growth of every single atomic layer requires
Yi-Chia Chou (1587535)   +3 more
core   +5 more sources

Homogeneous nucleation of NAD and NAT in liquid stratospheric aerosols: insufficient to explain denitrification [PDF]

open access: yes, 2002
Knopf DA, Koop T, Luo BP, Weers UG, Peter T. Homogeneous nucleation of NAD and NAT in liquid stratospheric aerosols: insufficient to explain denitrification. ATMOSPHERIC CHEMISTRY AND PHYSICS. 2002;2(3):207-214.The nucleation of NAD and NAT from HNO3/H2O
U. G. Weers   +10 more
core   +2 more sources

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