Results 151 to 160 of about 4,167,476 (238)

Sidechain Modulation of Responsive Metal‐Organic Framework Pore Chirality for Enhanced Enantioseparation

Angewandte Chemie, EarlyView.
[Zn2(L‐ValPyr)2] is a chiral and flexible metal‐organic framework that places the isopropyl sidechains of L‐valine inside the pores, creating accessible space in the shape of a three‐blade propeller. The framework adapts its structure to position the substituted aromatic guests in its peripheral pockets through favorable interactions with the isopropyl
Luke A. Johnson, Laurence J. Kershaw Cook, Bhupendra P. Mali, Datta Markad, Nikos Panagiotou, Dmytro Antypov, Alexandros P. Katsoulidis, Matthew J. Rosseinsky   +7 more
wiley   +2 more sources

Remote Electrostatic Effect between Octahedral Ru/Ir‐Complexes and Aromatic Micelles to Improve Their Photofunctions in Water

Angewandte Chemie, EarlyView.
The aqueous‐state encapsulation of cationic Ru(II)/Ir(III)‐complexes is efficiently demonstrated by anionic aromatic micelles via remote electrostatic interactions. The resulting host–guest composites exhibit enhanced metal‐complex‐based emission (∼3 to 10‐fold) and NIR emission through guest‐to‐guest FRET upon co‐encapsulation.
Rina Morooka, Yuya Tanaka, Michito Yoshizawa   +2 more
wiley   +2 more sources

Expanding the Chemical Space of Analytes in the 2G Crystalline Sponge Method: Size‐Compensation Strategy for the Structural Analysis of Low‐Polarity Small Molecules

Angewandte Chemie, EarlyView.
The accessible chemical space of second‐generation crystalline sponges (2G‐CSs) is extended to low‐polarity small molecules via a modulator‐enabled strategy. The key is the size compensation between guest and modulator to achieve a snug fit within the cage cavity.
Wei He, Luc Soliman, Hiroki Takezawa, Makoto Fujita   +3 more
wiley   +2 more sources

Energy Transfer‐Mediated Magnetoluminescence of an Octahedral MnII Complex Ligated With Bis(Diphenylphosphino)Methane Dioxide

Angewandte Chemie, EarlyView.
Energy‐transfer‐mediated magnetoluminescence of paramagnetic transition metal complexes: dope solids of an octahedral MnII complex into the corresponding ZnII complex exhibited a pronounced magnetic field response of emission spectra under the application of magnetic fields.
Asato Mizuno, Takuto Mibu, Ryota Matsuoka, Takema Hikawa, Shojiro Kimura, Tetsuro Kusamoto   +5 more
wiley   +2 more sources

Cavity-Containing [Fe₂L₃]⁴⁺ Helicates: An Examination of Host-Guest Chemistry and Cytotoxicity. [PDF]

Front Chem, 2021
Lisboa LS, Riisom M, Vasdev RAS, Jamieson SMF, Wright LJ, Hartinger CG, Crowley JD.   +6 more
europepmc   +1 more source

Aktivierung von Metallkomplexen durch Ultraschallwellen für eine gezielte Krebstherapie

Angewandte Chemie, EarlyView.
Ultrasound enables non‐invasive activation of metal‐based therapeutics deep within tumors. Acoustic cavitation can drive sonodynamic reactive oxygen species generation or mechanochemical metal–ligand bond dissociation, enabling controlled release of bioactive payloads.
Félix Grosjean, Nicolás Montesdeoca, Gilles Berger, Johannes Karges   +3 more
wiley   +1 more source

Photoswitchable Ambiphilicity: Light‐Gated Frustrated Lewis Pair Reactivity and Z‐Type Interaction

Angewandte Chemie, EarlyView.
Light‐controlled ambiphilicity is realized in photoswitchable intramolecular phosphorus/boron Lewis pairs. Reversible switching modulates both the thermodynamics and kinetics of frustrated Lewis‐pair reactivity, enabling light‐gated CO2 binding and release.
Lennart Stoess, Emil L. M. Paulin, Fabian Michel, Lutz Greb   +3 more
wiley   +2 more sources

Corrigendum: Cavity-Containing [Fe₂L₃]⁴⁺ Helicates: An Examination of Host-Guest Chemistry and Cytotoxicity. [PDF]

Front Chem, 2021
Lisboa LS, Riisom M, Vasdev RAS, Jamieson SMF, Wright LJ, Hartinger CG, Crowley JD.   +6 more
europepmc   +1 more source

Template‐Encoded Assembly and Adaptive Function in Selenium‐Based Molybdenum Chalcoxide Rings

Angewandte Chemie, EarlyView.
External templates write structural information into Se‐containing molybdenum rings, while selenium's softness confers adaptive host–guest behaviour and catalytic responsiveness, an integrated framework for programmable inorganic function. ABSTRACT Controlling both structure and function in inorganic self‐assembly remains a major challenge.
Giulia Pellegrino, Alexander Elliott, Yu‐Fei Song, Nuno A. G. Bandeira, Haralampos N. Miras   +4 more
wiley   +2 more sources

Higher-order assembly of BSA gold nanoclusters using supramolecular host-guest chemistry: a 40% absolute fluorescence quantum yield. [PDF]

Nanoscale Adv, 2022
Maity A, Kumar A.
europepmc   +1 more source