Results 71 to 80 of about 18,390 (240)

EPR Spectroscopy: A Powerful Tool to Analyze Supramolecular Host•Guest Complexes of Stable Radicals with Cucurbiturils

Molecules, 2020
Stable organic free radicals are increasingly studied compounds due to the multiple and unusual properties imparted by the single electron(s). However, being paramagnetic, classical methods such as NMR spectroscopy can hardly be used due to relaxation ...
Fengbo Liu, Hakim Karoui, Antal Rockenbauer, Simin Liu, Olivier Ouari, David Bardelang   +5 more
doaj   +1 more source

High‐Power Rapid Laser‐Induced Synthesis of Multi‐functional Cobalt Metal‐Organic Framework With an Unprecedented Synthesis Efficiency

Advanced Materials Technologies, EarlyView.
Laser‐assisted synthesis enables rapid (within 1 h) and high‐yield (≥90%) production of Co‐MOFs with mesoporous structures, tunable magnetic and optical properties, and efficient adsorption of N2, CH4, and CO2 for low‐energy gas separation. DFT calculations elucidate the electronic structure and adsorption behavior.
Saliha Mutlu, Bülend Ortaç, Ali Karatutlu, Taylan Gorkan, Engin Durgun, Dilek Soyler, Saniye Soylemez, Jelena Lillepäg, Volkan Filiz, Nergis Arsu, Sevil Savaskan Yilmaz   +10 more
wiley   +1 more source

Charge-transfer complexation of coordination cages for enhanced photochromism and photocatalysis

Nature Communications
Intensified host-guest electronic interplay within stable metal-organic cages (MOCs) presents great opportunities for applications in stimuli response and photocatalysis. Zr-MOCs represent a type of robust discrete hosts for such a design, but their host-
Gen Li, Zelin Du, Chao Wu, Yawei Liu, Yan Xu, Roy Lavendomme, Shihang Liang, En-Qing Gao, Dawei Zhang   +8 more
doaj   +1 more source

Mitigating Efficiency Roll‐Off in Phosphor‐Sensitized Fluorescence OLEDs via Molecular Polarity‐Based Benzofuropyridine Host Engineering

Advanced Optical Materials, EarlyView.
Positional isomerism in dibenzofuran‐based n‐type hosts modulates molecular polarity, charge‐transport balance, and emissive‐layer packing. The higher‐polarity BFPDB‐2 host facilitates efficient energy funneling, reduced aggregation, and preferential dipole orientation, leading to phosphor‐sensitized fluorescence OLEDs with enhanced external quantum ...
Nargis Ali, Xuyao Song, Yun‐Hi Kim, Min Chul Suh   +3 more
wiley   +1 more source

Applications of Cucurbiturils in Medicinal Chemistry and Chemical Biology

Frontiers in Chemistry, 2019
The supramolecular chemistry of cucurbit[n]urils (CBn) has been rapidly developing to encompass diverse medicinal applications, including drug formulation and delivery, controlled drug release, and sensing for bioanalytical purposes.
Debapratim Das, Khaleel I. Assaf, Khaleel I. Assaf, Werner M. Nau   +3 more
doaj   +1 more source

Naphthyridine‐Based Donor–Acceptor Boron Difluoride Complexes Targeting Red Emission in Organic Light‐Emitting Diodes

Advanced Optical Materials, EarlyView.
Four donor–acceptor boron difluoride complexes based on triphenylamine donor and a naphthyridine acceptor units were synthesized, studied, and applied as OLED emitters. They exhibit pronounced intramolecular charge transfer character, balanced charge transport properties, and tunable emission. Near‐unity PLQYs are achieved for selected compounds, while
Omar Lahna, Stepan Kutsiy, Dmytro Volyniuk, Roman Luboradzki, Elina Andresen, Ute Resch‐Genger, Juozas V. Grazulevicius, Pavlo Stakhira, Mykhaylo A. Potopnyk   +8 more
wiley   +1 more source

Red Fluorescent Protein‐Metal Organic Framework Hybrids for Lighting Applications

Advanced Optical Materials, EarlyView.
We demonstrate the encapsulation in a metal‐organic framework (MOF) of two red fluorescent proteins, DsRed and mCherry. The materials conserve all spectroscopical and structural properties of the underlying components, which allows for their implementation as color down‐converting materials in bio‐hybrid light‐emitting diodes, which exhibit average 3 ...
David Gutiérrez‐Armayor, Youssef Atoini, Rubén D. Costa   +2 more
wiley   +1 more source

Supramolecular nanotherapeutics based on cucurbiturils

Journal of Nanobiotechnology
Polymeric biomaterials have important applications in aiding clinical disease treatment, including drug delivery, bioimaging, and tissue engineering. Currently, conventional tumor chemotherapy faces obstacles such as poor solubility/stability, inability ...
Maiyier Muheyati, Guangheng Wu, Yilin Li, Ziting Pan, Yueyue Chen   +4 more
doaj   +1 more source

Circularly Polarized Red‐NIR Emission With High Dissymmetry Factor From Achiral [Mo6I8(OCOC2F5)6]2− Cluster Anion Embedded in a Bent‐Core Liquid Crystal Host

Advanced Optical Materials, EarlyView.
Associating a chiral bent core liquid crystal molecule, that self‐assembles into helical nanofilaments, with an achiral red‐NIR phosphorescent octahedral molybdenum cluster produces a hybrid material exhibiting efficient red‐NIR circularly polarized emission under UV excitation.
Jeanne Rebours, Shamima Akhter, Md Kamrul Hasan, Serge Paofai, Maria Amela‐Cortes, Marianne Estelle Prévôt, Yann Molard   +6 more
wiley   +1 more source

Fluorescence Resonance Energy Transfer Systems in Supramolecular Macrocyclic Chemistry

Molecules, 2017
The fabrication of smart materials is gradually becoming a research focus in nanotechnology and materials science. An important criterion of smart materials is the capacity of stimuli-responsiveness, while another lies in selective recognition ...
Xin-Yue Lou, Nan Song, Ying-Wei Yang
doaj   +1 more source