Results 111 to 120 of about 9,914 (265)

Strain and Band Modulation of WO3/SnSe Micro‐Nano Composites Achieving Superior Photocatalytic Performance

ENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
WO3/SnSe micro‐nano composites demonstrate exceptional photocatalytic performance through synergistic strain and band modulation. Lattice strain modulation enhances methyl orange adsorption and visible light absorption, while Z‐scheme band alignment promotes efficient charge separation. The 2.5% WO3/SnSe composite achieves 99.71% degradation efficiency,
Qinyuan Huang, Xiaoyan Ma, Xing Yang, Chongyu Wang, Quan Shan, Chunjian Wang, Fei Wang, Jing Feng, Zhenhua Ge, Lidong Zhao   +9 more
wiley   +1 more source

Asymmetric Dual‐Electron Bridge Via Gradient Orbital Coupling for Robust Alkaline Oxygen Evolution in Low‐Iridium Water Electrolysis

ENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
The engineered IrOx/FeEu‐NiTex composite, with ultralow Eu (0.72 at%) and Ir (0.14 at%) content, harnesses an asymmetric dual‐electron‐bridge structure (Ni 3d–O 2p–Eu 4f, Ni 3d–O 2p–Ir 5d) for gradient orbital coupling. This unique architecture delivers superior and robust alkaline oxygen evolution activity, enabling efficient low‐iridium water ...
Guiling Wu, Qianlin Chen, Feng Wang, Yan Zhao, Zhaoyang Wang   +4 more
wiley   +1 more source

Machine Learning Unveils Isolated‐Surrounded Pt Motifs in High‐Entropy Alloys for Superior Low‐Temperature Ammonia Oxidation

ENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
A physics‐informed machine learning approach successfully decodes the complex catalytic activity of high‐entropy alloys for ammonia oxidation. By revealing a synergistic mechanism involving lattice and electronic couplings, the study identifies a superior “isolated‐surrounded” platinum motif.
Shangfeng Jiang, Ting Tao, Kexiang Guo, Xinyu Fan, Xu Zhang, Zhen Zhou   +5 more
wiley   +1 more source

Trifluoroacetyl-Activated Nitrogen−Nitrogen Bond Cleavage of Hydrazines by Samarium(II) Iodide

, 2016
Trifluoroacetyl derivatives of hydrazines undergo clean and efficient reductive cleavage of the N−N bond with SmI2 in the presence of MeOH. After N-trifluoroacetylation, acyl-, aryl-, and alkyl-substituted hydrazines are reductively cleaved by this ...
Hui Ding (308976), Gregory K. Friestad (1581157)   +1 more
core   +1 more source

Chelation‐Assisted Metal‐Catalyzed Ligation and Cleavage Reactions for Chemical Biology

European Journal of Organic Chemistry, EarlyView.
Chelation‐assisted transition metal catalysis has emerged as a promising complement to bioorthogonal click chemistry for studying biological processes. By pre‐organizing catalytic metal centers, designed coordinating substrates enhance reactivity and biocompatibility, enabling site‐selective ligation and decaging reactions in complex biological media ...
Emilie Plantiveau, Maxime Riberaud, Frédéric Taran, Antoine Sallustrau   +3 more
wiley   +1 more source

Oxidative Heck Reaction of Glycals and Aryl Hydrazines: A Palladium-Catalyzed C‑Glycosylation

, 2016
An efficient Heck-type C-glycosylation of glycals via the C–N bond cleavage of aryl hydrazines has been developed. The flexibility of the reaction was tested by the substrate scope, consisting of glycals from different carbohydrate origins as well as ...
Le Mai Hoang Kim (1915654), Xue-Wei Liu (736285), Hongze Liao (1915657), Yaguang Bai (1915651)   +3 more
core   +1 more source

The Expanding Role of Diazirines in Synthetic Methodology

European Journal of Organic Chemistry, EarlyView.
Beyond their established role in photoaffinity labeling, diazirines have emerged as versatile reagents in synthetic chemistry. This review highlights their dual reactivity as carbene and nitrogen‐transfer precursors, showcasing mechanistic insights and diverse applications in cyclopropanations, cycloadditions, skeletal editing, amination, heterocycle ...
Viktor Savic, Dominik Schnalzer, Marko D. Mihovilovic, Michael Schnürch   +3 more
wiley   +1 more source

Selective N‐Functionalization of Pyrazoles

European Journal of Organic Chemistry, EarlyView.
This review traces the evolution of regioselective N‐functionalization strategies for pyrazoles, a key class of nitrogen heterocycles widely used in medicinal chemistry. Due to rapid tautomerism, N‐functionalization often lacks selectivity, leading to poor and unpredictable regioisomeric outcomes.
Lucas Popek, Matthias Schrader, Christopher J. Teskey   +2 more
wiley   +1 more source

Synthesis of Cysteine–Fluorophore Conjugates by Visible‐Light‐Promoted Thiol–Ene Coupling Using Organic Photocatalysts

European Journal of Organic Chemistry, EarlyView.
Cysteine–fluorophore conjugates were efficiently prepared through a visible‐light‐driven thiol–ene approach employing solely organic photocatalysts. The reaction proceeds under mild, metal‐free conditions. The fluorophore scope includes mono‐ and dialkene‐functionalized naphthalene, naphthalimide, and aromatic diimide derivatives.
Julieth Bellaizac‐Riascos, Pilar Ortiz‐Serna, Raúl Pérez‐Ruiz, Susana Encinas, M. Consuelo Jiménez   +4 more
wiley   +1 more source

Postsynthetic Modifications of Amide‐Enaminone‐Based [2]Rotaxanes for the Stereocontrolled Synthesis of Functionalized β‐Lactams

ChemistryEurope
Novel amido‐enaminone threads serve as efficient templates for the assembly of hydrogen‐bonded [2]rotaxanes, enabling versatile postsynthetic modifications.
Syed S. Razi, Isabel M. Perez‐Artigao, Mateo Alajarin, Alberto Martinez‐Cuezva, Jose Berna   +4 more
doaj   +1 more source