Results 131 to 140 of about 2,558 (239)

Postsynthetic Modifications of Amide‐Enaminone‐Based [2]Rotaxanes for the Stereocontrolled Synthesis of Functionalized β‐Lactams

open access: yesChemistryEurope
Novel amido‐enaminone threads serve as efficient templates for the assembly of hydrogen‐bonded [2]rotaxanes, enabling versatile postsynthetic modifications.
Syed S. Razi   +4 more
doaj   +1 more source

Strain and Band Modulation of WO3/SnSe Micro‐Nano Composites Achieving Superior Photocatalytic Performance

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
WO3/SnSe micro‐nano composites demonstrate exceptional photocatalytic performance through synergistic strain and band modulation. Lattice strain modulation enhances methyl orange adsorption and visible light absorption, while Z‐scheme band alignment promotes efficient charge separation. The 2.5% WO3/SnSe composite achieves 99.71% degradation efficiency,
Qinyuan Huang   +9 more
wiley   +1 more source

Asymmetric Dual‐Electron Bridge Via Gradient Orbital Coupling for Robust Alkaline Oxygen Evolution in Low‐Iridium Water Electrolysis

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
The engineered IrOx/FeEu‐NiTex composite, with ultralow Eu (0.72 at%) and Ir (0.14 at%) content, harnesses an asymmetric dual‐electron‐bridge structure (Ni 3d–O 2p–Eu 4f, Ni 3d–O 2p–Ir 5d) for gradient orbital coupling. This unique architecture delivers superior and robust alkaline oxygen evolution activity, enabling efficient low‐iridium water ...
Guiling Wu   +4 more
wiley   +1 more source

The N-H stretching frequency of substituted hydrazines

open access: yes, 1965
Thesis (M.A.)--Boston UniversityPLEASE NOTE: Boston University Libraries did not receive an Authorization To Manage form for this thesis or dissertation. It is therefore not openly accessible, though it may be available by request.
Saeed, Muhammad Ghaleb
core  

Gold(I)‐Mediated Reactivity of Allenes With Mesoionic Nucleophiles: A Computational Exploration

open access: yesEuropean Journal of Organic Chemistry, EarlyView.
The regioselective gold(I)‐mediated reactivity of allenes with mesoionic nucleophiles has been evaluated through computational analysis of the mechanisms involved. Instead of typical (3 + 2) pathways, sydnones and münchnones favour the formal (3 + 3) cyclizations affording substituted dihydropyridines.
Eduardo Garcia‐Padilla, Feliu Maseras
wiley   +1 more source

Mechanistic and Reactivity Insights into Diboron‐Mediated NN and NN Bond Scission

open access: yesEuropean Journal of Organic Chemistry, EarlyView.
This review highlights the emerging ability of diboron reagents to cleave both π‐bonded (N=N) and σ‐bonded (N—N) nitrogen–nitrogen linkages, integrating mechanistic understanding with recent synthetic applications. Diboron reagents have emerged as versatile reducing agents capable of transforming a broad range of functional groups through pathways like
Raúl Valderrama‐Callejón   +2 more
wiley   +1 more source

Syntheses of some N-substituted hydrazines by the anhydrous chloramine process

open access: yes, 1985
ClNH2, produced in the gas phase by the reaction of Cl2 and NH3, reacts with various primary and secondary amines in nonaq. solvents in the presence of a fixed base to form the corresponding N-substituted hydrazines.
Chellappa, D, Jain, SR
core  

Research progress on flexible MXene‐based materials in advanced energy storage devices: From preparation strategies to device applications

open access: yesFlexMat, EarlyView.
This review summarizes MXene synthesis and flexible electrode fabrication for FESDs, highlighting their potential owing to high conductivity and flexibility, and outlines future research directions. Abstract The rapid development of wearable and portable electronics has created demand for flexible energy storage systems (FESDs) that not only exhibit ...
Nanxi Miao   +10 more
wiley   +1 more source

Exploring variations in potential carbon and nitrogen mineralization in managed grasslands among the diversity of soils in North Carolina

open access: yesGrassland Research, EarlyView.
Under steady–state conditions, potential nitrogen mineralization in soil under grasslands is closely tied to potential carbon mineralization. This study provides supporting evidence that field–specific nitrogen fertilizer recommendations could be indicated by using a simple and rapid analysis of soil–test biological activity.
Alan J. Franzluebbers
wiley   +1 more source

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