Results 91 to 100 of about 5,572 (222)
A domino reaction for generating β-aryl aldehydes from alkynes by substrate recognition catalysis
Nature Communications, 2019 Supramolecular interactions may be responsible for higher degree of efficiency and selectivity in homogeneous catalysis. Here, the authors exploit the concept of supramolecular catalysis to develop a domino rhodium-catalyzed hydroformylation of α ...
Weiwei Fang +3 more
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Kinetic analysis of homogeneous catalytic reactions
, 2012 Reaction progress kinetic analysis (RPKA) is a powerful tool for determining kinetic parameters of catalytic reactions. Many of the published articles that have used RPKA have employed reaction calorimetry for obtaining sufficient data to be reliable ...
Robb, Lynzi M.
core
Nature Communications, 2019 Tuning the environment of catalytic active sites may improve the selectivity of heterogeneous catalysts. Here, the authors modify the outer-sphere environment of active sites in hydroformylation catalysts by encapsulating the active sites in nanovessels ...
Ke Dong +8 more
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The Hydroformylation of 2-Pentene-5,5,5-d3
CHIMIA, 1974 In the title reaction, at low pCO (5 at), rapid isomerisation of the substrate occurs and a random distribution of deuterium in the reaction products has been found.
Denis A. von Bézard +2 more
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, 2008 Rhodium nanoparticles have been conveniently synthesized by one-pot chemical reduction of aqueous rhodium chloride (RhCl3.3H(2)O) dispersed in toluene solution in the presence of amphiphilic tetraoctylammonium bromide (TOAB) and chiral (R)-BINAP at ...
Li, Xiaohong +6 more
core +1 more source
Beilstein Journal of Organic Chemistry, 2014 The capacity of two cavity-shaped ligands, HUGPHOS-1 and HUGPHOS-2, to generate exclusively singly phosphorus-ligated complexes, in which the cyclodextrin cavity tightly wraps around the metal centre, was explored with a number of late transition metal ...
Matthieu Jouffroy +6 more
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Small StructuresThe hydroformylation of alkenes is a cornerstone transformation for the chemical industry, central for both functionalizing and extending the carbon backbone of an alkene.
Arjun Neyyathala +7 more
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Study on catalysts and reaction process for highly selective hydroformylation of 1-octene
上海师范大学学报. 自然科学版Using rhodium dicarbonylacetylacetonate as the rhodium(Rh) catalyst precursor, the catalytic performances of different monodentate and bidentate phosphine ligands, bisphosphite ligands, and the self-synthesized ligand system Rh-L9 were investigated in ...
YANG Xushi +5 more
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Formation of 3-pentanone via ethylene hydroformylation over Coactivated carbon catalyst
, 2013 Formation of 3-pentanone via ethylene hydroformylation over Coactivated carbon ...
斐彦鹏 +7 more
core
Synthesis of (–)-Indolizidine 167B based on domino hydroformylation/cyclization reactions
Beilstein Journal of Organic Chemistry, 2008 The synthesis of (–)-Indolizidine 167B has been achieved from optically active (R)-3-(pyrrol-1-yl)hex-1-ene. The key step is a highly regioselective hydroformylation reaction and a one-pot intramolecular cyclization providing a general approach to the ...
Giuditta Guazzelli +2 more
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