Results 191 to 200 of about 102,510 (291)

Hydrogen Sulfide Metabolism in the Skin: From Physiology to Malignancy. [PDF]

Int J Mol Sci
Tampa M, Nicolae I, Mitran MI, Mitran CI, Matei C, Georgescu SR, Capusa C, Ene CD.   +7 more
europepmc   +1 more source

Decreased Plasma Concentration of Hydrogen Sulfide in Hospitalized COVID-19 Patients: A Novel Determinant of Mortality? [PDF]

Antioxidants (Basel)
Stranieri C, Di Leo EG, Danese E, Poffe R, Barbieri A, Pighi L, Randon A, Cominacini L, Fratta Pasini AM.   +8 more
europepmc   +1 more source

Positive Electrochemical Potentials Induce Enhanced Chemoselectivity and Activity in the Thermocatalytic Hydrogenation of 3‐Nitrostyrene

Angewandte Chemie, EarlyView.
Induced by positive electrochemical potentials, thermocatalytic hydrogenation (TCH) of 3‐nitrostyrene with H2 delivers one single product with six‐fold enhanced yield. The enhanced selectivity and activity originate from changes in the adsorption geometry of 3‐nitrostyrene and in the surface concentration of 3‐nitrostyrene and hydrogen via a concurrent
Yunfei Jiao, Martina A. Pogany, Murielle F. Delley   +2 more
wiley   +2 more sources

Involvement of cystathionine β-synthase in ATP-induced hydrogen sulfide production in cochlear outer hair cells. [PDF]

J Otol
Harada N, Ito Y, Takashima I, Ojida A, Sekiguchi F, Kawabata A.   +5 more
europepmc   +1 more source

A Crystalline and Thermally Stable Selenocysteine Selenenic Acid

Angewandte Chemie, EarlyView.
The long‐sought catalytic intermediate of selenoproteins, selenocysteine selenenic acid (Sec–SeOH), is isolated for the first time at ambient temperature. A bioinspired selenopeptide sequence encapsulated within a protective molecular cradle and an oxidant‐free route from selenenyl iodide (Sec–SeI) enable the isolation of Sec–SeOH. Contrary to the long‐
Ryosuke Masuda, Satoru Kuwano, Kei Goto
wiley   +2 more sources

Bioelectronic synthesis of hydrogen sulfide enables spatiotemporal regulation of protein modification and cellular redox. [PDF]

Sci Adv
Lim L, Lee C, Lee J, Lee M, Kim Y, Lee TK, Lee G, Kim J, Oh SY, Kim J, Park J.   +10 more
europepmc   +1 more source

Speciation‐Controlled C–F Bond Functionalization Enabled by Zwitterionic Pnictinidenes

Angewandte Chemie, EarlyView.
Zwitterionic pnictinidenes turn C–F activation into C–X bond construction, enabling broad defluorinative functionalization of polyfluoro(hetero)arenes under mild conditions. Rather than following a metallomimetic Sb(I)/Sb(III) redox turnover, catalysis is redirected by ligand scrambling into a redox‐neutral manifold, revealing catalyst speciation as a ...
Irene Sánchez‐Sordo, Sergio Fernandez, Selwin Fernando, Diego M. Andrada, Oriol Planas   +4 more
wiley   +2 more sources

Role of hydrogen sulfide in catalyzing the formation of NO-ferroheme. [PDF]

Nitric Oxide
Poudel L, Karunarathna T, Baker S, Alipour E, Dent MR, Tejero J, Gladwin MT, DeMartino AW, Kim-Shapiro DB.   +8 more
europepmc   +1 more source

Flavin Catalysts in Organic Synthesis

Angewandte Chemie, EarlyView.
Flavins and their congeners are potent catalysts for organic synthesis inspired by enzymatic transformations. In addition to catalysis in the flavin ground state via covalent intermediates, the excited singlet and triplet states unlock applications including photooxidation, photoreduction, and energy transfer via sensitization.
Jan Freudenberg, Golo Storch
wiley   +2 more sources

Changes in plasma hydrogen sulfide are associated with cognitive improvements in schizophrenia patients treated with atypical antipsychotics. [PDF]

Front Psychiatry
Huang YC, Li YH, Li L, Xiong JW, Wei B, Yang YJ, Zhao Y, Zhan HY.   +7 more
europepmc   +1 more source