Results 201 to 210 of about 102,510 (291)

Functionalization‐Mediated Synthesis of Bridge‐Coordinated Fe Atoms on MoS2 Nanosheets for PEM Water Electrolyzers

open access: yesAngewandte Chemie, EarlyView.
We report a functionalization‐mediated strategy to synthesize robust iron (Fe) atoms selectively coordinated at bridge sites on molybdenum disulfide (MoS2) nanosheets. The resulting b‐Fe‐MoS2 catalyst exhibits enhanced activity and durability for the hydrogen evolution reaction in proton exchange membrane water electrolyzers compared to atop ...
Zakaria Anfar   +13 more
wiley   +2 more sources

Hydrogen sulfide-dependent activation of human sulfide quinone oxidoreductase. [PDF]

open access: yesJ Biol Chem
Roman JV   +6 more
europepmc   +1 more source

An NHC‐Coordinated Silicon/Sulfur Analogue of an Acyl Carbene

open access: yesAngewandte Chemie, EarlyView.
An NHC complex of an Si/S analogue of an acyl carbene is synthesized by the reaction of a disilyne with a cyclic thiourea. The observed Si2S three‐membered ring with unsymmetrical Si─S distances and a Si─Si single bond is consistent with intramolecular coordination of the silathioacyl sulfur to the silylene center.
Takuto Toyooka   +2 more
wiley   +2 more sources

Inverse Vulcanization Through Epoxide Chemistry: A Low Temperature Non‐Olefin Route to Sulfur‐Rich Polymer Networks

open access: yesAngewandte Chemie, EarlyView.
Epoxide monomers undergo base‐catalyzed ring‐opening copolymerization with elemental sulfur to afford sulfur‐rich polymers under mild conditions. The resulting materials exhibit excellent mechanical performance, strong adhesion (up to 10 MPa on stainless steel), and outstanding reprocessability.
Pan Yang   +5 more
wiley   +2 more sources

Hydrogen sulfide alleviates hyperoxia effects on mitochondria in human developing airway smooth muscle. [PDF]

open access: yesJCI Insight
Bartman CM   +11 more
europepmc   +1 more source

Unlocking Zn‐Ion Diffusion in Disordered Rocksalt Cathodes for Nonaqueous Zn‐Ion Batteries

open access: yesAngewandte Chemie, EarlyView.
Developing viable cathode materials for multivalent battery chemistries is challenging due to the intrinsic sluggish diffusion kinetics. A disordered rocksalt oxide host was found to “lock” the cycling of zinc ions from nonaqueous electrolyte. We unlock zinc ion diffusion in the disordered rocksalt by introduction of a percolating vacancy network ...
Zixuan Li   +10 more
wiley   +2 more sources

Borylcyclopropanes: Synthetic Strategies and Applications

open access: yesAngewandte Chemie, EarlyView.
Borylcyclopropanes (cyclopropanes bearing a boron substituent) sit at the intersection of two privileged frameworks in synthesis. This review provides the first exhaustive survey of their chemistry, spanning metal–carbene, nucleophilic cyclization, radical, hydroboration, and C─H activation routes, and documenting applications in medicinal chemistry ...
Aiza A. Butt, Joseph M. Ready
wiley   +2 more sources

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