Results 201 to 210 of about 1,828,854 (335)

Hydrogen sulfide increases intracellular oxygen and inhibits the HIF response. [PDF]

open access: yesJ Biol Chem
Brake J   +8 more
europepmc   +1 more source

Positive Electrochemical Potentials Induce Enhanced Chemoselectivity and Activity in the Thermocatalytic Hydrogenation of 3‐Nitrostyrene

open access: yesAngewandte Chemie, EarlyView.
Induced by positive electrochemical potentials, thermocatalytic hydrogenation (TCH) of 3‐nitrostyrene with H2 delivers one single product with six‐fold enhanced yield. The enhanced selectivity and activity originate from changes in the adsorption geometry of 3‐nitrostyrene and in the surface concentration of 3‐nitrostyrene and hydrogen via a concurrent
Yunfei Jiao   +2 more
wiley   +2 more sources

A Crystalline and Thermally Stable Selenocysteine Selenenic Acid

open access: yesAngewandte Chemie, EarlyView.
The long‐sought catalytic intermediate of selenoproteins, selenocysteine selenenic acid (Sec–SeOH), is isolated for the first time at ambient temperature. A bioinspired selenopeptide sequence encapsulated within a protective molecular cradle and an oxidant‐free route from selenenyl iodide (Sec–SeI) enable the isolation of Sec–SeOH. Contrary to the long‐
Ryosuke Masuda, Satoru Kuwano, Kei Goto
wiley   +2 more sources

Inverse Vulcanization Through Epoxide Chemistry: A Low Temperature Non‐Olefin Route to Sulfur‐Rich Polymer Networks

open access: yesAngewandte Chemie, EarlyView.
Epoxide monomers undergo base‐catalyzed ring‐opening copolymerization with elemental sulfur to afford sulfur‐rich polymers under mild conditions. The resulting materials exhibit excellent mechanical performance, strong adhesion (up to 10 MPa on stainless steel), and outstanding reprocessability.
Pan Yang   +5 more
wiley   +2 more sources

Mesoporous N,S‐Dual‐Doped Carbon Nanoreactors via Entropy‐Driven Interface Self‐Assembly for Efficient H2O2 Electrosynthesis

open access: yesAngewandte Chemie, EarlyView.
An entropy‐driven interface self‐assembly strategy is proposed for the controllable synthesis of mesoporous N,S‐dual‐doped carbon nanoreactors. The N,S‐dual‐doping sites optimized the *OOH adsorption, boosting the 2e− selectivity, while the favorable mesostructure accelerated O2 enrichment.
Fei Liu   +6 more
wiley   +2 more sources

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