Results 11 to 20 of about 119,307 (312)

eHydrogenation: Hydrogen‐free Electrochemical Hydrogenation

open access: yesAngewandte Chemie International Edition, 2023
AbstractHydrogenation reactions are staple transformations commonly used across scientific fields to synthesise pharmaceuticals, natural products, and various functional materials. However, the vast majority of these reactions require the use of a toxic and costly catalyst leading to unpractical, hazardous and often functionally limited conditions ...
Camilla Russo   +13 more
openaire   +5 more sources

Metallic hydrogen [PDF]

open access: yesJournal of Physics: Condensed Matter, 2018
Abstract Hydrogen is the simplest and most abundant element in the Universe. There are two pathways for creating metallic hydrogen under high pressures. Over 80 years ago Wigner and Huntington predicted that if solid molecular hydrogen was sufficiently compressed in the T   =
Ranga Dias, Isaac Silvera
openaire   +2 more sources

Ionization of Hydrogen and Hydrogenic Ions by Antiprotons [PDF]

open access: yesPhysical Review Letters, 1996
Presented here is a description of the ionization of hydrogen and hydrogenic ions by antiproton-impact, based on very large scale numerical solutions of the time-dependent Schrödinger equation in three spatial dimensions and on analysis of the topology of the electronic eigenenergy surfaces in the plane of complex internuclear distance.
Schultz, D. R.   +3 more
openaire   +3 more sources

Developments in the hydrogenation of challenging substrates utilising transition metal complexes [PDF]

open access: yes, 2014
This thesis describes the developments of new protocols for the hydrogenation of challenging substrates. Three specific substrates were highlighted for study after an initial review of the literature; benzofurans, esters and bulky ketones.
Ian Carpenter, Carpenter, Ian
core   +2 more sources

Hydrogen [PDF]

open access: yesMaterials, 2011
The idea of a “Hydrogen Economy” is that carbon containing fuels should be replaced by hydrogen, thus eliminating air pollution and growth of CO2 in the atmosphere. However, storage of a gas, its transport and reconversion to electricity doubles the cost of H2 from the electrolyzer.
openaire   +2 more sources

Synthetic and mechanistic investigations of iridium-catalysed imine hydrogenation [PDF]

open access: yes, 2013
Chiral amines occur as structural elements in many biologically active natural and unnatural products. In addition, they find applications as chiral auxiliaries, catalysts, and resolving agents.
Schramm, York
core   +1 more source

An Operando Nuclear Magnetic Resonance Study on Solid-Liquid-Gas Heterogeneous Benzene Hydrogenation Reaction

open access: yesChinese Journal of Magnetic Resonance, 2021
The reaction of heterogeneous benzene hydrogenation reaction in a real solid-liquid-gas environment was studied by operando nuclear magnetic resonance (NMR) spectroscopy.
Song SUI   +4 more
doaj   +1 more source

Hydrogenation of unactivated enamines to tertiary amines : rhodium complexes of fluorinated phosphines give marked improvements in catalytic activity [PDF]

open access: yes, 2015
Date of Acceptance: 16/04/2015In the hydrogenation of sluggish unactivated enamine substrates, Rh complexes of electron-deficient phosphines are demonstrated to be far more reactive catalysts than those derived from triphenylphosphine.
Matthew L. Clarke   +6 more
core   +1 more source

Hydrogenation of styrene-isoprene-styrene block copolymer and its product properties

open access: yesHecheng xiangjiao gongye, 2021
The hydrogenation of styrene-isoprene-styrene block copolymer(SIS) was catalyzed by nickel-based catalyst, and the mechanism of catalytic reaction was studied.
LIANG Ai-min
doaj   +1 more source

Iridium-Catalyzed asymmetric hydrogenation : A: Studies on the synthesis of pyrazine-based P,N Ligands, B: Diastereoselective hydrogenation of chiral cyclohexenes [PDF]

open access: yes, 2016
The synthesis of a new ligand class of pyrazine based ligands and their attempted complexation with iridium to form dimeric complexes is presented. Furthermore, the synthesis of chiral cyclohexenes by enantioselective Diels-Alder reactions is shown ...
Scheil, Robin
core   +1 more source

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