Results 41 to 50 of about 119,307 (312)

Monolayer via Hydrogenation

open access: yes, 2022
The realization of two-dimensional (2D) magnetism opens an unprecedented possibility for building future magnetoelectric nanodevices; however, wide application is still restricted by the lack of a material platform with a simultaneously large magnetic ...
Munirah Alsubaie   +9 more
core   +1 more source

Identification of Copper as an Ideal Catalyst for Electrochemical Alkyne Semi-hydrogenation

open access: yes, 2022
Selective removal of ∼1% acetylene impurity from ethylene is an essential process to prevent the poisoning of the Ziegler–Natta catalyst in polyethylene production.
Cheng Cai (4684924)   +5 more
core   +2 more sources

Improvement of the selectivity of isophorone hydrogenation by Lewis acids [PDF]

open access: yesRoyal Society Open Science, 2018
The selective hydrogenation of isophorone (3,5,5-trimethyl-2- cyclohexen-1-one) to produce 3,3,5-trimethylcyclohexanone (TMCH), an important organic solvent and pharmaceutical intermediate, is of significance in industry.
Yucui Hou   +3 more
doaj   +1 more source

Structural and biochemical analysis of a B12 superbinder

open access: yesFEBS Letters, EarlyView.
BtuG proteins are vitamin B12 scavengers in Bacteroides thetaiotaomicron, a dominant human gut bacterium. We present crystal structures of three BtuG homologs bound to cobalamin and its precursor cobinamide, revealing picomolar binding affinities, among the highest known for any natural protein.
Jose M. Martinez Felices   +3 more
wiley   +1 more source

CO2 hydrogenation to methanol over zeolite-encaged mononuclear copper centers [PDF]

open access: yes, 2022
The selective hydrogenation of CO2 to methanol by renewable hydrogen source represents an attractive route for CO2 recycling and carbon neutral. Stable catalysts with high activity and methanol selectivity are being hotly pursued, and current debates on ...
Landong, Li   +6 more
core   +2 more sources

Converting copper sulfide to copper with surface sulfur for electrocatalytic alkyne semi-hydrogenation with water

open access: yesNature Communications, 2021
Electrocatalytic alkyne semi-hydrogenation to alkenes with water as the hydrogen source using a low-cost noble-metal-free catalyst is highly desirable but challenging because of their over-hydrogenation to undesired alkanes.
Yongmeng Wu   +5 more
doaj   +1 more source

C2H2 semi-hydrogenation on the PdxMy cluster/graphdiyne catalysts: Effects of cluster composition and size on the activity and selectivity

open access: yesGreen Energy & Environment, 2022
C2H2 semi-hydrogenation has been widely applied in industry to eliminate trace C2H2 from C2H4 feed. C2H2 semi-hydrogenation to C2H4 on a series of the newly designed catalysts, graphdiyne (GDY) as a new carbon allotrope supported different sizes of PdxMy
Ying Wang   +5 more
doaj   +1 more source

Structures of mycobacterial 3‐methylcrotonyl‐CoA carboxylase reveal carrier‐domain translocation between catalytic sites

open access: yesFEBS Letters, EarlyView.
Mycobacterial 3‐methylcrotonyl‐CoA carboxylase uses a mobile biotin‐carrying domain to shuttle a carboxyl group between two catalytic sites, enabling carboxylation of 3‐methylcrotonyl‐CoA during leucine breakdown. Cryo‐electron microscopy captures the carrier at both sites and reveals an inward loop movement that may prevent futile rebinding to the ...
Ajit Yadav   +2 more
wiley   +1 more source

Bifunctional Pd sites on Pd4/Co3O4 nanowires for high selectivity of pyrazine electrocatalytic hydrogenation with water as the hydrogen source [PDF]

open access: yesRSC Applied Interfaces
Liquid organic hydrogen carriers (LOHCs) are considered highly promising materials for hydrogen storage. However, hydrogenation and dehydrogenation of LOHCs often require harsh reaction conditions.
Fangcheng Qiu   +7 more
doaj   +1 more source

The Shewanella oneidensis Fic enzyme SoFic targets the switch‐I region of EF‐Tu for AMPylation

open access: yesFEBS Letters, EarlyView.
Fic enzymes mediate diverse post‐translational modifications across all domains of life, including AMPylation. Prokaryotic EF‐Tu can be AMPylated and deAMPylated by the conserved Fic enzyme SoFic. Structural and biochemical approaches were used to characterize the effect of AMPylation on EF‐Tu, SoFic's enzymatic activities, and the enzyme‐target ...
Svenja Runge   +6 more
wiley   +1 more source

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