Results 31 to 40 of about 38,094 (268)

Converting copper sulfide to copper with surface sulfur for electrocatalytic alkyne semi-hydrogenation with water

open access: yesNature Communications, 2021
Electrocatalytic alkyne semi-hydrogenation to alkenes with water as the hydrogen source using a low-cost noble-metal-free catalyst is highly desirable but challenging because of their over-hydrogenation to undesired alkanes.
Yongmeng Wu   +5 more
doaj   +1 more source

Engineering peptides into antibodies—opportunities and strategies for therapeutic innovation

open access: yesFEBS Letters, EarlyView.
Peptides and antibodies occupy complementary therapeutic niches. Peptides recognize difficult targets in a compact format, while antibodies add specificity, long half‐life, and effector functions. This review examines strategies that merge both modalities—peptide grafting into loops, terminal and Fc fusions, and bioconjugation—highlighting how ...
Jinling Wang   +2 more
wiley   +1 more source

C2H2 semi-hydrogenation on the PdxMy cluster/graphdiyne catalysts: Effects of cluster composition and size on the activity and selectivity

open access: yesGreen Energy & Environment, 2022
C2H2 semi-hydrogenation has been widely applied in industry to eliminate trace C2H2 from C2H4 feed. C2H2 semi-hydrogenation to C2H4 on a series of the newly designed catalysts, graphdiyne (GDY) as a new carbon allotrope supported different sizes of PdxMy
Ying Wang   +5 more
doaj   +1 more source

Emerging experimental and computational methods for studying redox‐regulated structural transitions

open access: yesFEBS Letters, EarlyView.
Redox reactions can reshape proteins and alter how they behave in cells, with important consequences for health and disease. This review explores emerging experimental and computational approaches for discovering these redox‐sensitive protein switches, revealing their structural effects, and predicting their behavior, opening new opportunities to ...
Tasneem Rass   +2 more
wiley   +1 more source

Bifunctional Pd sites on Pd4/Co3O4 nanowires for high selectivity of pyrazine electrocatalytic hydrogenation with water as the hydrogen source [PDF]

open access: yesRSC Applied Interfaces
Liquid organic hydrogen carriers (LOHCs) are considered highly promising materials for hydrogen storage. However, hydrogenation and dehydrogenation of LOHCs often require harsh reaction conditions.
Fangcheng Qiu   +7 more
doaj   +1 more source

Improvement of the selectivity of isophorone hydrogenation by Lewis acids [PDF]

open access: yesRoyal Society Open Science, 2018
The selective hydrogenation of isophorone (3,5,5-trimethyl-2- cyclohexen-1-one) to produce 3,3,5-trimethylcyclohexanone (TMCH), an important organic solvent and pharmaceutical intermediate, is of significance in industry.
Yucui Hou   +3 more
doaj   +1 more source

Structural and biochemical analysis of a B12 superbinder

open access: yesFEBS Letters, EarlyView.
BtuG proteins are vitamin B12 scavengers in Bacteroides thetaiotaomicron, a dominant human gut bacterium. We present crystal structures of three BtuG homologs bound to cobalamin and its precursor cobinamide, revealing picomolar binding affinities, among the highest known for any natural protein.
Jose M. Martinez Felices   +3 more
wiley   +1 more source

Structures of mycobacterial 3‐methylcrotonyl‐CoA carboxylase reveal carrier‐domain translocation between catalytic sites

open access: yesFEBS Letters, EarlyView.
Mycobacterial 3‐methylcrotonyl‐CoA carboxylase uses a mobile biotin‐carrying domain to shuttle a carboxyl group between two catalytic sites, enabling carboxylation of 3‐methylcrotonyl‐CoA during leucine breakdown. Cryo‐electron microscopy captures the carrier at both sites and reveals an inward loop movement that may prevent futile rebinding to the ...
Ajit Yadav   +2 more
wiley   +1 more source

"Hydrogenated nitrile rubber with different hydrogenation degrees prepared by solution hydrogenation method"

open access: yesHecheng xiangjiao gongye
Hydrogenated nitrile rubber with hydrogenation degree of 90%, 95% and 99% was prepared by solution hydrogenation of nitrile rubber with ruthenium catalyst, the effects of catalyst amount, solid rubber content and filling volume of reactor on ...
LI Wen-xina, LIU Ping-pingb, LI Lina, WANG Huia
doaj   +1 more source

Recent Advances in Iridium-Catalyzed Asymmetric Hydrogenation: New Catalysts, Substrates and Applications in Total Synthesis

open access: yesCHIMIA, 2012
Iridium-catalyzed asymmetric hydrogenation has emerged as a highly efficient method for the synthesis of enantiomerically pure compounds. This account summarizes our recent efforts in this field.
Adnan Ganić   +3 more
doaj   +1 more source

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