Results 31 to 40 of about 21,056 (199)

Laccase-catalyzed derivatization of 6-aminopenicillanic, 7-aminocephalosporanic and 7-aminodesacetoxycephalosporanic acid

open access: yesAMB Express, 2020
Trametes spec. laccase (EC 1.10.3.2.) mediates the oxidative coupling of 6-aminopenicillanic, 7-aminocephalosporanic, and 7-aminodesacetoxycephalosporanic acid with 2,5-dihydroxybenzoic acid derivatives to form new penicillin and cephalosporin structures,
Annett Mikolasch   +3 more
doaj   +1 more source

Xishaeleganins A–D, Sesquiterpenoid Hydroquinones from Xisha Marine Sponge Dactylospongia elegans

open access: yesMarine Drugs, 2022
Four new sesquiterpene hydroquinones, xishaeleganins A–D (6–9), along with eleven known related ones (12 and 14–23) were isolated from the Xisha marine sponge Dactylospongia elegans (family Thorectida).
Bao Chen   +5 more
doaj   +1 more source

Electron Donor–Acceptor Complex Catalysis in Synthetic Chemistry

open access: yesAngewandte Chemie, EarlyView.
Electron donor–acceptor (EDA) complexes are moving beyond stoichiometric photoactivation toward catalytic platforms for radical generation. Productive EDA catalysis requires coordinated donor–acceptor association, charge‐transfer excitation, radical reactivity, and vcatalyst turnover.
Tristan von Münchow   +3 more
wiley   +2 more sources

Heck- and Suzuki-coupling approaches to novel hydroquinone inhibitors of calcium ATPase

open access: yesBeilstein Journal of Organic Chemistry, 2019
In this study, we explored Heck- and Suzuki-coupling methodology to modify the template 2,5-di-tert-butylhydroquinone (BHQ, 2), an inhibitor of the enzyme sarco/endoplasmic reticulum calcium ATPase (SERCA).
Robert J. Kempton   +3 more
doaj   +1 more source

Electrophilic Catalysis in Iodosylbenzene Oxidation of Aromatic Derivatives

open access: yesCHIMIA, 1986
The oxidation of activated aromatic compounds (phenols and hydroquinones) is catalyzed by BF3 or RuCl2(PPh3)3. The catalytic effect of the ruthenium is ascribed to electrophilic catalysis, due to complexation between iodosylbenzene and the Ru species ...
Paul Müller, David Manuel Gilabert
doaj   +1 more source

Oxidation of hydroquinones by a nonheme iron(IV)-oxo species

open access: yes, 2017
The reactivity of an isolated, well-characterized nonheme iron(IV)-oxo complex, [(TMC)FeIV{double bond, long}O]2+ (TMC = 1,4,8,11-tetramethyl-1,4,8,11-tetraazacyclotetradecane), has been examined in the oxidation of hydroquinones.
김진흥, 남원우
core   +1 more source

Preparation of Substituted Hydroquinones and Benzofurans from 1,4-Quinone Monoketals

open access: yes, 2006
International audienceAn easy procedure for the preparation of 2-substituted hydroquinones, by addition of organolithium or organomagnesium compounds to 1,4-quinone monoketals followed by acid-catalyzed dienone-phenol type rearrangement, is described ...
Salom-Roig, Xavier   +5 more
core   +1 more source

NMR assignment in regioisomeric hydroquinones [PDF]

open access: yes, 2011
A set of regioisomeric pairs of tricyclic hydroquinones, analogues of antitumor 9,10-dihydroxy-4,4-dimethyl-5,8-dihydroanthracen-1(4H)-one (1) and other derivatives, were synthesized and their regiochemistry and NMR spectra assigned by using 1H-detected ...
Henar Martínez-García   +21 more
core   +1 more source

Recent Advances in Light‐Addressable Electrochemistry for Spatially Resolved Applications

open access: yesAdvanced Materials Technologies, EarlyView.
This comprehensive review highlights light‐addressable electrochemistry as a powerful tool that uses light to control localized chemical reactions on unstructured semiconductor surfaces. The work evaluates advanced strategies to optimize electrode materials for enhanced spatial resolution and stability. Furthermore, it showcases diverse applications in
Nhi Trang Vo   +2 more
wiley   +1 more source

Multi‐Property Machine Learning Models to Accelerate the Transition Toward Bio‐Based Emulsion Polymers

open access: yesAdvanced Intelligent Discovery, EarlyView.
A machine learning framework simultaneously predicts four critical properties of monomers for emulsion polymerization: propagation rate constant, reactivity ratios, glass transition temperature, and water solubility. These tools can be used to systematically identify viable bio‐based monomer pairs as replacements for conventional formulations, with ...
Kiarash Farajzadehahary   +1 more
wiley   +1 more source

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